Short Enantioselective Total Syntheses of trans-Clerodane Diterpenoids: Convergent Fragment Coupling Using a trans-Decalin Tertiary Radical Generated from a Tertiary Alcohol Precursor

Journal of Organic Chemistry

Volumn 81, Issue 16, 2016, Pages 7029-7035

  Slutskyy, Yuriy ^a   Jamison, Christopher R ^a   Lackner, Gregory L ^a   Müller, Daniel S ^a   Dieskau, André P ^a   Untiedt, Nicholas L ^a   Overman, Larry E ^a  

^a UNIVERSITY OF CALIFORNIA   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

BIOCHEMISTRY; CARBON; ENANTIOSELECTIVITY; IRIDIUM; ORGANIC SOLVENTS; SYNTHESIS (CHEMICAL);

CLERODANE DITERPENOIDS; CONJUGATE ADDITION; ELECTRON-DEFICIENT; ENANTIOSELECTIVE TOTAL SYNTHESIS; ORGANIC SYNTHESIS; SYNTHETIC PATHWAYS; SYNTHETIC SEQUENCE; SYNTHETIC STRATEGIES;

LIPIDS;

2 CYCLOHEXENONE DERIVATIVE; 3 METHYL 2 CYCLOHEXENONE; 4 VINYLFURAN 2 ONE; ALCOHOL; CARBON; CESIUM; CLERODANE DERIVATIVE; DECALIN; FURANONE DERIVATIVE; IRIDIUM; NITRILE; OXALIC ACID; RADICAL; UNCLASSIFIED DRUG;

ARTICLE; CATALYST; CONTROLLED STUDY; ELECTRON; ENANTIOSELECTIVITY; LIGHT; NUCLEOPHILICITY; SYNTHESIS;

EID: 84982297047     PISSN: 00223263     EISSN: 15206904     Source Type: Journal    
DOI: 10.1021/acs.joc.6b00697     Document Type: Article

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