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Volumn 22, Issue 23, 2016, Pages 7924-7934

Peroxyl Radical Reactions in Water Solution: A Gym for Proton-Coupled Electron-Transfer Theories

Author keywords

antioxidants; kinetics; proton inventory; radical reactions; reaction mechanisms

Indexed keywords

ANTIOXIDANTS; ELECTRON TRANSITIONS; ELECTRONS; ENZYME KINETICS; PHENOLS; RADIATION CHEMISTRY; RADIOLYSIS; RATE CONSTANTS; REACTION KINETICS; SOLVENTS;

EID: 84964425608     PISSN: 09476539     EISSN: 15213765     Source Type: Journal    
DOI: 10.1002/chem.201504492     Document Type: Article
Times cited : (63)

References (71)
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    • dioxane≈4, which is justified by the very minor acidic dissociation of the phenol in MeOH. See:, M. Musialik, G. Litwinienko, Org. Lett. 2005, 7, 4951-4954.
    • (2005) Org. Lett. , vol.7 , pp. 4951-4954
    • Musialik, M.1    Litwinienko, G.2
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    • One additional explanation is that phenol/THF and deuterated phenol/THF have different contributions to the kinetic solvent effect, because PhOH and PhOD have different hydrogen-bond donating abilities. For instance, the ratio of equilibrium constants K(H)/K(D) for the hydrogen bonding of phenol to solvents was reported to be 0.5 for acetone and 0.7 for acetonitrile at 25 °C, see:, We thank an anonymous reviewer for this suggestion
    • One additional explanation is that phenol/THF and deuterated phenol/THF have different contributions to the kinetic solvent effect, because PhOH and PhOD have different hydrogen-bond donating abilities. For instance, the ratio of equilibrium constants K(H)/K(D) for the hydrogen bonding of phenol to solvents was reported to be 0.5 for acetone and 0.7 for acetonitrile at 25 °C, see:, S. Singh, C. N. R. Rao, Can. J. Chem. 1966, 44, 2611-2615. We thank an anonymous reviewer for this suggestion.
    • (1966) Can. J. Chem. , vol.44 , pp. 2611-2615
    • Singh, S.1    Rao, C.N.R.2


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.