Experimental and theoretical study of a tungsten dihydride silyl complex: New insight into its bonding nature and fluxional behavior

Organometallics

Volumn 29, Issue 23, 2010, Pages 6267-6281

  Ray, Mausumi ^c,d   Nakao, Yoshihide ^a   Sato, Hirofumi ^e   Sakaki, Shigeyoshi ^b   Watanabe, Takahito ^c   Hashimoto, Hisako ^c   Tobita, Hiromi ^c  

^a KYOTO UNIVERSITY   (Japan)

^b KYOTO UNIVERSITY   (Japan)

^c TOHOKU UNIVERSITY   (Japan)

^d NORTHWESTERN UNIVERSITY   (United States)

^e NONE

Author keywords

[No Author keywords available]

Indexed keywords

ACTIVATION ENERGY; BEARINGS (STRUCTURAL); CHEMICAL BONDS; HYDRIDES; MOLECULAR ORBITALS; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; OXIDATION; SILICATES; SILICON; SPECTROSCOPIC ANALYSIS; TUNGSTEN; X RAY CRYSTALLOGRAPHY;

ACTIVATION BARRIERS; ACTIVATION FREE ENERGY; BEFORE AND AFTER; BONDING INTERACTIONS; BONDING NATURE; COORDINATION STRUCTURES; DIHYDRIDES; DIHYDROGEN; ELECTRON CONFIGURATION; ELECTRON POPULATION; ELEMENTAL ANALYSIS; FLUXIONAL BEHAVIOR; H NMR SPECTROSCOPY; H-BONDS; NEGATIVE CHARGE; OPTIMIZED GEOMETRIES; OXIDATION STATE; SILYL COMPLEXES; SILYLENES; SPECTROSCOPIC DATA; THEORETICAL INVESTIGATIONS; THEORETICAL STUDY; TIME-SCALES; TRANSITION STATE; VARIABLE TEMPERATURE;

TUNGSTEN COMPOUNDS;

EID: 84962425727     PISSN: 02767333     EISSN: 15206041     Source Type: Journal    
DOI: 10.1021/om100653v     Document Type: Article

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