Structure and chemical properties of chlorohydrido(diarylsilyl)rhodium(III) complexes, mer-RhCl(H)(SiHAr2)(PMe3)3. Thermally induced chloro transfer from rhodium to silicon in the complexes and silane exchange

Organometallics

Volumn 16, Issue 18, 1997, Pages 3973-3980

  Osakada, Kohtaro ^a   Sarai, Susumu ^a   Koizumi, Take Aki ^a   Yamamoto, Takakazu ^a  

^a TOKYO INSTITUTE OF TECHNOLOGY   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 3242765727     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om970391z     Document Type: Article

References (45)

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39. 2 were observed. This random scrambling of Si-H(D) and Rh-H(D) is slower than the silyl ligand exchange reaction in Scheme 3 and is not related to the process.
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