Highly efficient alkane oxidation catalyzed by [MnV(N)(CN) 4]2-. Evidence for [MnVII(N)(O)(CN) 4]2- as an active intermediate

Journal of the American Chemical Society

Volumn 136, Issue 21, 2014, Pages 7680-7687

  Ma, Li ^a   Pan, Yi ^a   Man, Wai Lun ^a   Kwong, Hoi Ki ^a   Lam, William W Y ^a   Chen, Gui ^a   Lau, Kai Chung ^a   Lau, Tai Chu ^a  

^a CITY UNIVERSITY OF HONG KONG   (Hong Kong)

Author keywords

[No Author keywords available]

Indexed keywords

CATALYSIS; CATALYTIC OXIDATION; CYCLOHEXANE; ISOTOPES; KETONES; MASS SPECTROMETRY; OXIDANTS; OXIDATION; PARAFFINS; RATE CONSTANTS; REACTION INTERMEDIATES;

ACTIVE INTERMEDIATES; ELECTROSPRAY IONIZATION MASS SPECTROMETRY; EQUIMOLAR MIXTURES; H-ATOM ABSTRACTION; HETEROLYTIC CLEAVAGE; KINETIC ISOTOPE EFFECTS; RATE-LIMITING FORMATION; TERMINAL OXIDANTS;

MANGANESE;

ALCOHOL DERIVATIVE; ALKANE; CERIUM; CYANIC ACID DERIVATIVE; CYCLOHEXANE; HYDROGEN PEROXIDE; KETONE DERIVATIVE; MANGANESE DERIVATIVE; NITROGEN DERIVATIVE; OXIDIZING AGENT; OXYGEN DERIVATIVE; SOLVENT;

ARTICLE; BIOTRANSFORMATION; CATALYSIS; DENSITY FUNCTIONAL THEORY; ELECTROSPRAY MASS SPECTROMETRY; OXIDATION; QUANTUM YIELD; REACTION ANALYSIS; ROOM TEMPERATURE;

EID: 84961978327     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/ja5019546     Document Type: Article

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