Oxygen Reduction Catalysis at a Dicobalt Center: The Relationship of Faradaic Efficiency to Overpotential

Journal of the American Chemical Society

Volumn 138, Issue 9, 2016, Pages 2925-2928

  Passard, Guillaume ^a   Ullman, Andrew M ^a   Brodsky, Casey N ^a   Nocera, Daniel G ^a  

^a HARVARD UNIVERSITY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

CATALYSIS; EFFICIENCY; ELECTROLYTIC REDUCTION; THERMODYNAMIC PROPERTIES;

ELECTROCHEMICAL REDUCTIONS; ELECTROCHEMICAL STUDIES; FARADAIC EFFICIENCIES; OXYGEN REDUCTION CATALYSIS; OXYGEN REDUCTION REACTION; ROTATING RING-DISK ELECTRODE; STANDARD POTENTIAL; THERMODYNAMIC CYCLE;

REDUCTION;

ACETIC ACID; COBALT; HYDROGEN PEROXIDE; ORGANIC SOLVENT; OXYGEN; PROTON;

AQUEOUS SOLUTION; ARTICLE; CATALYSIS; ELECTROCHEMICAL ANALYSIS; ELECTRON; REDUCTION; THERMODYNAMICS;

EID: 84960432065     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/jacs.5b12828     Document Type: Article

References (31)

1. Lewis, N. S.; Nocera, D. G. Proc. Natl. Acad. Sci. U. S. A. 2006, 103, 15729 10.1073/pnas.0603395103
2. Lewis, N. S.; Nocera, D. G. Bridge 2015, 46, 41
3. Borup, R.; Meyers, J.; Pivovar, B.; Kim, Y. S.; Mukundan, R.; Garland, N.; Myers, D.; Wilson, M.; Garzon, F.; Wood, D.; Zelenay, P.; More, K.; Stroh, K.; Zawodzinski, T.; Boncella, J.; McGrath, J. E.; Inaba, M.; Miyatake, K.; Hori, M.; Ota, K.; Ogumi, Z.; Miyata, S.; Nishikata, A.; Siroma, Z.; Uchimoto, Y.; Yasuda, K.; Kimijima, K.; Iwashita, N. Chem. Rev. 2007, 107, 3904 10.1021/cr050182l
4. Cook, T. R.; Dogutan, D. K.; Reece, S. Y.; Surendranath, Y.; Teets, T. S.; Nocera, D. G. Chem. Rev. 2010, 110, 6474 10.1021/cr100246c
5. Steele, B. C. H.; Heinzel, A. Nature 2001, 414, 345 10.1038/35104620
6. Anson, F. C.; Shi, C.; Steiger, B. Acc. Chem. Res. 1997, 30, 437 10.1021/ar960264j
7. Kadish, K. M.; Shen, J.; Frémond, L.; Chen, P.; Ojaimi, M. E.; Chkounda, M.; Gros, C. P.; Barbe, J.-M.; Ohkubo, K.; Fukuzumi, S.; Guilard, R. Inorg. Chem. 2008, 47, 6726 10.1021/ic800458s
8. Dogutan, D. K.; Stoian, S. A.; McGuire, R.; Schwalbe, M.; Teets, T. S.; Nocera, D. G. J. Am. Chem. Soc. 2011, 133, 131 10.1021/ja108904s
9. Geiger, T.; Anson, F. C. J. Am. Chem. Soc. 1981, 103, 7489 10.1021/ja00415a016
10. McGuire, R., Jr; Dogutan, D. K.; Teets, T. S.; Suntivich, J.; Shao-Horn, Y.; Nocera, D. G. Chem. Sci. 2010, 1, 411 10.1039/c0sc00281j
11. Collman, J. P.; Devaraj, N. K.; Decréau, R. A.; Yang, Y.; Yan, Y.-L.; Ebina, W.; Eberspacher, T. A.; Chidsey, C. E. D. Science 2007, 315, 1565 10.1126/science.1135844
12. Collman, J. P.; Decréau, R. A.; Lin, H.; Hosseini, A.; Yang, Y.; Dey, A.; Eberspacher, T. A. Proc. Natl. Acad. Sci. U. S. A. 2009, 106, 7320 10.1073/pnas.0902285106
13. Collman, J. P.; Ghosh, S.; Dey, A.; Decréau, R. A.; Yang, Y. J. Am. Chem. Soc. 2009, 131, 5034 10.1021/ja9001579
14. Carver, C. T.; Matson, B. D.; Mayer, J. M. J. Am. Chem. Soc. 2012, 134, 5444 10.1021/ja211987f
15. Wasylenko, D. J.; Rodríguez, C.; Pegis, M. L.; Mayer, J. M. J. Am. Chem. Soc. 2014, 136, 12544 10.1021/ja505667t
16. Chatterjee, S.; Sengupta, K.; Samanta, S.; Das, P. K.; Dey, A. Inorg. Chem. 2015, 54, 2383 10.1021/ic5029959
17. Samanta, S.; Mittra, K.; Sengupta, K.; Chatterjee, S.; Dey, A. Inorg. Chem. 2013, 52, 1443 10.1021/ic3021782
18. Samanta, S.; Das, P. K.; Chatterjee, S.; Sengupta, K.; Mondal, B.; Dey, A. Inorg. Chem. 2013, 52, 12963 10.1021/ic4020652
19. Rosenthal, J.; Nocera, D. G. Acc. Chem. Res. 2007, 40, 543 10.1021/ar7000638
20. Kakuda, S.; Peterson, R. L.; Ohkubo, K.; Karlin, K. D.; Fukuzumi, S. J. Am. Chem. Soc. 2013, 135, 6513 10.1021/ja3125977
21. Fukuzumi, S.; Mandal, S.; Mase, K.; Ohkubo, K.; Park, H.; Benet-Buchholz, J.; Nam, W.; Llobet, A. J. Am. Chem. Soc. 2012, 134, 9906 10.1021/ja303674n
22. Davenport, T. C.; Tilley, T. D. Angew. Chem., Int. Ed. 2011, 50, 12205 10.1002/anie.201106081
23. Davenport, T. C.; Tilley, T. D. Dalton Trans. 2015, 44, 12244 10.1039/C4DT02727B
24. Davenport, T. C.; Ahn, H. S.; Ziegler, M. S.; Tilley, T. D. Chem. Commun. 2014, 50, 6326 10.1039/c3cc46865h
25. Allen, J.; Bard, L. R. F. Electrochemical Methods: Fundamentals and Applications, 2 nd ed.; Wiley: New York, 2001.
26. Andrieux, C. P.; Gamby, J.; Hapiot, P.; Savéant, J.-M. J. Am. Chem. Soc. 2003, 125, 10119 10.1021/ja035268f
27. Costentin, C.; Evans, D. H.; Robert, M.; Savéant, J.-M.; Singh, P. S. J. Am. Chem. Soc. 2005, 127, 12490 10.1021/ja053911n
28. Kütt, A.; Rodima, T.; Saame, J.; Raamat, E.; Mäemets, V.; Kaljurand, I.; Koppel, I. A.; Garlyauskayte, R. Y.; Yagupolskii, Y. L.; Yagupolskii, L. M.; Bernhardt, E.; Willner, H.; Leito, I. J. Org. Chem. 2011, 76, 391 10.1021/jo101409p
29. Izutsu, K. Acid-Base Dissociation Constants in Dipolar Aprotic Solvents; Blackwell: Boston, 1990.
30. Costentin, C.; Drouet, S.; Robert, M.; Savéant, J.-M. Science 2012, 338, 90 10.1126/science.1224581
31. Pegis, M. L.; Roberts, J. A. S.; Wasylenko, D. J.; Mader, E. A.; Appel, A. M.; Mayer, J. M. Inorg. Chem. 2015, 54, 11883 10.1021/acs.inorgchem.5b02136