Catalytic four-electron reduction of O 2 via rate-determining proton-coupled electron transfer to a dinuclear cobalt-μ-1,2-peroxo complex

Journal of the American Chemical Society

Volumn 134, Issue 24, 2012, Pages 9906-9909

  Fukuzumi, Shunichi ^a,b   Mandal, Sukanta ^b,c   Mase, Kentaro ^a   Ohkubo, Kei ^a   Park, Hyejin ^b   Benet Buchholz, Jordi ^c   Nam, Wonwoo ^b   Llobet, Antoni ^b,c  

^a OSAKA UNIVERSITY   (Japan)

^b Ewha Womans University   (South Korea)

^c INSTITUTE OF CHEMICAL RESEARCH OF CATALONIA ICIQ   (Spain)

Author keywords

[No Author keywords available]

Indexed keywords

CATALYTIC CYCLES; CATALYTIC REACTIONS; DINUCLEAR; FOUR-ELECTRON REDUCTION; KINETIC INVESTIGATIONS; PROTON-COUPLED ELECTRON TRANSFER; RATE DETERMINING STEP; TRIFLUOROACETIC ACIDS;

ACETONITRILE; CATALYSIS; COBALT; ELECTRON TRANSITIONS; PROTONS;

COBALT COMPOUNDS;

ACETONITRILE; COBALT COMPLEX; COBALT MU 1,2 PEROXO COMPLEX; OXYGEN; PROTON; TRIFLUOROACETIC ACID; UNCLASSIFIED DRUG;

ARTICLE; CATALYSIS; CHEMICAL REACTION KINETICS; CHEMICAL STRUCTURE; ELECTRON TRANSPORT; REDUCTION; SPECTROSCOPY; SYNTHESIS; X RAY CRYSTALLOGRAPHY;

CATALYSIS; COBALT; ELECTRON TRANSPORT; ELECTRONS; FERROUS COMPOUNDS; MODELS, MOLECULAR; OXIDATION-REDUCTION; OXYGEN; PEROXIDES; PROTONS;

EID: 84862573322     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/ja303674n     Document Type: Article

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