Hydrogen Storage in the Expanded Pore Metal-Organic Frameworks M2(dobpdc) (M = Mg, Mn, Fe, Co, Ni, Zn)

Chemistry of Materials

Volumn 28, Issue 4, 2016, Pages 1128-1138

  Gygi, David ^a   Bloch, Eric D ^a   Mason, Jarad A ^a   Hudson, Matthew R ^b   Gonzalez, Miguel I ^a   Siegelman, Rebecca L ^a   Darwish, Tamim A ^e   Queen, Wendy L ^c,f   Brown, Craig M ^b,d   Long, Jeffrey R ^a  

^a UNIVERSITY OF CALIFORNIA   (United States)

^b NATIONAL INSTITUTE OF STANDARDS AND TECHNOLOGY   (United States)

^c LAWRENCE BERKELEY NATIONAL LABORATORY   (United States)

^d University of Delaware   (United States)

^e AUSTRALIAN NUCLEAR SCIENCE AND TECHNOLOGY ORGANISATION   (Australia)

^f EPFL   (Switzerland)

Author keywords

[No Author keywords available]

Indexed keywords

ADSORPTION; ADSORPTION ISOTHERMS; CARBOXYLATION; COPPER; CRYSTALLINE MATERIALS; GAS ADSORPTION; HYDROGEN; MANGANESE; METALS; NICKEL; ORGANOMETALLICS; STORAGE (MATERIALS); ZINC;

ADSORPTION ENTHALPIES; EXPANDED FRAMEWORKS; GRAVIMETRIC CAPACITY; HIGH PRESSURE ADSORPTIONS; HYDROGEN STORAGE PROPERTIES; ISOSTERIC HEATS OF ADSORPTIONS; METAL ORGANIC FRAMEWORK; POWDER NEUTRON DIFFRACTION;

HYDROGEN STORAGE;

EID: 84959016968     PISSN: 08974756     EISSN: 15205002     Source Type: Journal    
DOI: 10.1021/acs.chemmater.5b04538     Document Type: Article

References (90)

1. Ogden, J. M.; Steinbugler, M. M.; Kreutz, T. G. A comparison of hydrogen, methanol and gasoline as fuels for fuel cell vehicles: implications for vehicle design and infrastructure development J. Power Sources 1999, 79, 143-168 10.1016/S0378-7753(99)00057-9
2. Kamat, P. V.; Bisquert, J. Solar Fuels. Photocatalytic Hydrogen Generation J. Phys. Chem. C 2013, 117, 14873-14875 10.1021/jp406523w
3. Alternative Fuels Data Center. www.afdc.energy.gov/fuels/hydrogen.html (accessed August 26, 2013).
4. EERE: Hydrogen, Fuel Cells, & Infrastructure Technologies Program Storage Targets. http://www1.eere.energy.gov/hydrogenandfuelcells/storage/pdfs/targetsonboardhydrostorage.pdf (accessed August 2012).
5. Sakintuna, B.; Lamari-Darkrim, F.; Hirscher, M. Metal hydride materials for solid hydrogen storage: A review Int. J. Hydrogen Energy 2007, 32, 1121-1140 10.1016/j.ijhydene.2006.11.022
6. Schlapbach, L.; Züttel, A. Hydrogen Storage Materials for Mobile Applications Nature 2001, 414, 353-358 10.1038/35104634
7. Zuettel, A. Materials for hydrogen storage Mater. Today 2003, 6, 24-33 10.1016/S1369-7021(03)00922-2
8. Weitkamp, J.; Fritz, M.; Ernst, S. Zeolites as media for hydrogen storage Int. J. Hydrogen Energy 1995, 20, 967-970 10.1016/0360-3199(95)00058-L
9. Yang, Z.; Xia, Y.; Mokaya, R. Enhanced Hydrogen Storage Capacity of High Surface Area Zeolite-like Carbon Materials J. Am. Chem. Soc. 2007, 129, 1673-1679 10.1021/ja067149g
10. Ricchiardi, G.; Vitillo, J. G.; Cocina, D.; Gribov, E. N.; Zecchina, A. Direct observation and modelling of ordered hydrogen adsorption and catalyzed ortho-para conversion on ETS-10 titanosilicate material Phys. Chem. Chem. Phys. 2007, 9, 2753-2760 10.1039/b703409a
11. Bhatia, S. K.; Myers, A. L. Optimum Conditions for Adsorptive Storage Langmuir 2006, 22, 1688-1700 10.1021/la0523816
12. Rowsell, J. L. C.; Millward, A. R.; Park, K. S.; Yaghi, O. M. Hydrogen Sorption in Functionalized Metal-Organic Frameworks J. Am. Chem. Soc. 2004, 126, 5666-5667 10.1021/ja049408c
13. Rowsell, J. L. C.; Yaghi, O. M. Strategies for Hydrogen Storage in Metal-Organic Frameworks Angew. Chem., Int. Ed. 2005, 44, 4670-4679 10.1002/anie.200462786
14. Millward, A. R.; Yaghi, O. M. Metal-Organic Frameworks with Exceptionally High Capacity for Storage of Carbon Dioxide at Room Temperature J. Am. Chem. Soc. 2005, 127, 17998-17999 10.1021/ja0570032
15. 2 Saturation Uptake in Microporous Metal-Organic Frameworks J. Am. Chem. Soc. 2006, 128, 3494-3495 10.1021/ja058213h
16. Wu, H.; Zhou, W.; Yildirim, T. Hydrogen Storage in a Prototypical Zeolitic Imidazolate Framework-8 J. Am. Chem. Soc. 2007, 129, 5314-5315 10.1021/ja0691932
17. 3 (MOF-5) J. Am. Chem. Soc. 2007, 129, 14176-14177 10.1021/ja076877g
18. Li, Y.; Yang, R. T. Gas Adsorption and Storage in Metal-Organic Framework MOF-177 Langmuir 2007, 23, 12937-12944 10.1021/la702466d
19. Dincǎ, M.; Long, J. R. Hydrogen Storage in Microporous Metal-Organic Frameworks with Exposed Metal Sites Angew. Chem., Int. Ed. 2008, 47, 6766-6779 10.1002/anie.200801163
20. Murray, L. J.; Dincǎ, M.; Long, J. R. Hydrogen storage in metal-organic frameworks Chem. Soc. Rev. 2009, 38, 1294-1314 10.1039/b802256a
21. Getman, R. B.; Bae, Y.; Wilmer, C. E.; Snurr, R. Q. Review and Analysis of Molecular Simulations of Methane, Hydrogen, and Acetylene Storage in Metal-Organic Frameworks Chem. Rev. 2012, 112, 703-723 10.1021/cr200217c
22. Suh, M. P.; Park, H. J.; Prasad, T. K.; Lim, D.-W. Hydrogen Storage in Metal-Organic Frameworks Chem. Rev. 2012, 112, 782-835 10.1021/cr200274s
23. 4 J. Am. Chem. Soc. 2009, 131, 15120-15121 10.1021/ja9072707
24. Bae, Y.-S.; Dubbeldam, D.; Nelson, A.; Walton, K. S.; Hupp, J. T.; Snurr, R. Q. Strategies for Characterization of Large-Pore Metal-Organic Frameworks by Combined Experimental and Computational Methods Chem. Mater. 2009, 21, 4768-4777 10.1021/cm803218f
25. Martin, R. M.; Haranczyk, M. Exploring frontiers of high surface area metal-organic frameworks Chem. Sci. 2013, 4, 1781-1785 10.1039/c3sc00033h
26. Chae, H. K.; Siberio-Pérez, D. Y.; Kim, J.; Go, Y.; Eddaoudi, M.; Matzger, A. J.; O'Keeffe, M.; Yaghi, O. M. A route to high surface area, porosity and inclusion of large molecules in crystals Nature 2004, 427, 523-527 10.1038/nature02311
27. Farha, O. K.; Eryazici, I.; Jeong, N. C.; Hauser, B. G.; Wilmer, C. E.; Sarjeant, A. A.; Snurr, R. Q.; Nguyen, S. T.; Yazaydin, A. Ö.; Hupp, J. T. Metal-Organic Framework Materials with Ultrahigh Surface Areas: Is the Sky the Limit? J. Am. Chem. Soc. 2012, 134, 15016-15021 10.1021/ja3055639
28. 2+ Coordination Sites J. Am. Chem. Soc. 2006, 128, 16876-16883 10.1021/ja0656853
29. 2 J. Am. Chem. Soc. 2007, 129, 11172-11176 10.1021/ja072871f
30. 2 Interactions in a Fully Desolvated Sodalite-Type Metal-Organic Framework Angew. Chem., Int. Ed. 2007, 46, 1419-1422 10.1002/anie.200604362
31. 3btt) Dalton Trans. 2011, 40, 12288-12300 10.1039/c1dt11590a
32. Sumida, K.; Stück, D.; Mino, L.; Chai, J.-D.; Bloch, E. D.; Zavorotynska, O.; Murray, L. J.; Dincǎ, M.; Chavan, S.; Bordiga, S.; Head-Gordon, M.; Long, J. R. Impact of Metal and Anion Substitutions on the Hydrogen Storage Properties of M-BTT Metal-Organic Frameworks J. Am. Chem. Soc. 2013, 135, 1083-1091 10.1021/ja310173e
33. Sumida, K.; Horike, S.; Kaye, S. S.; Herm, Z. R.; Queen, W. L.; Brown, C. M.; Grandjean, F.; Long, G. J.; Long, J. R.; Dailly, A. Hydrogen storage and carbon dioxide capture in an iron-based sodalite-type metal-organic framework (Fe-BTT) discovered via high-throughput methods Chem. Sci. 2010, 1, 184-191 10.1039/c0sc00179a
34. Rosi, N. L.; Kim, J.; Eddaoudi, M.; Chen, B.; O'Keeffe, M.; Yaghi, O. M. Rod Packings and Metal-Organic Frameworks Constructed from Rod-Shaped Secondary Building Units J. Am. Chem. Soc. 2005, 127, 1504-1518 10.1021/ja045123o
35. Dietzel, P. D. C.; Morita, Y.; Blom, R.; Fjellvåg, H. An In Situ High-Temperature Single-Crystal Investigation of a Dehydrated Metal-Organic Framework Compound and Field-Induced Magnetization of One-Dimensional Metal-Oxygen Chains Angew. Chem., Int. Ed. 2005, 44, 6354-6358 10.1002/anie.200501508
36. Dietzel, P. D. C.; Panella, B.; Hirscher, M.; Blom, R.; Fjellvåg, H. Hydrogen adsorption in a nickel based coordination polymer with open metal sites in the cylindrical cavities of the desolvated framework Chem. Commun. 2006, 959-961 10.1039/b515434k
37. Dietzel, P. D. C.; Blom, R.; Fjellvåg, H. Base-Induced Formation of Two Magnesium Metal-Organic Framework Compounds with a Bifunctional Tetratopic Ligand Eur. J. Inorg. Chem. 2008, 3624-3632 10.1002/ejic.200701284
38. 2 Adsorption in Isostructural Metal-Organic Frameworks with Open Metal Sites: Strong Dependence of the Binding Strength on Metal Ions J. Am. Chem. Soc. 2008, 130, 15268-15269 10.1021/ja807023q
39. 2 in a Redox-Active Metal-Organic Framework with Open Iron(II) Coordination Sites J. Am. Chem. Soc. 2011, 133, 14814-14822 10.1021/ja205976v
40. Sanz, R.; Martínez, F.; Orcajo, G.; Wojtas, L.; Briones, D. Synthesis of a honeycomb-like Cu-based metal-organic framework and its carbon dioxide adsorption behavior Dalton Trans. 2013, 42, 2392-2398 10.1039/C2DT32138F
41. Díaz-García, M.; Sánchez-Sánchez, M. Synthesis and characterization of a new Cd-based metal-organic framework isostructural with MOF-74/CPO-27 materials Microporous Mesoporous Mater. 2014, 190, 248-254 10.1016/j.micromeso.2014.02.021
42. 2+ Sites J. Phys. Chem. C 2011, 115, 8414-8421 10.1021/jp200638n
43. 2 (M = Cr, Fe, Ni, Cu, Mo, Ru) Dalton. Trans. 2012, 41, 7931-7938 10.1039/c2dt30372h
44. 2+ Chem. Sci. 2012, 3, 2110-2113 10.1039/c2sc20306e
45. 2+-Substituted MOF-5 and Redox Reactivity in Cr- and Fe-MOF-5 J. Am. Chem. Soc. 2013, 135, 12886-12981 10.1021/ja4064475
46. Brozek, C. K.; Dincǎ, M. Thermodynamic parameters of cation exchange in MOF-5 and MFU-41 Chem. Commun. 2015, 51, 11780-11782 10.1039/C5CC04249F
47. Wiers, B. M.; Foo, M.-L.; Balsara, N.; Long, J. R. A Solid Lithium Electrolyte via Addition of Lithium Isopropoxide to a Metal-Organic Framework with Open Metal Sites J. Am. Chem. Soc. 2011, 133, 14522-14525 10.1021/ja205827z
48. Kobayashi, Y.; Jacobs, B.; Allendorf, M. D.; Long, J. R. Conductivity, Doping, and Redox Chemistry of a Microporous Dithiolene-Based Metal-Organic Framework Chem. Mater. 2010, 22, 4120-4122 10.1021/cm101238m
49. Aubrey, M. L.; Ameloot, R.; Wiers, B. M.; Long, J. R. Metal-organic frameworks as solid magnesium electrolytes Energy Environ. Sci. 2014, 7, 667-671 10.1039/c3ee43143f
50. Talin, A. A.; Centrone, A.; Ford, A. C.; Foster, M. E.; Stavila, V.; Haney, P.; Kinney, A.; Szalai, V.; El Gabaly, F.; Yoon, H. P.; Léonard, F.; Allendorf, M. D. Tunable Electrical Conductivity in Metal-Organic Framework Thin-Film Devices Science 2014, 343, 66-69 10.1126/science.1246738
51. Horcajada, P.; Serre, C.; Maurin, G.; Ramsahye, N. A.; Balas, F.; Vallet-Regí, M.; Sebban, M.; Taulelle, F.; Férey, G. Flexible Porous Metal-Organic Frameworks for a Controlled Drug Delivery J. Am. Chem. Soc. 2008, 130, 6774-6780 10.1021/ja710973k
52. 2(dobdc) J. Am. Chem. Soc. 2015, 137, 3466-3469 10.1021/ja5132243
53. 2O in a metal-organic framework with coordinatively unsaturated iron(II) sites Nat. Chem. 2014, 6, 590-595 10.1038/nchem.1956
54. Gonzalez, M. I.; Bloch, E. D.; Mason, J. A.; Teat, S. J.; Long, J. R. Single-Crystal-to-Single-Crystal Metalation of a Metal-Organic Framework: A Route toward Structurally Well-Defined Catalysts Inorg. Chem. 2015, 54, 2995-3005 10.1021/acs.inorgchem.5b00096
55. Mlinar, A. N.; Keitz, B. K.; Gygi, D.; Bloch, E. D.; Long, J. R.; Bell, A. T. Selective Propene Oligomerization with Nickel(II)-Based Metal-Organic Frameworks ACS Catal. 2014, 4, 717-721 10.1021/cs401189a
56. Liu, Y.; Kabbour, H.; Brown, C. M.; Neumann, D. A.; Ahn, C. C. Increasing the Density of Adsorbed Hydrogen with Coordinatively Unsaturated Metal Centers in Metal-Organic Frameworks Langmuir 2008, 24, 4772-4777 10.1021/la703864a
57. 2(dhtp) from gas adsorption, IR spectroscopy and X-ray diffraction Chem. Commun. 2008, 5125-5127 10.1039/b810574j
58. Britt, D.; Furukawa, H.; Wang, B.; Glover, T. G.; Yaghi, O. M. Highly efficient separation of carbon dioxide by a metal-organic framework replete with open metal sites Proc. Natl. Acad. Sci. U. S. A. 2009, 106, 20637-20640 10.1073/pnas.0909718106
59. Dietzel, P. D. C.; Besikiotis, V.; Blom, R. Application of metal-organic frameworks with coordinatively unsaturated metal sites in storage and separation of methane and carbon dioxide J. Mater. Chem. 2009, 19, 7362-7370 10.1039/b911242a
60. Herm, Z. R.; Swisher, J. A.; Smit, B.; Krishna, R.; Long, J. R. Metal-Organic Frameworks as Adsorbents for Hydrogen Purification and Precombustion Carbon Dioxide Capture J. Am. Chem. Soc. 2011, 133, 5664-5667 10.1021/ja111411q
61. Mason, J. A.; Sumida, K.; Herm, Z. R.; Krishna, R.; Long, J. R. Evaluating metal-organic frameworks for post-combustion carbon dioxide capture via temperature swing adsorption Energy Environ. Sci. 2011, 4, 3030-3040 10.1039/c1ee01720a
62. Bloch, E. D.; Queen, W. L.; Krishna, R.; Zadrozny, J. M.; Brown, C. M.; Long, J. R. Hydrocarbon Separations in a Metal-Organic Framework with Open Iron(II) Coordination Sites Science 2012, 335, 1606-1610 10.1126/science.1217544
63. 2 Dynamics in a Metal-Organic Framework with Open Metal Sites J. Am. Chem. Soc. 2012, 134, 14341-14344 10.1021/ja306822p
64. 2(dobdc) (M = Mg, Mn, Fe, Co, Ni, Zn) Chem. Sci. 2013, 4, 2054-2061 10.1039/c3sc00032j
65. 2(dobdc) Microporous Mesoporous Mater. 2012, 151, 481-487 10.1016/j.micromeso.2011.09.004
66. 2 adsorption in the metal-organic framework CPO-27 with different metals Chem. Sci. 2013, 4, 3544-3556 10.1039/c3sc51319j
67. 4 J. Am. Chem. Soc. 2014, 136, 698-704 10.1021/ja4102979
68. Herm, Z. R.; Bloch, E. D.; Long, J. R. Hydrocarbon Separations in Metal-Organic Frameworks Chem. Mater. 2014, 26, 323-338 10.1021/cm402897c
69. 2 in Prototypical Metal-Organic Frameworks: A Combined Neutron Diffraction and First-Principles Study J. Phys. Chem. Lett. 2010, 1, 1946-1951 10.1021/jz100558r
70. 2+ adsorption sites Chem. Commun. 2011, 47, 1157-1159 10.1039/C0CC03453C
71. 2 Adsorption and Zero Thermal Expansion in an Anisotropic Pore Network J. Phys. Chem. C 2011, 115, 24915-24919 10.1021/jp208529p
72. 2) (dobdc) Dalton Trans. 2012, 41, 4180-4187 10.1039/c2dt12138g
73. Brown, C. M.; Ramirez-Cuesta, A. J.; Her, J.-H.; Wheatley, P. S.; Morris, R. E. Structure and spectroscopy of hydrogen adsorbed in a nickel metal-organic framework Chem. Phys. 2013, 427, 3-8 10.1016/j.chemphys.2013.08.010
74. 2 Binding at the Open Metal Sites J. Am. Chem. Soc. 2014, 136, 12119-12129 10.1021/ja506230r
75. Deng, H.; Grunder, S.; Cordova, K. E.; Valente, C.; Furukawa, H.; Hmadeh, M.; Gandara, F.; Whalley, A. C.; Liu, Z.; Asahina, S.; Kazumori, H.; O'Keeffe, M.; Terasaki, O.; Stoddart, J. F.; Yaghi, O. M. Large-Pore Apertures in a Series of Metal-Organic Frameworks Science 2012, 336, 1018-1023 10.1126/science.1220131
76. 2(dobpdc) J. Am. Chem. Soc. 2012, 134, 7056-7065 10.1021/ja300034j
77. 2 Dynamics in Metal-Organic Frameworks with Open Metal Sites Angew. Chem., Int. Ed. 2013, 52, 4410-4413 10.1002/anie.201300446
78. 2 in diamine-appended metal-organic frameworks Nature 2015, 519, 303-308 10.1038/nature14327
79. Toby, B. H. EXPGUI, a graphical user interface for GSAS J. Appl. Crystallogr. 2001, 34, 210-213 10.1107/S0021889801002242
80. Larson, A. C.; Von Dreele, R. B. General Structure Analysis System (GSAS); Los Alamos National Laboratory Report LAUR: Los Alamos, New Mexico, 1994; pp 86-748.
81. Walton, K. S.; Snurr, R. Q. Applicability of the BET Method for Determining Surface Areas of Microporous Metal-Organic Frameworks J. Am. Chem. Soc. 2007, 129, 8552-8556 10.1021/ja071174k
82. 2(dobdc) (M = Mg, Mn, Fe, Co, Ni, Cu, Zn) Chem. Sci. 2014, 5, 4569-4581 10.1039/C4SC02064B
83. Vitillo, J. G.; Regli, L.; Chavan, S.; Ricchiardi, G.; Spoto, G.; Dietzel, P. D. C.; Bordiga, S.; Zecchina, A. Role of Exposed Metal Sites in Hydrogen Storage in MOFs J. Am. Chem. Soc. 2008, 130, 8386-8396 10.1021/ja8007159
84. Rowsell, J. L. C.; Yaghi, O. M. Effects of Functionalization, Catenation, and Variation of the Metal Oxide and Organic Linking Units on the Low-Pressure Hydrogen Adsorption Properties of Metal-Organic Frameworks J. Am. Chem. Soc. 2006, 128, 1304-1315 10.1021/ja056639q
85. Irving, H.; Williams, J. P. Order of Stability of Metal Complexes Nature 1948, 162, 746-747 10.1038/162746a0
86. Sato, H.; Kosaka, W.; Matsuda, R.; Hori, A.; Hijikata, Y.; Belosludov, R. V.; Sakaki, S.; Takata, M.; Kitagawa, S. Self-Accelerating CO Sorption in a Soft Nanoporous Crystal Science 2014, 343, 167-170 10.1126/science.1246423
87. 1/2 Bull. Chem. Soc. Jpn. 2008, 81, 847-856 10.1246/bcsj.81.847
88. Yuan, D.; Zhao, D.; Sun, D.; Zhou, H.-C. An Isoreticular Series of Metal-Organic Frameworks with Dendritic Hexacarboxylate Ligands and Exceptionally High Gas-Uptake Capacity Angew. Chem., Int. Ed. 2010, 49, 5357-5361 10.1002/anie.201001009
89. Park, H. J.; Lim, D.-W.; Yang, W. S.; Oh, T.-R.; Suh, M. P. A Highly Porous Metal-Organic Framework: Structural Transformations of a Guest-Free MOF Depending on Activation Method and Temperature Chem. Eur. J. 2011, 17, 7251-7260 10.1002/chem.201003376
90. Mason, J. A.; Veenstra, M.; Long, J. R. Evaluating metal-organic frameworks for natural gas storage Chem. Sci. 2014, 5, 32-51 10.1039/C3SC52633J