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Volumn 129, Issue 46, 2007, Pages 14176-14177

Impact of preparation and handling on the hydrogen storage properties of Zn4O(1,4-benzenedicarboxylate)3 (MOF-5)

Author keywords

[No Author keywords available]

Indexed keywords

HYDROGEN; ZINC OXIDE;

EID: 36448988968     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja076877g     Document Type: Article
Times cited : (1522)

References (23)
  • 1
    • 0035891289 scopus 로고    scopus 로고
    • and references therein
    • Schlapbach, L.; Züttel, A. Nature 2001, 414, 353 and references therein.
    • (2001) Nature , vol.414 , pp. 353
    • Schlapbach, L.1    Züttel, A.2
  • 8
  • 9
    • 36448992449 scopus 로고    scopus 로고
    • Excess uptake is the amount of gas taken up in addition to what would be present in a container with a equal to the pore within the sample. Total uptake is the amount of gas contained within the of the crystals, which includes both surface-adsorbed molecules and pressurized gas within the pores
    • Excess uptake is the amount of gas taken up in addition to what would be present in a container with a volume equal to the pore volume within the sample. Total uptake is the amount of gas contained within the volume of the crystals, which includes both surface-adsorbed molecules and pressurized gas within the pores.
  • 17
    • 36448954318 scopus 로고    scopus 로고
    • The yellow color is likely due to decomposition of DEF to form guest oligomers that are not readily evacuated. Heating a solution of just Zn-(NO 3)2·6H2O in DEF indeed led to a yellow precipitate and a yellow solution containing a range of higher molecular weight organic species
    • 2O in DEF indeed led to a yellow precipitate and a yellow solution containing a range of higher molecular weight organic species.
  • 20
    • 33947615627 scopus 로고    scopus 로고
    • Additional factors in some of the preparations may be framework interpenetration and/or the presence of zinc guest species: Hafizovic, J, Bjørgen, M, Olsbye, U, Dietzel, P. D. C, Bordiga, S, Prestipino, C, Lamberti, C, Lillerud, K. P. J. Am. Chem. Soc. 2007, 129, 3612
    • Additional factors in some of the preparations may be framework interpenetration and/or the presence of zinc guest species: Hafizovic, J.; Bjørgen, M.; Olsbye, U.; Dietzel, P. D. C.; Bordiga, S.; Prestipino, C.; Lamberti, C.; Lillerud, K. P. J. Am. Chem. Soc. 2007, 129, 3612.
  • 21
    • 34447502239 scopus 로고    scopus 로고
    • Grand canonical Monte Carlo simulations suggest that these steps are associated with preferential initial adsorption of N2 molecules at the corners within the framework: Walton, K. S, Snurr, R. Q. J. Am. Chem. Soc. 2007, 129, 8552
    • 2 molecules at the corners within the framework: Walton, K. S.; Snurr, R. Q. J. Am. Chem. Soc. 2007, 129, 8552.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.