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Excess uptake is the amount of gas taken up in addition to what would be present in a container with a equal to the pore within the sample. Total uptake is the amount of gas contained within the of the crystals, which includes both surface-adsorbed molecules and pressurized gas within the pores
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Excess uptake is the amount of gas taken up in addition to what would be present in a container with a volume equal to the pore volume within the sample. Total uptake is the amount of gas contained within the volume of the crystals, which includes both surface-adsorbed molecules and pressurized gas within the pores.
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The yellow color is likely due to decomposition of DEF to form guest oligomers that are not readily evacuated. Heating a solution of just Zn-(NO 3)2·6H2O in DEF indeed led to a yellow precipitate and a yellow solution containing a range of higher molecular weight organic species
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2O in DEF indeed led to a yellow precipitate and a yellow solution containing a range of higher molecular weight organic species.
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Additional factors in some of the preparations may be framework interpenetration and/or the presence of zinc guest species: Hafizovic, J, Bjørgen, M, Olsbye, U, Dietzel, P. D. C, Bordiga, S, Prestipino, C, Lamberti, C, Lillerud, K. P. J. Am. Chem. Soc. 2007, 129, 3612
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Additional factors in some of the preparations may be framework interpenetration and/or the presence of zinc guest species: Hafizovic, J.; Bjørgen, M.; Olsbye, U.; Dietzel, P. D. C.; Bordiga, S.; Prestipino, C.; Lamberti, C.; Lillerud, K. P. J. Am. Chem. Soc. 2007, 129, 3612.
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Grand canonical Monte Carlo simulations suggest that these steps are associated with preferential initial adsorption of N2 molecules at the corners within the framework: Walton, K. S, Snurr, R. Q. J. Am. Chem. Soc. 2007, 129, 8552
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2 molecules at the corners within the framework: Walton, K. S.; Snurr, R. Q. J. Am. Chem. Soc. 2007, 129, 8552.
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