Surface Enhancement in Ultrafast 2D ATR IR Spectroscopy at the Metal-Liquid Interface

Journal of Physical Chemistry C

Volumn 120, Issue 6, 2016, Pages 3350-3359

  Kraack, Jan Philip ^a   Kaech, Andres ^a   Hamm, Peter ^a  

^a UNIVERSITY OF ZURICH   (Switzerland)

Author keywords

[No Author keywords available]

Indexed keywords

AROMATIC COMPOUNDS; CYANIDES; GOLD; LIQUIDS; SPACECRAFT INSTRUMENTS; STRUCTURAL DYNAMICS;

ATR-IR SPECTROSCOPY; ATTENUATED TOTAL REFLECTANCE INFRARED; ELECTROMAGNETIC ENHANCEMENT; METAL LIQUID INTERFACES; MOLECULAR PROPERTIES; SOLID-LIQUID INTERFACES; SURFACE ENHANCEMENT; ULTRA-FAST SPECTROSCOPIES;

PHASE INTERFACES;

EID: 84958077540     PISSN: 19327447     EISSN: 19327455     Source Type: Journal    
DOI: 10.1021/acs.jpcc.5b11051     Document Type: Article

References (92)

1. Alibabaei, L.; Brennaman, M. K.; Norris, M. R.; Kalanyan, B.; Song, W.; Losego, M. D.; Concepcion, J. J.; Binstead, R. A.; Parsons, G. N.; Meyer, T. J. Solar Water Splitting in a Molecular Photoelectrochemical Cell Proc. Natl. Acad. Sci. U. S. A. 2013, 110, 20008-20013 10.1073/pnas.1319628110
2. Radu, I.; Schleeger, M.; Bolwien, C.; Heberle, J. Time-Resolved Methods in Biophysics. 10. Time-Resolved FT-IR Difference Spectroscopy and the Application to Membrane Proteins Photochem. Photobiol. Sci. 2009, 8, 1517-1528 10.1039/b9pp00050j
3. DiBenedetto, S. A.; Facchetti, A.; Ratner, M. A.; Marks, T. J. Molecular Self-Assembled Monolayers and Multilayers for Organic and Unconventional Inorganic Thin-Film Transistor Applications Adv. Mater. 2009, 21, 1407-1433 10.1002/adma.200803267
4. Rosenfeld, D. E.; Gengeliczki, Z.; Smith, B. J.; Stack, T. D. P.; Fayer, M. D. Structural Dynamics of a Catalytic Monolayer Probed by Ultrafast 2D IR Vibrational Echoes Science 2011, 334, 634-639 10.1126/science.1211350
5. Kraack, J. P.; Lotti, D.; Hamm, P. 2D Attenuated Total Reflectance Infrared Spectroscopy Reveals Ultrafast Vibrational Dynamics of Organic Monolayers at Metal-Liquid Interfaces J. Chem. Phys. 2015, 142, 212413 10.1063/1.4916915
6. Nihonyanagi, S.; Eftekhari-Bafrooei, A.; Borguet, E. Ultrafast Vibrational Dynamics and Spectroscopy of a Siloxane Self-Assembled Monolayer J. Chem. Phys. 2011, 134, 084701 10.1063/1.3518457
7. Hamm, P.; Zanni, M. Concepts and Methods of 2D Infrared Spectroscopy; Cambridge University Press: New York, 2011.
8. Cho, M. Coherent Two-Dimensional Optical Spectroscopy Chem. Rev. 2008, 108, 1331-1418 10.1021/cr078377b
9. Zanni, M. T.; Hochstrasser, R. M. Two-Dimensional Infrared Spectroscopy: A Promising New Method for the Time Resolution of Structures Curr. Opin. Struct. Biol. 2001, 11, 516-522 10.1016/S0959-440X(00)00243-8
10. Zheng, J.; Kwak, K.; Fayer, M. D. Ultrafast 2D IR Vibrational Echo Spectroscopy Acc. Chem. Res. 2007, 40, 75-83 10.1021/ar068010d
11. van Wilderen, L. J. G. W.; Bredenbeck, J. Von ultraschnellen Strukturbestimmungen bis zum Steuern von Reaktionen: Mehrdimensionale gemischte IR/nicht-IR-Schwingungsspektroskopie Angew. Chem. 2015, 127, 11790-11807 10.1002/ange.201503155
12. Kraack, J. P.; Lotti, D.; Hamm, P. Ultrafast, Multidimensional Attenuated Total Reflectance Spectroscopy of Adsorbates at Metal Surfaces J. Phys. Chem. Lett. 2014, 5, 2325-2329 10.1021/jz500978z
13. Kraack, J. P.; Lotti, D.; Hamm, P. Surface-Enhanced, Multi-Dimensional Attenuated Total Reflectance Spectroscopy Proc. SPIE 2015, 9549, 95490S 10.1117/12.2185533
14. Lotti, D.; Hamm, P.; Kraack, J. P. Surface-Sensitive Spectro-Electrochemistry Using Ultrafast 2D ATR IR Spectroscopy. J. Phys. Chem. C 2016, 10.1021/acs.jpcc.6b00395.
15. Lummerstorfer, T.; Kattner, J.; Hoffmann, H. Monolayers at Solid-Solid Interfaces Probed with Infrared Spectroscopy Anal. Bioanal. Chem. 2007, 388, 55-64 10.1007/s00216-006-1010-4
16. Donaldson, P. M.; Hamm, P. Gold Nanoparticle Capping Layers: Structure, Dynamics, and Surface Enhancement Measured Using 2D-IR Spectroscopy Angew. Chem. 2013, 125, 662-666 10.1002/ange.201204973
17. Osawa, M. Surface-Enhanced Infrared Absorption. In Near-Field Optics and Surface Plasmon Polaritons; Kawata, S., Ed.; Topics in Applied Physics Series; Springer-Verlag: Berlin, 2001; Vol. 81, pp 163-187.
18. Aroca, R. Surface-Enhanced Vibrational Spectroscopy; John Wiley & Sons, Ltd.: Chichester, U.K., 2006.
19. Adato, R.; Altug, H. In-Situ Ultra-Sensitive Infrared Absorption Spectroscopy of Biomolecule Interactions in Real Time with Plasmonic Nanoantennas Nat. Commun. 2013, 4, 2154 10.1038/ncomms3154
20. Ataka, K.; Stripp, S. T.; Heberle, J. Surface-Enhanced Infrared Absorption Spectroscopy (SEIRAS) to Probe Monolayers of Membrane Proteins Biochim. Biophys. Acta, Biomembr. 2013, 1828, 2283-2293 10.1016/j.bbamem.2013.04.026
21. Aroca, R. F.; Ross, D. J.; Domingo, C. Surface-Enhanced Infrared Spectroscopy Appl. Spectrosc. 2004, 58, 324A-338A 10.1366/0003702042475420
22. Selig, O.; Siffels, R.; Rezus, Y. L. A. Ultrasensitive Ultrafast Vibrational Spectroscopy Employing the Near Field of Gold Nanoantennas Phys. Rev. Lett. 2015, 114, 233004 10.1103/PhysRevLett.114.233004
23. Keller, E. L.; Brandt, N. C.; Cassabaum, A. A.; Frontiera, R. R. Ultrafast Surface-Enhanced Raman Spectroscopy Analyst 2015, 140, 4922-4931 10.1039/C5AN00869G
24. Osawa, M.; Ataka, K. Electromagnetic Mechanism of Enhanced Infrared Absorption of Molecules Adsorbed on Metal Island Films Surf. Sci. 1992, 262, L118-L122 10.1016/0039-6028(92)90119-Q
25. Xu, X. G.; Raschke, M. B. Near-Field Infrared Vibrational Dynamics and Tip-Enhanced Decoherence Nano Lett. 2013, 13, 1588-1595 10.1021/nl304804p
26. Muller, E. A.; Pollard, B.; Raschke, M. B. Infrared Chemical Nano-Imaging: Accessing Structure, Coupling, and Dynamics on Molecular Length Scales J. Phys. Chem. Lett. 2015, 6, 1275-1284 10.1021/acs.jpclett.5b00108
27. Wu, C.; Khanikaev, A. B.; Adato, R.; Arju, N.; Yanik, A. A.; Altug, H.; Shvets, G. Fano-Resonant Asymmetric Metamaterials for Ultrasensitive Spectroscopy and Identification of Molecular Monolayers Nat. Mater. 2011, 11, 69-75 10.1038/nmat3161
28. Novotny, L.; van Hulst, N. Antennas for Light Nat. Photonics 2011, 5, 83-90 10.1038/nphoton.2010.237
29. Zeman, E. J.; Schatz, G. C. An Accurate Electromagnetic Theory Study of Surface Enhancement Factors for Ag, Au, Cu, Li, Na, AI, Ga, In, Zn, and Cd J. Phys. Chem. 1987, 91, 634-643 10.1021/j100287a028
30. Kelly, K. L.; Coronado, E.; Zhao, L. L.; Schatz, G. C. The Optical Properties of Metal Nanoparticles: The Influence of Size, Shape, and Dielectric Environment J. Phys. Chem. B 2003, 107, 668-677 10.1021/jp026731y
31. Schlücker, S. Surface-Enhanced Raman Spectroscopy: Concepts and Chemical Applications Angew. Chem., Int. Ed. 2014, 53, 4756-4795 10.1002/anie.201205748
32. Enders, D.; Nagao, T.; Pucci, A.; Nakayama, T.; Aono, M. Surface-Enhanced ATR-IR Spectroscopy with Interface-Grown Plasmonic Gold-Island Films near the Percolation Threshold Phys. Chem. Chem. Phys. 2011, 13, 4935-4941 10.1039/c0cp01450h
33. Grechko, M.; Zanni, M. T. Quantification of Transition Dipole Strengths Using 1D and 2D Spectroscopy for the Identification of Molecular Structures via Exciton Delocalization: Application to α-Helices J. Chem. Phys. 2012, 137, 184202 10.1063/1.4764861
34. Loparo, J. J.; Roberts, S. T.; Nicodemus, R. A.; Tokmakoff, A. Variation of the Transition Dipole Moment across the OH Stretching Band of Water Chem. Phys. 2007, 341, 218-229 10.1016/j.chemphys.2007.06.056
35. Hamm, P.; Kaindl, R. A.; Stenger, J. Noise Suppression in Femtosecond Mid-Infrared Light Sources Opt. Lett. 2000, 25, 1798-1800 10.1364/OL.25.001798
36. Helbing, J.; Hamm, P. Compact Implementation of Fourier Transform Two-Dimensional IR Spectroscopy without Phase Ambiguity J. Opt. Soc. Am. B 2011, 28, 171 10.1364/JOSAB.28.000171
37. Demirdöven, N.; Khalil, M.; Golonzka, O.; Tokmakoff, A. Dispersion Compensation with Optical Materials for Compression of Intense Sub-100-Fs Mid-Infrared Pulses Opt. Lett. 2002, 27, 433-435 10.1364/OL.27.000433
38. Bagchi, S.; Boxer, S. G.; Fayer, M. D. Ribonuclease S Dynamics Measured Using a Nitrile Label with 2D IR Vibrational Echo Spectroscopy J. Phys. Chem. B 2012, 116, 4034-4042 10.1021/jp2122856
39. Kim, Y. S.; Hochstrasser, R. M. Chemical Exchange 2D IR of Hydrogen-Bond Making and Breaking Proc. Natl. Acad. Sci. U. S. A. 2005, 102, 11185-11190 10.1073/pnas.0504865102
40. Zhang, Z.; Imae, T. Study of Surface-Enhanced Infrared Spectroscopy J. Colloid Interface Sci. 2001, 233, 99-106 10.1006/jcis.2000.7220
41. Badilescu, S.; Ashrit, P. V.; Truong, V. V. Enhanced Infrared Attenuated-Total-Reflection Spectra of p-Nitrobenzoic Acid with Ag Films Appl. Phys. Lett. 1988, 52, 1551-1553 10.1063/1.99078
42. Nishikawa, Y.; Fujiwara, K.; Ataka, K.; Osawa, M. Surface-Enhanced Infrared External Reflection Spectroscopy at Low Reflective Surfaces and Its Application to Surface Analysis of Semiconductors, Glasses, and Polymers Anal. Chem. 1993, 65, 556-562 10.1021/ac00053a011
43. Chen, T.; Borchers, R. L.; Perry, D. A. Surface-Enhanced Infrared Absorption Spectroscopic Investigation of Benzamide Thin-Film Formation, Stability, and Catalysis on Gold and Silver Nanostructures Part. Sci. Technol. 2014, 32, 234-241 10.1080/02726351.2013.851134
44. Johnson, E.; Aroca, R. Surface-Enhanced Infrared Spectroscopy of Monolayers J. Phys. Chem. 1995, 99, 9325-9330 10.1021/j100023a004
45. Pucci, A. IR Spectroscopy of Adsorbates on Ultrathin Metal Films Phys. Status Solidi B 2005, 242, 2704-2713 10.1002/pssb.200541131
46. Kumar, N.; Thomas, S.; Tokas, R. B.; Kshirsagar, R. J. SEIRA Studies of Uracil Adsorbed on Wet-Chemically Prepared Gold Nanoparticles Film on Glass Substrate-Effect of Morphology of Film Spectrochim. Acta, Part A 2014, 129, 359-364 10.1016/j.saa.2014.03.062
47. Hatta, A.; Suzuki, Y.; Suëtaka, W. Infrared Absorption Enhancement of Monolayer Species on Thin Evaporated Ag Films by Use of a Kretschmann Configuration: Evidence for Two Types of Enhanced Surface Electric Fields Appl. Phys. A: Solids Surf. 1984, 35, 135-140 10.1007/BF00616965
48. Hatta, A.; Chiba, Y.; Suëtaka, W. Infrared Absorption Study of Adsorbed Species at Metal/Water Interface by Use of the Kretschmann Configuration Surf. Sci. Lett. 1985, 158, A437 10.1016/0167-2584(85)90052-0
49. Suzuki, Y.; Osawa, M.; Hatta, A.; Suëtaka, W. Mechanism of Absorption Enhancement in Infrared ATR Spectra Observed in the Kretschmann Configuration Appl. Surf. Sci. 1988, 33-34, 875-881 10.1016/0169-4332(88)90393-5
50. Kaneko, F.; Miyamoto, H.; Kobayashi, M. Polarized Infrared Attenuated Total Reflection Spectroscopy for Three-Dimensional Structural Analysis on Long-Chain Compounds J. Chem. Phys. 1996, 105, 4812 10.1063/1.472318
51. Hao, E.; Schatz, G. C. Electromagnetic Fields around Silver Nanoparticles and Dimers J. Chem. Phys. 2004, 120, 357-366 10.1063/1.1629280
52. Huck, C.; Neubrech, F.; Vogt, J.; Toma, A.; Gerbert, D.; Katzmann, J.; Härtling, T.; Pucci, A. Surface-Enhanced Infrared Spectroscopy Using Nanometer-Sized Gaps ACS Nano 2014, 8, 4908-4914 10.1021/nn500903v
53. Siegel, J.; Lyutakov, O.; Rybka, V.; Kolská, Z.; Svorčík, V. Properties of Gold Nanostructures Sputtered on Glass Nanoscale Res. Lett. 2011, 6, 96 10.1186/1556-276X-6-96
54. Sönnichsen, C.; Geier, S.; Hecker, N. E.; von Plessen, G.; Feldmann, J.; Ditlbacher, H.; Lamprecht, B.; Krenn, J. R.; Aussenegg, F. R.; Chan, V. Z.-H. Z.-H. et al. Spectroscopy of Single Metallic Nanoparticles Using Total Internal Reflection Microscopy Appl. Phys. Lett. 2000, 77, 2949-2951 10.1063/1.1323553
55. Osawa, M.; Ikeda, M. Surface-Enhanced Infrared Absorptlon of p-Nitrobenzole Acid Deposited on Silver Island Fllms: Contributions of Electromagnetic and Chemical Mechanisms J. Phys. Chem. 1991, 95, 9914-9919 10.1021/j100177a056
56. Chen, C.-F.; Tzeng, S.-D.; Chen, H.-Y.; Lin, K.-J.; Gwo, S. Tunable Plasmonic Response from Alkanethiolate-Stabilized Gold Nanoparticle Superlattices: Evidence of Near-Field Coupling J. Am. Chem. Soc. 2008, 130, 824-826 10.1021/ja0773610
57. Maier, S.; Brongersma, M.; Kik, P.; Atwater, H. Observation of Near-Field Coupling in Metal Nanoparticle Chains Using Far-Field Polarization Spectroscopy Phys. Rev. B: Condens. Matter Mater. Phys. 2002, 65, 193408 10.1103/PhysRevB.65.193408
58. Wang, X.; Gogol, P.; Cambril, E.; Palpant, B. Near- and Far-Field E Ff Ects on the Plasmon Coupling in Gold Nanoparticle Arrays J. Phys. Chem. C 2012, 116, 24741-24747 10.1021/jp306292r
59. Sambles, J.; Bradbery, G.; Yang, F. Optical Excitation of Surface Plasmons: An Introduction Contemp. Phys. 1991, 32, 173-183 10.1080/00107519108211048
60. Barnes, W. L.; Dereux, A.; Ebbesen, T. W. Surface Plasmon Subwavelength Optics Nature 2003, 424, 824-830 10.1038/nature01937
61. Zayats, A.; Smolyaninov, I. Near-Field Photonics: Surface Plasmon Polaritons and Localized Surface Plasmons J. Opt. A: Pure Appl. Opt. 2003, 5, S16-S50 10.1088/1464-4258/5/4/353
62. Zayats, A. V.; Smolyaninov, I. I.; Maradudin, A. A. Nano-Optics of Surface Plasmon Polaritons Phys. Rep. 2005, 408, 131-314 10.1016/j.physrep.2004.11.001
63. Lis, D.; Cecchet, F. Localized Surface Plasmon Resonances in Nanostructures to Enhance Nonlinear Vibrational Spectroscopies: Towards an Astonishing Molecular Sensitivity Beilstein J. Nanotechnol. 2014, 5, 2275-2292 10.3762/bjnano.5.237
64. Novotny, L.; Hecht, B. Principles of Nano-Optics, 1 st ed.; Cambridge University Press: New York, 2006.
65. Axelrod, D. Total Internal Reflection Fluorescence Microscopy in Cell Biology Traffic 2001, 2, 764-774 10.1034/j.1600-0854.2001.21104.x
66. Hoang, C. V.; Oyama, M.; Saito, O.; Aono, M.; Nagao, T. Monitoring the Presence of Ionic Mercury in Environmental Water by Plasmon-Enhanced Infrared Spectroscopy Sci. Rep. 2013, 3, 1175 10.1038/srep01175
67. Pelton, M.; Aizpurua, J.; Bryant, G. Metal-Nanoparticle Plasmonics Laser Photonics Rev. 2008, 2, 136-159 10.1002/lpor.200810003
68. Lecomte, S.; Matejka, P.; Baron, M. H. Correlation between Surface Enhanced Raman Scattering and Absorbance Changes in Silver Colloids. Evidence for the Chemical Enhancement Mechanism Langmuir 1998, 14, 4373-4377 10.1021/la980094e
69. Merklin, G. T.; Griffiths, P. R. Influence of Chemical Interactions on the Surface-Enhanced Infrared Absorption Spectrometry of Nitrophenols on Copper and Silver Films Langmuir 1997, 13, 6159-6163 10.1021/la960828s
70. Osawa, M. Dynamic Processes in Electrochemical Reactions Studied by Surface-Enhanced Infrared Absorption Spectroscopy (SEIRAS) Bull. Chem. Soc. Jpn. 1997, 70, 2861-2880 10.1246/bcsj.70.2861
71. Jiang, X.; Zaitseva, E.; Schmidt, M.; Siebert, F.; Engelhard, M.; Schlesinger, R.; Ataka, K.; Vogel, R.; Heberle, J. Resolving Voltage-Dependent Structural Changes of a Membrane Photoreceptor by Surface-Enhanced IR Difference Spectroscopy Proc. Natl. Acad. Sci. U. S. A. 2008, 105, 12113-12117 10.1073/pnas.0802289105
72. Merklin, G. T.; Griffiths, P. R. Effect of Microscopic Surface Roughness in Surface-Enhanced Infrared Absorption Spectrometry J. Phys. Chem. B 1997, 101, 5810-5813 10.1021/jp962635j
73. Voronine, D. V.; Sinyukov, A. M.; Hua, X.; Munusamy, E.; Ariunbold, G.; Sokolov, A. V.; Scully, M. O. Complex Line Shapes in Surface-Enhanced Coherent Raman Spectroscopy J. Mod. Opt. 2015, 62, 90-96 10.1080/09500340.2014.960018
74. Alonso-González, P.; Albella, P.; Schnell, M.; Chen, J.; Huth, F.; García-Etxarri, A.; Casanova, F.; Golmar, F.; Arzubiaga, L.; Hueso, L. E. et al. Resolving the Electromagnetic Mechanism of Surface-Enhanced Light Scattering at Single Hot Spots Nat. Commun. 2012, 3, 684 10.1038/ncomms1674
75. Neubrech, F.; Pucci, A. Plasmonic Enhancement of Vibrational Excitations in the Infrared IEEE J. Sel. Top. Quantum Electron. 2013, 19, 4600809-4600809 10.1109/JSTQE.2012.2227302
76. Abb, M.; Wang, Y.; Papasimakis, N.; De Groot, C. H.; Muskens, O. L. Surface-Enhanced Infrared Spectroscopy Using Metal Oxide Plasmonic Antenna Arrays Nano Lett. 2014, 14, 346-352 10.1021/nl404115g
77. Vogt, J.; Huck, C.; Neubrech, F.; Toma, A.; Gerbert, D.; Pucci, A. Impact of the Plasmonic Near- and Far-Field Resonance-Energy Shift on the Enhancement of Infrared Vibrational Signals Phys. Chem. Chem. Phys. 2015, 17, 21169-21175 10.1039/C4CP04851B
78. Renger, J.; Quidant, R.; Novotny, L. Enhanced Nonlinear Response from Metal Surfaces Opt. Express 2011, 19, 1777-1785 10.1364/OE.19.001777
79. Aizpurua, J.; Taubner, T.; García de Abajo, F. J.; Brehm, M.; Hillenbrand, R. Substrate-Enhanced Infrared Near-Field Spectroscopy Opt. Express 2008, 16, 1529-1545 10.1364/OE.16.001529
80. Li, M.; Cushing, S. K.; Wu, N. Plasmon-Enhanced Optical Sensors: A Review Analyst 2015, 140, 386-406 10.1039/C4AN01079E
81. Demekhin, P. V.; Cederbaum, L. S. Dynamic Interference of Photoelectrons Produced by High-Frequency Laser Pulses Phys. Rev. Lett. 2012, 108, 253001 10.1103/PhysRevLett.108.253001
82. Autler, S. H.; Townes, C. H. Stark Effect in Rapidly Varying Fields Phys. Rev. 1955, 100, 703-722 10.1103/PhysRev.100.703
83. Rahn, L. A.; Farrow, R. L.; Koszykowski, M. L.; Mattern, P. L. Observation of an Optical Stark Effect on Vibrational and Rotational Transitions Phys. Rev. Lett. 1980, 45, 620-623 10.1103/PhysRevLett.45.620
84. Yamakata, A.; Uchida, T.; Kubota, J.; Osawa, M. Laser-Induced Potential Jump at the Electrochemical Interface Probed by Picosecond Time-Resolved Surface-Enhanced Infrared Absorption Spectroscopy J. Phys. Chem. B 2006, 110, 6423-6427 10.1021/jp060387d
85. Bandara, A.; Kubota, J.; Onda, K.; Wada, A.; Kano, S. S.; Domen, K.; Hirose, C. Short-Lived Reactive Intermediate in the Decomposition of Formate on NiO(111) Surface Observed by Picosecond Temperature Jump J. Phys. Chem. B 1998, 102, 5951-5954 10.1021/jp9816364
86. Bonn, M. Phonon- Versus Electron-Mediated Desorption and Oxidation of CO on Ru(0001) Science (Washington, DC, U. S.) 1999, 285, 1042-1045 10.1126/science.285.5430.1042
87. Funk, S.; Bonn, M.; Denzler, D. N.; Hess, C.; Wolf, M.; Ertl, G. Desorption of CO from Ru(001) Induced by Near-Infrared Femtosecond Laser Pulses J. Chem. Phys. 2000, 112, 9888-9897 10.1063/1.481626
88. El Khoury, Y.; van Wilderen, L. J. G. W.; Bredenbeck, J. Ultrafast 2D-IR Spectroelectrochemistry of Flavin Mononucleotide J. Chem. Phys. 2015, 142, 212416 10.1063/1.4916916
89. Miyake, H.; Osawa, M. Surface-Enhanced Infrared Spectrum of CO Adsorbed on Cu Electrodes in Solution Chem. Lett. 2004, 33, 278-279 10.1246/cl.2004.278
90. Osawa, M.; Tsushima, M.; Mogami, H.; Samjeske, G.; Yamakata, A. Structure of Water at the Electrified Platinum-Water Interface: A Study by Surface-Enhanced Infrared Absorption Spectroscopy J. Phys. Chem. C 2008, 112, 4248-4256 10.1021/jp710386g
91. Kunimatsu, K.; Senzaki, T.; Tsushima, M.; Osawa, M. A Combined Surface-Enhanced Infrared and Electrochemical Kinetics Study of Hydrogen Adsorption and Evolution on a Pt Electrode Chem. Phys. Lett. 2005, 401, 451-454 10.1016/j.cplett.2004.11.100
92. Rosenfeld, D. E.; Nishida, J.; Yan, C.; Kumar, S. K. K.; Tamimi, A.; Fayer, M. D. Structural Dynamics at Monolayer-Liquid Interfaces Probed by 2D IR Spectroscopy J. Phys. Chem. C 2013, 117, 1409-1420 10.1021/jp311144b