Dehydration of Ions in Voltage-Gated Carbon Nanopores Observed by in Situ NMR

Journal of Physical Chemistry Letters

Volumn 6, Issue 24, 2015, Pages 5022-5026

  Luo, Zhi Xiang ^a   Xing, Yun Zhao ^b   Liu, Shubin ^a   Ling, Yan Chun ^b   Kleinhammes, Alfred ^a   Wu, Yue ^a,b  

^a UNIVERSITY OF NORTH CAROLINA   (United States)

^b University of North Carolina at Chapel Hill   (United States)

Author keywords

carbon nanopores; nanoconfinement; NICS; supercapacitor; voltage gated

Indexed keywords

CAPACITORS; CHEMICAL SHIFT; DEHYDRATION; ELECTRIC ENERGY STORAGE; ELECTROLYTES; ELECTROLYTIC CAPACITORS; HYDRATION; NANOPORES; NUCLEAR MAGNETIC RESONANCE; RECONFIGURABLE HARDWARE;

CARBON NANOPORES; CARBON SUPERCAPACITORS; MICROSCOPIC OBSERVATIONS; NANOCONFINEMENTS; NICS; NUCLEAR MAGNETIC RESONANCE STUDIES; NUCLEUS INDEPENDENT CHEMICAL SHIFTS; SUPER CAPACITOR;

IONS;

EID: 84952790452     PISSN: None     EISSN: 19487185     Source Type: Journal    
DOI: 10.1021/acs.jpclett.5b02208     Document Type: Article

References (47)

1. Kunz, W.; Lo Nostro, P.; Ninham, B. W. The Present State of Affairs with Hofmeister Effects Curr. Opin. Colloid Interface Sci. 2004, 9, 1-18 10.1016/j.cocis.2004.05.004
2. Kunz, W. Specific Ion Effects; World Scientific: Singapore, 2010.
3. Daiguji, H.; Yang, P.; Majumdar, A. Ion Transport in Nanofluidic Channels Nano Lett. 2004, 4, 137-142 10.1021/nl0348185
4. Duan, C.; Majumdar, A. Anomalous Ion Transport in 2-nm Hydrophilic Nanochannels Nat. Nanotechnol. 2010, 5, 848-852 10.1038/nnano.2010.233
5. Holt, J. K.; Park, H. G.; Wang, Y.; Stadermann, M.; Artyukhin, A. B.; Grigoropoulos, C. P.; Noy, A.; Bakajin, O. Fast Mass Transport through Sub-2-nanometer Carbon Nanotubes Science 2006, 312, 1034-1037 10.1126/science.1126298
6. Dutzler, R.; Campbell, E. B.; MacKinnon, R. Gating the Selectivity Filter in CIC Chloride Channels Science 2003, 300, 108-112 10.1126/science.1082708
7. Noskov, S. Y.; Berneche, S.; Roux, B. Control of Ion Selectivity in Potassium Channels by Electrostatic and Dynamic Properties of Carbonyl Ligands Nature 2004, 431, 830-834 10.1038/nature02943
8. Gouaux, E.; MacKinnon, R. Principles of Selective Ion Transport in Channels and Pumps Science 2005, 310, 1461-1465 10.1126/science.1113666
9. + Channel-Fab Complex at 2.0 Angstrom Resolution Nature 2001, 414, 43-48 10.1038/35102009
10. Conway, B. Electrochemical Supercapacitors: Scientific Fundamentals and Technological Applications; Kluwer Academic/Plenum: New York, 1999.
11. Chmiola, J.; Yushin, G.; Gogotsi, Y.; Portet, C.; Simon, P.; Taberna, P. L. Anomalous Increase in Carbon Capacitance at Pore Sizes Less Than 1 Nanometer Science 2006, 313, 1760-1763 10.1126/science.1132195
12. Chmiola, J.; Largeot, C.; Taberna, P.-L.; Simon, P.; Gogotsi, Y. Desolvation of Ions in Subnanometer Pores and Its Effect on Capacitance and Double-Layer Theory Angew. Chem. 2008, 120, 3440-3443 10.1002/ange.200704894
13. Huang, J.; Sumpter, B. G.; Meunier, V. Theoretical Model for Nanoporous Carbon Supercapacitors Angew. Chem., Int. Ed. 2008, 47, 520-524 10.1002/anie.200703864
14. Beckstein, O.; Tai, K.; Sansom, M. S. Not Ions Alone: Barriers to Ion Permeation in Nanopores and Channels J. Am. Chem. Soc. 2004, 126, 14694-14695 10.1021/ja045271e
15. Allen, T. W.; Andersen, O. S.; Roux, B. Energetics of Ion Conduction through the Gramicidin Channel Proc. Natl. Acad. Sci. U. S. A. 2004, 101, 117-122 10.1073/pnas.2635314100
16. Richards, L. A.; Schäfer, A. I.; Richards, B. S.; Corry, B. The Importance of Dehydration in Determining Ion Transport in Narrow Pores Small 2012, 8, 1701-1709 10.1002/smll.201102056
17. Song, C.; Corry, B. Intrinsic Ion Selectivity of Narrow Hydrophobic Pores J. Phys. Chem. B 2009, 113, 7642-7649 10.1021/jp810102u
18. Aryal, P.; Abd-Wahab, F.; Bucci, G.; Sansom, M. S.; Tucker, S. J. A Hydrophobic Barrier Deep within the Inner Pore of the TWIK-1 K2P Potassium Channel Nat. Commun. 2014, 5, 4377 10.1038/ncomms5377
19. Ohba, T.; Hata, K.; Kanoh, H. Significant Hydration Shell Formation Instead of Hydrogen Bonds in Nanoconfined Aqueous Electrolyte Solutions J. Am. Chem. Soc. 2012, 134, 17850-17853 10.1021/ja307338t
20. Ohkubo, T.; Konishi, T.; Hattori, Y.; Kanoh, H.; Fujikawa, T.; Kaneko, K. Restricted Hydration Structures of Rb and Br Ions Confined in Slit-Shaped Carbon Nanospace J. Am. Chem. Soc. 2002, 124, 11860-11861 10.1021/ja027144t
21. Yamakata, A.; Soeta, E.; Ishiyama, T.; Osawa, M.; Morita, A. Real-Time Observation of the Destruction of Hydration Shells under Electrochemical Force J. Am. Chem. Soc. 2013, 135, 15033-15039 10.1021/ja408326d
22. Yamakata, A.; Osawa, M. Destruction of the Hydration Shell around Tetraalkylammonium Ions at the Electrochemical Interface J. Am. Chem. Soc. 2009, 131, 6892-6893 10.1021/ja8100374
23. Xing, Y.-Z.; Luo, Z.-X.; Kleinhammes, A.; Wu, Y. Probing Carbon Micropore Size Distribution by Nucleus Independent Chemical Shift Carbon 2014, 77, 1132-1139 10.1016/j.carbon.2014.06.031
24. Luo, Z.-X.; Xing, Y.-Z.; Ling, Y.-C.; Kleinhammes, A.; Wu, Y. Electroneutrality Breakdown and Specific Ion Effects in Nanoconfined Aqueous Electrolytes Observed by NMR Nat. Commun. 2015, 6, 6358 10.1038/ncomms7358
25. Forse, A. C.; Griffin, J. M.; Merlet, C.; Bayley, P. M.; Wang, H.; Simon, P.; Grey, C. P. NMR Study of Ion Dynamics and Charge Storage in Ionic Liquid Supercapacitors J. Am. Chem. Soc. 2015, 137, 7231 10.1021/jacs.5b03958
26. Griffin, J. M.; Forse, A. C.; Tsai, W.-Y.; Taberna, P.-L.; Simon, P.; Grey, C. P. In Situ NMR and Electrochemical Quartz Crystal Microbalance Techniques Reveal the Structure of the Electrical Double Layer in Supercapacitors Nat. Mater. 2015, 14, 812 10.1038/nmat4318
27. Van Geet, A. L. Hydration Number of Sodium Ions Determined by Sodium Magnetic-Resonance J. Am. Chem. Soc. 1972, 94, 5583 10.1021/ja00771a009
28. 19F NMR Shifts Are Not a Measure for the Nakedness of the Fluoride Anion J. Fluorine Chem. 2002, 116, 49-58 10.1016/S0022-1139(02)00101-X
29. Van Geet, A. L. Hydration Number of Sodium Ions Determined by Sodium Magnetic Resonance J. Am. Chem. Soc. 1972, 94, 5583-5587 10.1021/ja00771a009
30. Laszlo, P. Sodium-23 Nuclear Magnetic Resonance Spectroscopy Angew. Chem., Int. Ed. Engl. 1978, 17, 254-266 10.1002/anie.197802541
31. Wang, H.; Forse, A. C.; Griffin, J. M.; Trease, N. M.; Trognko, L.; Taberna, P.-L.; Simon, P.; Grey, C. P. In Situ NMR Spectroscopy of Supercapacitors: Insight into the Charge Storage Mechanism J. Am. Chem. Soc. 2013, 135, 18968-18980 10.1021/ja410287s
32. Deschamps, M.; Gilbert, E.; Azais, P.; Raymundo-Pinero, E.; Ammar, M. R.; Simon, P.; Massiot, D.; Béguin, F. Exploring Electrolyte Organization in Supercapacitor Electrodes with Solid-State NMR Nat. Mater. 2013, 12, 351 10.1038/nmat3567
33. Ilott, A. J.; Trease, N. M.; Grey, C. P.; Jerschow, A. Multinuclear in Situ Magnetic Resonance Imaging of Electrochemical Double-Layer Capacitors Nat. Commun. 2014, 5, 4536 10.1038/ncomms5536
34. Wang, H.; Köster, T. K. J.; Trease, N. M.; Ségalini, J.; Taberna, P.-L.; Simon, P.; Gogotsi, Y.; Grey, C. P. Real-Time NMR Studies of Electrochemical Double-Layer Capacitors J. Am. Chem. Soc. 2011, 133, 19270-19273 10.1021/ja2072115
35. Forse, A. C.; Griffin, J. M.; Presser, V.; Gogotsi, Y.; Grey, C. P. Ring Current Effects: Factors Affecting the NMR Chemical Shift of Molecules Adsorbed on Porous Carbons J. Phys. Chem. C 2014, 118, 7508-7514 10.1021/jp502387x
36. Forse, A. C.; Griffin, J. M.; Wang, H.; Trease, N. M.; Presser, V.; Gogotsi, Y.; Simon, P.; Grey, C. P. Nuclear Magnetic Resonance Study of Ion Adsorption on Microporous Carbide-Derived Carbon Phys. Chem. Chem. Phys. 2013, 15, 7722 10.1039/c3cp51210j
37. Cansado, I.; Gonçalves, F.; Carrott, P.; Ribeiro Carrott, M. High Micropore Activated Carbon Prepared from Polyetheretherketone Carbon 2007, 45, 2454-2455 10.1016/j.carbon.2007.07.004
38. Cansado, I. P.; Gonçalves, F.; Nabais, J.; Ribeiro Carrott, M.; Carrott, P. Peek: An Excellent Precursor for Activated Carbon Production for High Temperature Application Fuel Process. Technol. 2009, 90, 232-236 10.1016/j.fuproc.2008.09.001
39. 2 Storage in Microporous Carbons from PEEK Precursors J. Phys. Chem. C 2010, 114, 13902-13908 10.1021/jp102178z
40. Israelachvili, J. N. Intermolecular and Surface Forces, 3 rd ed.; Academic Press: Waltham, MA, 2011.
41. Ramaniah, L. M.; Bernasconi, M.; Parrinello, M. Density-Functional Study of Hydration of Sodium in Water Clusters J. Chem. Phys. 1998, 109, 6839-6843 10.1063/1.477250
42. Novoselov, K. S.; Geim, A. K.; Morozov, S. V.; Jiang, D.; Zhang, Y.; Dubonos, S. V.; Grigorieva, I. V.; Firsov, A. A. Electric Field Effect in Atomically Thin Carbon Films Science 2004, 306, 666-669 10.1126/science.1102896
43. Das, A.; Pisana, S.; Chakraborty, B.; Piscanec, S.; Saha, S. K.; Waghmare, U. V.; Novoselov, K. S.; Krishnamurthy, H. R.; Geim, A. K.; Ferrari, A. C.; Sood, A. K. Monitoring Dopants by Raman Scattering in an Electrochemically Top-Gated Graphene Transistor Nat. Nanotechnol. 2008, 3, 210-215 10.1038/nnano.2008.67
44. Xia, J.; Chen, F.; Li, J.; Tao, N. Measurement of the Quantum Capacitance of Graphene Nat. Nanotechnol. 2009, 4, 505-509 10.1038/nnano.2009.177
45. Gerischer, H. An Interpretation of the Double Layer Capacity of Graphite Electrodes in Relation to the Density of States at the Fermi Level J. Phys. Chem. 1985, 89, 4249-4251 10.1021/j100266a020
46. Randin, J.-P.; Yeager, E. Differential Capacitance Study on the Basal Plane of Stress-Annealed Pyrolytic Graphite J. Electroanal. Chem. Interfacial Electrochem. 1972, 36, 257-276 10.1016/S0022-0728(72)80249-3
47. Gerischer, H.; McIntyre, R.; Scherson, D.; Storck, W. Density of the Electronic States of Graphite: Derivation from Differential Capacitance Measurements J. Phys. Chem. 1987, 91, 1930-1935 10.1021/j100291a049