A retro Diels-Alder route to diphosphorus chemistry: Molecular precursor synthesis, kinetics of P2transfer to 1,3-dienes, and detection of P2by molecular beam mass spectrometry

Journal of the American Chemical Society

Volumn 136, Issue 39, 2014, Pages 13586-13589

  Velian, Alexandra ^a   Nava, Matthew ^a   Temprado, Manuel ^b   Zhou, Yan ^a   Field, Robert W ^a   Cummins, Christopher C ^a  

^a MASSACHUSETTS INSTITUTE OF TECHNOLOGY   (United States)

^b UNIVERSITY OF ALCALÁ   (Spain)

Author keywords

[No Author keywords available]

Indexed keywords

ANTHRACENE; CHEMICAL ACTIVATION; ETHYLENE; MASS SPECTROMETRY; PLATINUM; X RAY DIFFRACTION;

1 ,3-CYCLOHEXADIENE; COMPUTATIONAL THERMODYNAMICS; DISSOCIATIVE PATHWAYS; MOLECULAR BEAM MASS SPECTROMETRIES; MOLECULAR FRAGMENTS; MOLECULAR PRECURSOR; REACTIVE INTERMEDIATE; THERMAL ACTIVATION;

MOLECULAR BEAMS;

1,3 BUTADIENE; 1,3 DIENE; ALKADIENE; ANTHRACENE; UNCLASSIFIED DRUG;

ARTICLE; CHEMICAL PARAMETERS; CHEMICAL REACTION KINETICS; CRYSTAL STRUCTURE; DIELS ALDER REACTION; MASS SPECTROMETRY; MOLECULAR BEAM MASS SPECTROMETRY; MOLECULE; SYNTHESIS; THERMODYNAMICS; TIGHT JUNCTION; X RAY DIFFRACTION;

EID: 84949115830     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/ja507922x     Document Type: Article

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