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4 was exposed to visible light up to 100 °C, red phosphorus was found to be the main product
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0001403481
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-1 at 254 nm
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34250428521
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max for 1,3-cyclohexadiene is at 258 nm, while that for DMB is at 228 nm for CHD see
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The intense absorption of 1,3-cyclohexadiene at 254 nm likely acts as a filter that inhibits P4 photolysis. The first λmax for 1,3-cyclohexadiene is at 258 nm, while that for DMB is at 228 nm for CHD see : Y. G. Dubinskii, M. I. Rozengart, B. A. Kazanskii, Russ. Chem. Bull. 1972, 21, 1193;
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0003520774
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77957602473
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See the Supporting Information for further details
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See the Supporting Information for further details.
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20
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0034703716
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77957579829
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CCDC 783707 (1) and 7 83708 (2) contain the supplementary crystallographic data for this paper. These data can be obtained free of charge from The Cambridge Crystallographic Data Centre via
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CCDC 783707 (1) and 783708 (2) contain the supplementary crystallographic data for this paper. These data can be obtained free of charge from The Cambridge Crystallographic Data Centre via www.ccdc.cam.ac.uk/data-request/cif.
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22
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77957599510
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note
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2, separation of the pure isomer mixture from other impurities has been unsuccessful so far. NMR spectra of crude samples are provided in the Supporting Information.
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23
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77957600452
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The signal for the non-olefinic protons is reported to split into a multiplet below -75 °C
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The signal for the non-olefinic protons is reported to split into a multiplet below -75 °C;
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