Ionic transport in nano-porous clays with consideration of electrostatic effects

Reviews in Mineralogy and Geochemistry

Volumn 80, Issue 1, 2015, Pages 287-329

  Tournassat, Christophe ^a,b   Steefel, Carl I ^a  

^a LAWRENCE BERKELEY NATIONAL LABORATORY   (United States)

^b BRGM   (France)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 84948671213     PISSN: 15296466     EISSN: None     Source Type: Book Series    
DOI: 10.2138/rmg.2015.80.09     Document Type: Article

References (128)

1. Aldaba D, Rigol A, Vidal M (2010) Diffusion experiments for estimating radiocesium and radiostrontium sorption in unsaturated soils from Spain: Comparison with batch sorption data. J Hazard Mater 181:1072-1079
2. Alt-Epping P, Tournassat C, Rasouli P, Steefel CI, Mayer KU, Jenni A, Mäder U, Sengor SS, Fernández R (2014) Benchmark reactive transport simulations of a column experiment in compacted bentonite with multispecies diffusion and explicit treatment of electrostatic effects. Computat Geosci 1-16
3. Altmann S (2008) Geochemical research: A key building block for nuclear waste disposal safety cases. J Contam Hydrol 102:174-179
4. Anderson RL, Ratcliffe I, Greenwell HC, Williams PA, Cliffe S, Coveney PV (2010) Clay swelling-a challenge in the oilfield. Earth-Sci Rev 98:201-216
5. Appelo CAJ, Wersin P (2007) Multicomponent diffusion modeling in clay systems with application to the diffusion of tritium, iodide, and sodium in Opalinus clay. Env Sci Tech 41:5002-5007
6. Appelo CAJ, Vinsot A, Mettler S, Wechner S (2008) Obtaining the porewater composition of a clay rock by modeling the in- and out-diffusion of anions and cations from an in-situ experiment. J Contam Hydrol 101:67-76
7. Appelo CAJ, Van Loon LR, Wersin P (2010) Multicomponent diffusion of a suite of tracers (HTO, Cl, Br, I, Na, Sr, Cs) in a single sample of Opalinus Clay. Geochim Cosmochim Acta 74:1201-1219
8. Banin A, Lahav N (1968) particle size and optical properties of montmorillonite in suspension. Isr J Chem 6:235-250
9. Bear J (1972) Dynamics of Fluids in Porous Media. Courier Dover Publications
10. Ben-Yaakov S (1981) Diffusion of seawater ions: Significance and consequences of cross-coupling effects. Am J Sci 281:974-980
11. Benna M, Kbir-Ariguib N, Clinard C, Bergaya F (2002) Card-house microstructure of purified sodium montmorillonite gels evidenced by filtration properties at different pH. In: Adsorption and Nanostructure. Springer, p 204-210
12. Bergaya F (1995) The meaning of surface area and porosity measurements of clays and pillared clays. Journal of Porous Materials 2:91-96
13. Bickmore B, Nagy KL, Sandlin PE, Crater TS (2002) Quantifying surface areas of clays by atomic force microscopy. Am Mineral 87:780-783
14. Birgersson M, Karnland O (2009) Ion equilibrium between montmorillonite interlayer space and an external solution-Consequences for diffusional transport. Geochim Cosmochim Acta 73:1908-1923
15. Boudreau BP, Meysman FJ, Middelburg JJ (2004) Multicomponent ionic diffusion in porewaters: Coulombic effects revisited. Earth Planet Sci Lett 222:653-666
16. Bourg IC, Sposito G (2010) Connecting the molecular scale to the continuum scale for diffusion processes in smectite-rich porous media. Env Sci Tech 44:2085-2091
17. 2) solutions. J Colloid Interface Sci 360:701-715
18. Bradbury MH, Baeyens B (2000) A generalised sorption model for the concentration dependent uptake of caesium by argillaceous rocksbae. J Contam Hydrol 42:141-163
19. Bradbury MH, Baeyens B (2005) Modelling the sorption of Mn (II), Co (II), Ni (II), Zn (II), Cd (II), Eu (III), Am (III), Sn (IV), Th (IV), Np (V) and U (VI) on montmorillonite: Linear free energy relationships and estimates of surface binding constants for some selected heavy metals and actinides. Geochim Cosmochim Acta 69:875-892
20. Brigatti MF, Galán E, Theng BKG (2013) Structure and Mineralogy of Clay Minerals. In: Handbook of Clay Science, Developments in Clay Science. Bergaya F, Lagaly G (eds) Elsevier, p 21-81
21. Brouwer E, Baeyens B, Maes A, Cremers A (1983) Cesium and Rubidium ion equilibria in illite clay. J Phys Chem 87:1213-1219
22. Chen Z, Montavon G, Ribet S, Guo Z, Robinet J, David K, Tournassat C, Grambow B, Landesman C (2014) Key factors to understand in-situ behavior of Cs in Callovo-Oxfordian clay-rock (France). Chem Geol 387:47-58
23. Chu SY, Sposito G (1981) The thermodynamics of ternary cation exchange systems and the subregular model. Soil Sci Soc Am J 45:1084-1089
24. Churakov S V, Gimmi T (2011) Up-scaling of molecular diffusion coefficients in clays: A two-step approach. J Phys Chem C 115:6703-6714
25. Churakov SV, Gimmi T, Unruh T, Van Loon LR, Juranyi F (2014) Resolving diffusion in clay minerals at different time scales: Combination of experimental and modeling approaches. Appl Clay Sci 96:36-44
26. De Carvalho Balaban R, Vidal ELF, Borges MR (2015) Design of experiments to evaluate clay swelling inhibition by different combinations of organic compounds and inorganic salts for application in water base drilling fluids. Appl Clay Sci 105-106:124-130
27. Delay J, Trouiller A, Lavanchy J-M (2006) Propriétés hydrodynamiques du Callovo-Oxfordien dans l'Est du bassin de Paris: comparaison des résultats obtenus selon différentes approches. C R Geosci 338:892-907
28. Delay J, Bossart P, Ling LX, Blechschmidt I, Ohlsson M, Vinsot A, Nussbaum C, Maes N (2014) Three decades of underground research laboratories: what have we learned? Geological Society, London, Special Publications 400, p 7-32
29. Delgado A, Gonzalez-Caballero F, Bruque JM (1986) On the zeta potential and surface charge density of montmorillonite in aqueous electrolyte solutions. J Colloid Interface Sci 113:203-211
30. Delgado A, Gonzalez-Caballero F, Salcedo J, Cabrerizo MA (1988) A study of the electrophoretic properties of montmorillonite particles in aqueous electrolyte solutions. Mater Chem Phys 19:327-340
31. Descostes M, Blin V, Bazer-Bachi F, Meier P, Grenut B, Radwan J, Schlegel ML, Buschaert S, Coelho D, Tevissen E (2008) Diffusion of anionic species in Callovo-Oxfordian argillites and Oxfordian limestones (Meuse/Haute-Marne, France). Appl Geochem 23:655-677
32. Dzombak DA, Hudson RJM (1995) Ion-exchange: the contributions of diffuse layer sorption and surface complexation. In: Aquatic Chemistry. Interfacial and Interspecies Processes. Advances in Chemistry Series 244. Huan CP, O'Melia C, Morgan JJ (eds) Am Chem Soc, Washington, p 59-94
33. Fernández AM, Sánchez-Ledesma DM, Tournassat C, Melón A, Gaucher EC, Astudillo J, Vinsot A (2014) Applying the squeezing technique to highly Consolidated clayrocks for pore water characterisation: Lessons learned from experiments at the Mont Terri Rock Laboratory. Appl Geochem 49:2-21
34. Gaboreau S, Claret F, Crouzet C, Giffaut E, Tournassat C (2012) Caesium uptake by Callovian-Oxfordian clayrock under alkaline perturbation. Appl Geochem 27:1194-1201
35. Gaines GLJ, Thomas HC (1953) Adsorption studies on clay minerals. II. A formulation of the thermodynamics of exchange adsorption. J Chem Phys 21:714-718
36. Gapon EN (1933) On the theory of exchange adsorption in soils. J. Gen. Chem. USSR (Engl. Transl.) 3:144-160
37. 36Cl in compacted FEBEX bentonite. Appl Clay Sci 26:65-73
38. Garrels RM, Mackenzie FT (1971) Evolution of sedimentary rocks. WW Norton & Co, New York
39. Gimmi T, Kosakowski G (2011) How mobile are sorbed cations in clays and clay rocks? Env Sci Tech 45:1443-1449
40. 85Sr in montmorillonite: evidence of interlayer diffusion being the dominant pathway at high compaction. Environ Sci Technol 41:478-485
41. Glaus MA, Rosse R, Van Loon LR, Yaroshchuk AE (2008) Tracer Diffusion in Sintered Stainless Steel Filters: Measurement of Effective Diffusion Coefficients and Implications for Diffusion Studies with Compacted Clays. Clays Clay Miner 56:677-685
42. Glaus MA, Frick S, Rosse R, Van Loon LR (2010) Comparative study of tracer diffusion of HTO, Na-22 (+) and Cl-36 (-) in compacted kaolinite, illite and montmorillonite. Geochim Cosmochim Acta 74:1999-2010
43. + in compacted montmorillonite. Env Sci Tech 47:11522-11527
44. Gonçalvès J, Rousseau-Gueutin P, Revil A (2007) Introducing interacting diffuse layers in TLM calculations: A reappraisal of the influence of the pore size on the swelling pressure and the osmotic efficiency of compacted bentonites. J Colloid Interface Sci 316:92-99
45. Gu XY, Evans LJ, Barabash SJ (2010) Modeling the adsorption of Cd (II), Cu (II), Ni (II), Pb (II) and Zn (II) onto montmorillonite. Geochim Cosmochim Acta 74:5718-5728
46. Hemes S, Desbois G, Urai JL, De Craen M, Honty M (2013) Variations in the morphology of porosity in the Boom Clay Formation: insights from 2D high resolution BIB-SEM imaging and Mercury injection Porosimetry. Neth J Geosci 92:275-300
47. Holmboe M, Bourg IC (2014) Molecular dynamics simulations of water and sodium diffusion in smectite interlayer nanopores as a function of pore size and temperature. J Phys Chem C 118:1001-1013
48. Holmboe M, Wold S, Jonsson M (2012) Porosity investigation of compacted bentonite using XRD profile modeling. J Contam Hydrol 128:19-32
49. Homand F, Shao J-F, Giraud A, Auvray C, Hoxha D (2006) Pétrofabrique et propriétés mécaniques des argilites. C R Geosci 338,: 882-891
50. Jakob A, Pfingsten W, Van Loon LR (2009) Effects of sorption competition on caesium diffusion through compacted argillaceous rock. Geochim Cosmochim Acta 73:2441-2456
51. Jardat M, Dufreche JF, Marry V, Rotenberg B, Turq P (2009) Salt exclusion in charged porous media: a coarsegraining strategy in the case of montmorillonite clays. Phys Chem Chem Phys 11:2023-2033
52. Keller LM, Holzer L, Wepf R, Gasser P (2011) 3D geometry and topology of pore pathways in Opalinus clay: Implications for mass transport. Appl Clay Sci 52:85-95
53. Keller LM, Holzer L, Schuetz P, Gasser P (2013) Pore space relevant for gas permeability in Opalinus clay: Statistical analysis of homogeneity, percolation, and representative volume element. J Geophys Res: Solid Earth 118:2799-2812
54. Kulik DA (2009) Thermodynamic concepts in modeling sorption at the mineral-water interface. Rev Mineral Geochem 70:125-180
55. Lagaly G, Dékány I (2013) Chapter 8 - Colloid Clay Science. In: Handbook of Clay Science, Developments in Clay Science. Bergaya, F, Lagaly G (eds) Elsevier p 243-345
56. Lasaga AC (1981) The treatment of multicomponent diffusion and ion pairs in diagenetic fluxes; further comments and clarification; reply. Am J Sci 281:981-988
57. Le Forestier L, Muller F, Villieras F, Pelletier M (2010) Textural and hydration properties of a synthetic montmorillonite compared with a natural Na-exchanged clay analogue. Appl Clay Sci 48:18-25
58. Lee SS, Fenter P, Park C, Sturchio NC, Nagy KL (2010) Hydrated cation speciation at the muscovite (001) - water interface. Langmuir 26:16647-16651
59. Lee SS, Fenter P, Nagy KL, Sturchio NC (2012) Monovalent ion adsorption at the muscovite (001)-solution interface: Relationships among ion coverage and speciation, interfacial water structure, and substrate relaxation. Langmuir 28:8637-8650
60. Leroy P, Revil A, Coelho D (2006) Diffusion of ionic species in bentonite. J Colloid Interface Sci 296:248-255
61. Li Y-H, Gregory S (1974) Diffusion of ions in sea water and in deep-sea sediments. Geochim Cosmochim Acta 38:703-714
62. Maes N, Salah S, Jacques D, Aertsens M, Van Gompel M, De Canniere P, Velitchkova N (2008) Retention of Cs in Boom Clay: Comparison of data from batch sorption tests and diffusion experiments on intact clay cores. Phys Chem Earth, Parts A/B/C 33:S149-S155
63. Marry V, Rotenberg B, Turq P (2008) Structure and dynamics of water at a clay surface from molecular dynamics simulation. Phys Chem Chem Phys 10:4802-4813
64. Marty NCM, Cama J, Sato T, Chino D, Villiéras F, Razafitianamaharavo A, Brendlé J, Giffaut E, Soler JM, Gaucher EC, Tournassat C (2011) Dissolution kinetics of synthetic Na-smectite. An integrated experimental approach. Geochim Cosmochim Acta 75:5849-5864
65. Melkior T, Yahiaoui S, Motellier S, Thoby D, Tevissen E (2005) Cesium sorption and diffusion in Bure mudrock samples. Appl Clay Sci 29:172-186
66. Melkior T, Gaucher EC, Brouard C, Yahiaoui S, Thoby D, Clinard C, Ferrage E, Guyonnet D, Tournassat C, Coelho D (2009) Na+ and HTO diffusion in compacted bentonite: Effect of surface chemistry and related texture. J Hydrol 370:9-20
67. Méring J (1946) On the hydration of montmorillonite. Trans Faraday Soc 42:B205-B219
68. Miller AW, Rodriguez DR, Honeyman BD (2010) Upscaling sorption/desorption processes in reactive transport models to describe metal/radionuclide transport: A critical review. Env Sci Tech 44:7996-8007
69. Miyahara K, Ashida T, Kohara Y, Yusa Y, Sasaki N (1991) Effect of bulk-density on diffusion for cesium in compacted sodium bentonite. Radiochim Acta 52-3:293-297
70. Molins S, Trebotich D, Steefel CI, Shen CP (2012) An investigation of the effect of pore scale flow on average geochemical reaction rates using direct numerical simulation. Water Resour Res 48:WR011404
71. + on MX-80 bentonite; Effect of compaction using the "capillary method". Environ Sci Technol 40:4672-4679
72. Muurinen A, Karnland O, Lehikoinen J (2004) Ion concentration caused by an external solution into the porewater of compacted bentonite. Phys Chem Earth, Parts A/B/C 29:119-127
73. 2O and I-in expandable mica and montmorillonite gels: contribution of bound H2O. Clays Clay Miner 50:1-10
74. Neuzil CE (1986) Groundwater flow in low-permeability environments. Water Resour Res 22:1163-1195
75. Norrish K (1954) The swelling of montmorillonite. Faraday Discuss Chem Soc 18:120-134
76. Obliger A, Duvail M, Jardat M, Coelho D, Békri S, Rotenberg B (2013) Numerical homogenization of electrokinetic equations in porous media using lattice-Boltzmann simulations. Phys Rev E 88:013019
77. Oscarson DW, Hume HB, King F (1994) Sorption of cesium on compacted bentonite. Clays Clay Miner 42:731-736
78. Parkhurst DL, Appelo CAJ (1999) User's guide to PHREEQC (Version 2) - A computer program for speciation, batch-reaction, one-dimensional transport, and inverse geochemical calculations (No. Denver, CO. U. S. Geological Survey. Water Resources Investigations Report p 99-4259.)
79. Parkhurst DL, Appelo C (2013) Description of Input and Examples for PHREEQC Version 3-a Computer Program for Speciation, Batch-reaction, One-dimensional Transport, and Inverse Geochemical Calculations
80. Pearson FJ (1999) What is the porosity of a mudrock? In: Muds and Mudstones: Physical and Fluid Flow Properties. Aplin AC, Fleet AJ, Macquaker JH (eds) Geol Soc Spec Pub, London, p 9-21
81. Pearson FJ, Arcos D, Boisson J-Y, Fernandez AM, Gäbler H-E, Gaucher E, Gautschi A, Griffault L, Hernan P, Waber HN (2003) Mont Terri project - Geochemistry of water in the Opalinus clay formation at the Mont Terri Rock Laboratory. Geology Series No. 5 Swiss Federal Office for Water and Geology, Bern
82. Poinssot C, Baeyens B, Bradbury MH (1999) Experimental and modelling studies of caesium sorption on illite. Geochim Cosmochim Acta 63:3217-3227
83. Reinholdt MX, Hubert F, Faurel M, Tertre E, Razafitianamaharavo A, Francius G, Prêt D, Petit S, Béré E, Pelletier M, Ferrage E (2013) Morphological properties of vermiculite particles in size-selected fractions obtained by sonication. Appl Clay Sci 77:18-32
84. Rotenberg B, Marry V, Dufrêche J-F, Giffaut E, Turq P (2007a) A multiscale approach to ion diffusion in clays: Building a two-state diffusion-reaction scheme from microscopic dynamics. J Colloid Interface Sci 309:289-295
85. Rotenberg B, Marry V, Dufreche J-F, Malikova N, Giffaut E, Turq P (2007b) Modelling water and ion diffusion in clays: A multiscale approach. C R Chim 10:1108-1116
86. Rotenberg B, Marry V, Vuilleumier R, Malikova N, Simon C, Turq P (2007c) Water and ions in clays: Unraveling the interlayer/micropore exchange using molecular dynamics. Geochim Cosmochim Acta 71:5089-5101
87. Rotenberg B, Marry V, Malikova N, Turq P (2010) Molecular simulation of aqueous solutions at clay surfaces. J Phys: Condens Matter 22:284114
88. Rotenberg B, Marry V, Salanne M, Jardat M, Turq P (2014) Multiscale modelling of transport in clays from the molecular to the sample scale. C R Geosci 346:298-306
89. Saiyouri N, Hicher P Y, Tessier D (2000) Microstructural approach and transfer water modelling in highly compacted unsaturated swelling clays. Mech Cohes-Frict Mat 5:41-60
90. Sayed Hassan M, Villieras F, Gaboriaud F, Razafitianamaharavo A (2006) AFM and low-pressure argon adsorption analysis of geometrical properties of phyllosilicates. J Colloid Interface Sci 296:614-623
91. Schramm LL, Kwak JCT (1982a) Influence of exchangeable cation composition on the size and shape of montmorillonite particles in dilute suspension. Clays Clay Miner 30:40-48
92. Schramm LL, Kwak JCT (1982b) Interactions in clay suspensions: The distribution of ions in suspension and the influence of tactoid formation. Colloid Surface 3:43-60
93. Shackelford CD, Moore SM (2013) Fickian diffusion of radionuclides for engineered containment barriers: Diffusion coefficients, porosities, and complicating issues. Eng Geol 152:133-147
94. Shainberg I, Otoh H (1968) Size and shape of montmorillonite particles saturated with Na/Ca ions (inferred from viscosity and optical measurements). Isr J Chem 6:251-259
95. Siretanu I, Ebeling D, Andersson MP, Stipp SS, Philipse A, Stuart MC, Ende D van den, Mugele F (2014) Direct observation of ionic structure at solid-liquid interfaces: a deep look into the Stern Layer. Sci Rep 4:4956
96. Solomon T (2001) The definition and unit of ionic strength. J Chem Educ 78:1691-1692
97. Sondi I, Biscan J, Pravdic V (1996) Electrokinetics of pure clay minerals revisited. J Colloid Interface Sci 178:514-522
98. Sposito G (1984) The Surface Chemistry of Soils. Oxford University Press, New York
99. Sposito G (1992) The diffuse-ion swarm near smectite particles suspended in 1:1 electrolyte solutions: modified Gouy-Chapman theory and quasicrystal formation. In: Clay-Water Interface and Its Rheological Implications. Güven N, Pollastro RM (eds) Clay Minerals Society, p 127-156
100. Sposito G (2004) The Surface Chemistry of Natural Particles. Oxford University Press, New York
101. Steefel CI, Carroll S, Zhao P, Roberts S (2003) Cesium migration in Hanford sediment: a multisite cation exchange model based on laboratory transport experiments. J Contam Hydrol 67:219-246
102. Steefel CI, Maher K (2009) Fluid-rock interaction: A reactive transport approach. Rev Mineral Geochem 70:485-532
103. Steefel CI, Appelo CAJ, Arora B, Jacques D, Kalbacher T, Kolditz O, Lagneau V, Lichtner PC, Mayer KU, Meeussen J. C. L., Molins S, Moulton D, Shao H, Šimunek J, Spycher N, Yabusaki SB, Yeh GT (2014) Reactive transport codes for subsurface environmental simulation. Computat Geosci: 1-34, doi=10.1007/s10596-014-9443-x
104. - and HTO in compacted sodium montmorillonite as a function of porewater salinity: Integrated sorption and diffusion model. Geochim Cosmochim Acta 132:75-93
105. Tachi Y, Yotsuji K, Suyama T, Ochs M (2014) Integrated sorption and diffusion model for bentonite. Part 2: porewater chemistry, sorption and diffusion modeling in compacted systems. J Nucl Sci Techn 51:1191-1204
106. Tertre E, Beaucaire C, Coreau N, Juery A (2009) Modelling Zn (II) sorption onto clayey sediments using a multi-site ion-exchange model. Appl Geochem 24:1852-1861
107. Tertre E, Delville A, Prêt D, Hubert F, Ferrage E (2015) Cation diffusion in the interlayer space of swelling clay minerals-A combined macroscopic and microscopic study. Geochim Cosmochim Acta 149:251-267
108. Tournassat C, Appelo CAJ (2011) Modelling approaches for anion-exclusion in compacted Na-bentonite. Geochim Cosmochim Acta 75:3698-3710
109. Tournassat C, Neaman A, Villiéras F, Bosbach D, Charlet L (2003) Nanomorphology of montmorillonite particles: Estimation of the clay edge sorption site density by low-pressure gas adsorption and AFM observations. Am Mineral 88:1989-1995
110. Tournassat C, Chapron Y, Leroy P, Boulahya F (2009a) Comparison of molecular dynamics simulations with Triple Layer and modified Gouy-Chapman models in a 0.1 M NaCl - montmorillonite system. J Colloid Interface Sci 339:533-541
111. Tournassat C, Gailhanou H, Crouzet C, Braibant G, Gautier A, Gaucher EC (2009b) Cation exchange selectivity coefficient values on smectite and mixed-layer illite/smectite minerals. Soil Sci Soc Am J 73:928-942
112. Tournassat C, Bizi M, Braibant G, Crouzet C (2011) Influence of montmorillonite tactoid size on Na-Ca cation exchange reactions. J Colloid Interface Sci 364:443-454
113. Tournassat C, Grangeon S, Leroy P, Giffaut E (2013) Modeling specific pH dependent sorption of divalent metals on montmorillonite surfaces. A review of pitfalls, recent achievements and current challenges. Am J Sci 313:395-451
114. Tsai S-C, Ouyang S, Hsu C-N (2001) Sorption and diffusion behavior of Cs and Sr on Jih-Hsing bentonite. Appl Radiat Isot 54:209-215
115. Van Loon LR, Baeyens B, Bradbury MH (2009) The sorption behaviour of caesium on Opalinus Clay: A comparison between intact and crushed material. Appl Geochem 24:999-1004
116. -in Opalinus Clay samples from Mont Terri: Effect of confining pressure. J Contam Hydrol 61:73-83
117. Van Loon LR, Soler JM, Muller W, Bradbury MH (2004a) Anisotropic diffusion in layered argillaceous rocks: a case study with Opalinus Clay. Env Sci Tech 38:5721-5728
118. + and I-in Opalinus Clay at the Mont Terri underground rock laboratory. Radiochim Acta 92:757-763
119. Van Loon LR, Müller W, Iijima K (2005) Activation energies of the self-diffusion of HTO, 22Na+ and 36Cl-in a highly compacted argillaceous rock (Opalinus Clay). Appl Geochem 20:961-972
120. Vanselow AP (1932) The utilization of the base-exchange reaction for the determination of activity coefficients in mixed electrolytes. J Am Chem Soc 54:1307-1311
121. Wang Z, Giammar DE (2013) Mass Action Expressions for Bidentate Adsorption in Surface Complexation Modeling: Theory and Practice. Env Sci Tech 47:3982-3996
122. 2+ in a clay formation: Results and modelling from an in situ experiment in Opalinus Clay. Appl Geochem 23:678-691
123. Wilson MJ, Wilson L (2014) Clay mineralogy and shale instability: an alternative conceptual analysis. Clay Miner 49:127-145
124. - in Upper Toarcian argillite samples from Tournemire: Effects of initial iodide concentration and ionic strength. Appl Geochem 27:1432-1441
125. Yokoyama S, Kuroda M, Sato T (2005) Atomic force microscopy study of montmorillonite dissolution under highly alkaline conditions. Clays Clay Miner 53:147-154
126. Zachara JM, Smith SC, McKinley JP, Resch CT (1993) Cadmium sorption on specimen and soil smectites in sodium and calcium electrolytes. Soil Sci Soc Am J 57:1491-1501
127. + to micaceous subsurface sediments from the Hanford site, USA. Geochim Cosmochim Acta 66:193-211
128. Zhao H, Bhattacharjee S, Chow R, Wallace D, Masliyah JH, Xu Z (2008) Probing surface charge potentials of clay basal planes and edges by direct force measurements. Langmuir 24:12899-12910