Activation energies of the self-diffusion of HTO, 22Na + and 36Cl- in a highly compacted argillaceous rock (Opalinus Clay)

Applied Geochemistry

Volumn 20, Issue 5, 2005, Pages 961-972

  Van Loon, L R ^a   Muller W ^a   Iijima, K ^b  

^a PAUL SCHERRER INSTITUTE   (Switzerland)

^b JAPAN ATOMIC ENERGY AGENCY   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

CLAY; DIFFUSION; GEOLOGY; POROSITY; THERMAL EFFECTS; VISCOSITY;

BULK WATER; OPALINUS CLAY; SELF DIFFUSION; STOKES EINSTEIN RELATIONSHIPS;

ACTIVATION ENERGY;

ACTIVATION ENERGY; CLAY MINERAL; DIFFUSION; POREWATER;

ARRHENIUS;

EID: 16844364916     PISSN: 08832927     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.apgeochem.2004.10.007     Document Type: Article

References (33)

1. M.-C. Bellissent-Funel Status of experiments probing the dynamics of water in confinement Eur. Phys. J. E 12 2003 83 92
2. I.C. Bourg, A.C.M. Bourg, and G. Sposito Modelling diffusion and adsorption in compacted bentonite: a critical review J. Contam. Hydrol. 61 2003 293 302
3. M.H. Bradbury, and B. Baeyens A physico-chemical characterisation and geochemical modelling approach for determining porewater chemistries in argillaceous rocks Geochim. Cosmochim. Acta 62 1998 783 795
4. M.H. Bradbury, and B. Baeyens Porewater chemistry in compacted re-saturated MX-80 bentonite J. Contam. Hydrol. 61 2003 329 338
5. Crank, J., 1975. The Mathematics of Diffusion, second ed. Oxford University Press, Oxford, reprinted version 1998
6. CRC Handbook of Chemistry and Physics, 59th ed. CRC Press, Florida, 1979
7. D. Eisenberg, and W. Kauzmann The Structure and Properties of Water 1969 Oxford University Press Ely House, London
8. P. Gallo, and M. Rovere Anomalous dynamics of confined water at low hydration J. Phys.: Condens. Matter 15 2003 7625 7633
9. Y. Ichikawa, K. Kawamura, M. Nakano, K. Kitayama, and H. Kawamura Unified molecular dynamics and homogenization analysis for bentonite behavior: current results and future possibilities Eng. Geol. 54 1999 21 31
10. Jakob, A., Sarott, F.A., Spieler, P., 1999. Diffusion and sorption on hardened cement pastes - experiments and modelling results. PSI-Bericht 99-05, Paul Scherrer Institut, Villigen, Switzerland. Also published as Nagra Technical Report NTB 99-06, Nagra, Wettingen, Switzerland
11. T. Kozaki, A. Fujishima, S. Sato, and H. Ohashi Self-diffusion of sodium ions in compacted sodium montmorillonite Nucl. Technol. 121 1998 63 69
12. T. Kozaki, N. Saito, A. Fujishima, S. Sato, and H. Ohashi Activation energy for diffusion of chloride ions in compacted sodium montmorillonite J. Contam. Hydrol. 35 1998 67 75
13. T. Kozaki, H. Sato, N. Saito, S. Sato, and H. Ohashi Effect of dry density on activation energy for diffusion of strontium in compacted sodium montmorillonite Mat. Res. Soc. Symp. Proc. 465 1997 893 900
14. Y.-H. Li, and S. Gregory Diffusion of ions in sea water and in deep-sea sediments Geochim. Cosmochim. Acta 38 1974 703 714
15. J. Liu, H. Yamada, T. Kozaki, S. Sato, and H. Ohashi Effect of silica on activation energy for diffusion of sodium ions in montmorillonite and silica sand mixture J. Contam. Hydrol. 61 2003 85 93
16. R. Mills Self-diffusion in normal and heavy water in the range 1-45°C J. Phys. Chem. 77 1973 685 688
17. S. Mitra, K.S. Mukhopadhyay, and K.S. Chandrasekaran Water dynamics in lignite coal pores Physica B 292 2000 29 34
18. Nagra, 2002. Project Opalinus Clay. Safety report: demonstration of disposal feasibility for spent fuel, vitrified high-level and long-lived intermediate-level waste (Entsorgungsnachweis). Nagra Technical Report NTB 02-05, Nagra, Wettingen, Switzerland
19. R. Parsons Handbook of Electrochemical Constants 1959 Butterworths Science Publications London
20. Pearson, F.J., 1998. Opalinus clay experimental water: A1 Type, Version 980318. Internal Technical Report TM-44-98-07, Paul Scherrer Institut: Villigen PSI, Switzerland
21. Pearson, F.J., 2000. Nagra unpublished internal report, Nagra, Wettingen, Switzerland
22. M.A. Ricci, and M. Rovere Studies of water in confinement by experiments and simulations J. Phys., IV France 10 2000 187 193
23. F.D. Ricci, M.A. Ricci, and D. Rocca Role of hydrogen bond in self-diffusion process in liquid water Phys. Lett. 48A 1974 289 290
24. M. Rovere, and P. Gallo Effect of confinement on static and dynamical properties of water Eur. Phys. J. E 12 2003 77 81
25. S. Suzuki, H. Sato, T. Ishidera, and N. Fujii Study on the anisotropy of the effective diffusion coefficient and activation energy for deuterated water in compacted sodium bentonite J. Contam. Hydrol. 68 2004 23 37
26. M. Thury, and P. Bossart The Mont Terri rock laboratory, a new international research project in a Mesozoic shale formation, in Switzerland Eng. Geol. 52 1999 347 359
27. R.M.E. Valckenborg, L. Pel, and K. Kopinga Combined NMR cryoporometry and relaxometry J. Phys. D: Appl. Phys. 35 2002 249 256
28. + in Opalinus Clay: effect of confining pressure, sample orientation, sample depth and temperature. PSI Bericht 04-03, Paul Scherrer Institut, Villigen, Switzerland. Also published as Nagra NTB 03-07, Nagra, Wettingen, Switzerland
29. - in Opalinus Clay samples from Mont Terri: effect of confining pressure J. Contam. Hydrol. 61 2003 73 83
30. - in a layered argillaceous rock (Opalinus Clay): diffusion perpendicular to the fabric Appl. Geochem. 18 2003 1653 1662
31. - in Opalinus Clay at the Mont Terri Underground Rock laboratory Radiochim. Acta 92 2004 757 763
32. Waber, N.H., Mazurek, M., Pearson, F.J., 1998. Opalinus clay: reference porewater, mineralogy and porosity. Nagra unpublished report
33. J.H. Wang, C.V. Robinson, and I.S. Edelman Self-diffusion and structure of liquid Water. III. Measurement of the self-diffusion of liquid water with H-2, H-3 and O-18 as Tracers J. Am. Chem. Soc. 75 1953 466 470