Nanomorphology of montmorillonite particles: Estimation of the clay edge sorption site density by low-pressure gas adsorption and AFM observations

American Mineralogist

Volumn 88, Issue 11-12 PART 2, 2003, Pages 1989-1995

  Tournassat, Christophe ^a,b   Neaman, Alexander ^c   Villéras, Frédéric ^c   Bosbach, Dirk ^d   Charlet, Laurent ^a  

^a UNIVERSITÉ GRENOBLE ALPES   (France)

^b ANDRA   (France)

^c Institut National Polytechnique de Lorraine   (France)

^d KARLSRUHE INSTITUTE OF TECHNOLOGY   (Germany)

Author keywords

[No Author keywords available]

Indexed keywords

ATOMIC FORCE MICROSCOPY; DENSITY OF GASES; GAS ADSORPTION; GASES; PLATELETS; SODIUM METALLOGRAPHY;

ADSORPTION EXPERIMENT; AQUEOUS SUSPENSIONS; DERIVATIVE ISOTHERM SUMMATIONS; INTERLAYER SURFACE; MICROSCOPIC TECHNIQUES; PERIMETER TO AREAS; SMECTITE PARTICLES; SUSPENDED PARTICLES;

SUSPENSIONS (FLUIDS);

CLAY MINERAL; MINERALOGY; MONTMORILLONITE; POLLUTANT REMOVAL; SMECTITE; SORPTION; SURFACE LAYER;

EID: 0345831964     PISSN: 0003004X     EISSN: None     Source Type: Journal    
DOI: 10.2138/am-2003-11-1243     Document Type: Article

References (47)

1. Avena, M.J. (2002) Acid-base behavior of clay surfaces in aqueous media. Encyclopedia of Surface and Colloid Science, 37-63.
2. Avena, M.J., Cabrol, R., and De Pauli, C. (1990) Study of some physicochemical properties of pillared montmorillonites: acid-base potentiometric titrations and electrophoretic measurements. Clays and Clay Minerals, 38, 356-362.
3. Baeyens, B. and Bradbury, M.H. (1997) A mechanistic description of Ni and Zn sorption on Na-montmorillonite. Part I: Titration and sorption measurements. Journal of Contaminant Hydrology, 27, 199-222.
4. Bardot, F., Villiéras, F., Michot, L.J., François, M., Gérard, G., and Cases, J.M. (1998) High resolution gas adsorption study on illites permuted with various cations: assessment of surface energetic properties. Journal of Dispersion Science and Technology, 19, 739-759.
5. Bérend, I. (1991) Les mécanismes d'hydratation de montmorillonites homoioniques pour des pressions relatives inférieures à 0.95, p. 308. Thesis at INPL Nancy, France.
6. +-exchanged forms. Clays and Clay Minerals, 43, 324-336.
7. Bickmore, B., Hochella, M.F., Bosbach, D., and Charlet, L. (1999) Methods for performing atomic force microscopy imaging of clay minerals in aqueous solution. Clays and Clay Minerals, 47, 573-581.
8. Bosbach, D., Charlet, L., Bickmore, B., and Hochella, M.F. (2000) The dissolution of hectorite: in-situ, real-time observations using atomic force microscopy. American Mineralogist, 85, 1209-1216.
9. Boult, K.A., Cowper, M.M., Heath, T.G., Sato, H., Shibutani, T., and Yui, M. (1998) Towards an understanding of the sorption of U(VI) and Se(VI) on sodium bentonite. Journal of Contaminant Hydrology, 35, 141-150.
10. Bradbury, M.H. and Baeyens, B. (1997) A mechanistic description of Ni and Zn sorption on Na-montmorillonite. Part II: modeling. Journal of Contaminant Hydrology, 27, 223-248.
11. Bradbury, M.H. and Baeyens, B. (1998) Modeling the sorption of Zn and Ni on Ca-montmorillonite. Geochimica et Cosmochimica Acta, 63, 325-336.
12. Cama, J., Ganor, J., Ayora, C., and Lasagna, C.A. (2000) Smectite dissolution kinetics at 80°C and pH 8.8. Geochimica et Cosmochimica Acta, 64, 2701-2717.
13. Cases, J.M., Cunin, P., Grillet, Y., Poinsignon, C., and Yvon, J. (1986) Method of analysing morphology of kaolinites: relations between crystallographic and morphological properties. Clay Minerals, 21, 55-68.
14. Cases, J.M., Bérend, I., Besson, G., François, M., Uriot, J.-P., Thomas, F., and Poirier, J.E. (1992) Mechanism of adsorption and desorption of water vapor by homoionic montmorillonite. 1. The sodium-exchanged form. Langmuir, 8, 2730-2739.
15. Cebula, D.J., Thomas, R.K., and White, J.W. (1978) The structure and dynamics of clay-water systems studied by neutron scattering. In M.M. Mortland and V.C. Farmer, Eds., Proceeding of International Clay Conference, p. 111-120. Elsiever, Amsterdam, Oxford.
16. Charlet, L., Schindler, P.W., Spadini, L., Furrer, G., and Zysset, M. (1993) Cation adsorption on oxides and clays : The aluminum case. Aquatic Science, 55/4, 1015-1621.
17. Claret, F., Bauer, A., Schäfer, T., Griffault, L., and Lanson, B. (2002) Experimental investigation of the interaction of clays with high pH solutions: A case study from the Callovo-Oxfordian formation, Meuse-Haute Marne underground laboratory (France). Clays and Clay Minerals, 50, 632-645.
18. Fletcher, P. and Sposito, G. (1989) The chemical modeling of clay/electrolyte interactions for montmorillonite. Clay Minerals, 24, 375-391.
19. Grillet, Y., Rouquerol, F., and Rouquerol, J. (1977) Etude de l'adsorption physique des gaz par une procédure continue. I. Application à la détermination des surfaces spécifiques d'adsorbants non poreux et mésoporeux. Journal of Chemical Physic, 74, 179-182.
20. Hight, R.J., Higdon, W.L., and Schmidt, P.W. (1960) Small angle scattering study of sodium montmorillonite clay suspensions. Journal of Chemical Physic, 33, 1656-1661.
21. Hight, R.J., Higdon, W.L., Darley, H.C.H., and Schmidt, P.W. (1962) Small angle X-ray scattering from montmorillonite clay suspensions. II. Journal of Chemical Physic, 37, 502-510.
22. Keren, R. and Shainberg, I. (1975) Water vapor isotherms and heat of immersion of Na/Ca-montmorillonite systems. I: homoionic clay. Clays and Clay Minerals, 23, 193-200.
23. Michot, L.J. and Villiéras, F. (2002) Assessment of surface energetic heterogeneity of synthetic Na-Saponites. The role of layer charge. Clay Minerals, 37, 39-57.
24. Michot, L.J., François, M., and Cases, J. M. (1990) Surface heterogeneity studied by a quasi-equilibrium adsorption procedure. Langmuir, 6, 637-643.
25. Michot, L.J., Villiéras, F., François, M., Yvon, J., Le Dred, R., and Cases, J.M. (1994) The structural microscopic hydrophobicity of talc. Langmuir, 10, 3765-3773.
26. Mooney, R.W., Keenan, A.G., and Wood, L.A. (1952) Adsorption of water vapor by montmorillonite. II. Effect of exchangeable ions and lattice swelling as measured by X-ray diffraction. Journal of American Chemical Society, 74, 1331-1374.
27. Norrish, K. (1954) The swelling of montmorillonite. Faraday Discussion Society, 18, 120-134.
28. Ochs, M., Boonekamp, M., Wanner, H., Sato, H., and Mikazu, Y. (1998) A quantitative model for ion diffusion in compacted bentonite. Radiochimica Acta, 82, 437-443.
29. Ochs, M., Lothenbach, B., Wanner, H., Sato, H., and Mikazu, Y. (2001) An integrated sorption-diffusion model for the calculation of consistent distribution and diffusion coefficients in compacted bentonite. Journal of Contaminant Hydrology, 47, 283-296.
30. Rouquerol, J., Rouquerol, F., Grillet, Y., and Ward, R.J. (1988) A critical assessment of quasi-equilibrium gas adsorption technique in volumetry, gravimetry and microcalorimetry. In K.K. Hunger, Ed., Characterization of Porous solids, p. 67-76. Elsevier, Amsterdam, Oxford.
31. Sato, T., Watanabe, T., and Otsuka, R. (1992) Effects of layer charge, charge location, and energy change on expansion properties of dioctahedral smectites. Clays and Clay Minerals, 40, 103-113.
32. Sauzéat, E., Guillaume, D., Neaman, A., Peiffert, C., Ruck, R., Dubessy, J., Cathelineau, M., Villiéras, F., and Yvon, J. (2000) MX-80: une argile de référence méthodologique pour l'ANDRA, p. 286-292. ANDRA, Agence nationale pour la gestion des déchets radioactifs.
33. Schramm, L.L. and Kwak, J.C.T. (1982) Influence of exchangeable cation composition on the size and shape of montmorillonite particles in dilute suspension. Clays and Clay Minerals, 30, 40-48.
34. Schwarzenbach, R.P., Gschwend, P.M., and Imboden, D.M., Eds. (1993) Environmental organic chemistry. Wiley, New York.
35. Sposito, G., Ed. (1981) The thermodynamics of soil solution. Oxford University Press, New York.
36. Sposito, G., Ed. (1984) Surface chemistry of soils, 223 p. Oxford University Press, New York.
37. 2+ adsorption on calcium-montmorillonite. Clays and Clay Minerals, 41, 288-296.
38. Tamura, K., Yamada, H., and Nakazawa, H. (2000) Stepwise hydratation of high-quality synthetic smectite with various cations. Clays and Clay Minerals, 48, 400-404.
39. Titiloye, J.O. and Skipper, N.T. (2000) Computer simulation of the structure and dynamics of methane in hydrated Na-smectites clays. Chemical Physical Letters, 329, 23-28.
40. Villiéras, F., Cases, J.M., François, M., Michot, L.J. and Thomas, F. (1992) Textural properties and surface energetic heterogeneity of solids from modeling of low pressure gas adsorption isotherms. Langmuir, 8, 1789-1795.
41. Villiéras, F., Michot, L.J., Bardot, F., Cases, J.M., François, M., and Rudzinski, W. (1997a) An improved derivative isotherm summation method to study surface heterogeneity of clay minerals. Langmuir, 13, 1104-1117.
42. Villiéras, F., Michot, L.J., Cases, J.M., Berend, I., Bardot, F., François, M., Gérard, G., and Yvon, J. (1997b) Static and dynamic studies of the energetic surface heterogeneity of clay minerals. In W. Rudzinski, W.A. Steele, and G. Zgrablich, Eds., Equilibria and Dynamics of Gas Adsorption on Heterogeneous Solid Surfaces, Studies in Surface Science and Catalysis, 104, p. 573-623. Elsevier Science Publication B. V., Amsterdam.
43. Villiéras, F., Michot, L.J., Bardot, F., Chamerois, M., Eypert-Blaison, C., Gérard, G., and Cases, J.M. (2002) Surface heterogeneity of minerals. C. R. Geosciences, 334, 597-609.
44. Wanner, H., Albinson, Y., Karnland, O., Wieland, E., Wersin, P., and Charlet, L. (1994) The acid/base chemistry of montmorillonite. Radiochimica Acta, 66/67, 157-162.
45. White, G.N. and Zelazny, L.W. (1988) Analysis and implications of the edge structure of dioctahedral phyllosilicates. Clays and Clay Minerals, 36, 141-146.
46. Zachara, J.M. and Smith, S.C. (1994) Edge complexation reactions of cadmium on specimen and soil-derived smectite. Soil Science Society of America, 59, 762-769.
47. Zachara, J.M., Smith, S.C., McKinley, J.P., and Resch, C.T. (1993) Cadmium sorption on specimen and soil smectites in sodium and calcium electrolytes. Soil Science Society of America, 57, 1491-1501.