Potential-Dependent Electrocatalytic Pathways: Controlling Reactivity with pKa for Mechanistic Investigation of a Nickel-Based Hydrogen Evolution Catalyst

Journal of the American Chemical Society

Volumn 137, Issue 41, 2015, Pages 13371-13380

  Rountree, Eric S ^a   Dempsey, Jillian L ^a  

^a University of North Carolina at Chapel Hill   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

CATALYSIS; CATALYSTS; HYDRIDES; HYDROGEN; KINETICS; LASER SPECTROSCOPY; RATE CONSTANTS; REACTION INTERMEDIATES;

CYCLIC VOLTAMMOGRAMS; ELECTROANALYTICAL METHOD; HYDROGEN EVOLUTION; MECHANISTIC ANALYSIS; NEGATIVE POTENTIAL; POTENTIAL-DEPENDENT; STOPPED-FLOW MEASUREMENTS; TIME-RESOLVED SPECTROSCOPY;

NICKEL;

ACETONITRILE; ANILINE; CYCLOOCTANE DERIVATIVE; FORMAMIDE DERIVATIVE; NICKEL; SODIUM BOROHYDRIDE;

ANALYTIC METHOD; ARTICLE; CATALYSIS; CYCLIC POTENTIOMETRY; ELECTROCATALYSIS; ELECTROCHEMICAL ANALYSIS; ELECTRON TRANSPORT; FLOW KINETICS; FOOT OF THE WAVE ANALYSIS; HYDROGEN EVOLUTION; MATHEMATICAL PARAMETERS; OBSERVED RATE CONSTANT; OXIDATION; OXIDATION REDUCTION POTENTIAL; PHOSPHORUS NUCLEAR MAGNETIC RESONANCE; PROTON NUCLEAR MAGNETIC RESONANCE; PROTON TRANSPORT; RATE CONSTANT; REDOX COUPLE; SPECTROSCOPY; STEADY STATE;

EID: 84945249368     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/jacs.5b08297     Document Type: Article

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