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Volumn 51, Issue 82, 2015, Pages 15110-15113

Tris(trimethylsilyl)silane and visible-light irradiation: A new metal- and additive-free photochemical process for the synthesis of indoles and oxindoles

Author keywords

[No Author keywords available]

Indexed keywords

HETEROCYCLIC COMPOUND; INDOLE DERIVATIVE; NITROGEN; OXINDOLE; SILANE DERIVATIVE; TRIS(TRIMETHYLSILYL)SILANE; UNCLASSIFIED DRUG; FREE RADICAL;

EID: 84942923657     PISSN: 13597345     EISSN: 1364548X     Source Type: Journal    
DOI: 10.1039/c5cc06329a     Document Type: Article
Times cited : (67)

References (85)
  • 71
    • 22744443220 scopus 로고    scopus 로고
    • (a) The kinetic study provided us a virtuous interpretation of this photo-mediated process. The simplified kinetic model reveals that the best adjustment of the curve was observed using the rate expression, which correlates both reagents in a single equation. Therefore, our kinetics data indicate that the overall reaction order is two, being first order in regard to each reagent. Having made this observation, we can conclude that both reagents are involved in the rate-determining step. (b) For a work that supports our findings, see
    • D. G. Blackmond Angew. Chem., Int. Ed. 2005 44 4302
    • (2005) Angew. Chem., Int. Ed. , vol.44 , pp. 4302
    • Blackmond, D.G.1


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.