Electrical Network of Single-Crystalline Metal Oxide Nanoclusters Wired by π-Molecules

Angewandte Chemie - International Edition

Volumn 53, Issue 42, 2014, Pages 11228-11231

  Tsunashima, Ryo ^a   Iwamoto, Yoshifumi ^a   Baba, Yusuke ^a   Kato, Chisato ^b   Ichihashi, Katsuya ^b   Nishihara, Sadafumi ^b   Inoue, Katsuya ^b   Ishiguro, Katsuya ^a   Song, Yu Fei ^c   Akutagawa, Tomoyuki ^d  

^a YAMAGUCHI UNIVERSITY   (Japan)

^b HIROSHIMA UNIVERSITY   (Japan)

^c BEIJING UNIVERSITY OF CHEMICAL TECHNOLOGY   (China)

^d TOHOKU UNIVERSITY   (Japan)

Author keywords

conducting materials; molecular electronics; nanoparticles; polyoxometalates

Indexed keywords

CRYSTAL STRUCTURE; ELECTRON TRANSPORT PROPERTIES; ELECTRONS; METALS; MOLECULAR ELECTRONICS; NANOPARTICLES; OXIDES; SINGLE CRYSTALS;

BETWEEN CLUSTERS; CONDUCTING MATERIALS; ELECTRICAL NETWORKS; ELECTRON TRANSPORT; POLYOXOMETALATES; SINGLE-CRYSTALLINE; STRONG INTERACTION; TETRATHIAFULVALENES;

MOLECULES;

EID: 84941099892     PISSN: 14337851     EISSN: 15213773     Source Type: Journal    
DOI: 10.1002/anie.201406223     Document Type: Article

References (46)

1. Y. F. Song, R. Tsunashima, Chem. Soc. Rev. 2012, 41, 7384-7402;
2. D.-L. Long, R. Tsunashima, L. Cronin, Angew. Chem. 2010, 122, 1780-1803;
3. Angew. Chem. Int. Ed. 2010, 49, 1736-1758;
4. A. Müller, F. Peters, M. T. Pope, D. Gatteschi, Chem. Rev. 1998, 98, 239-272;
5. C. L. Hill, Chem. Rev. 1998, 98, 1-2;
6. P. Kögerler, B. Tsukerblat, A. Müller, Dalton Trans. 2010, 39, 21-36;
7. U. Kortz, A. Müller, J. Slageren, J. Schnack, N. S. Dalal, M. Dressel, Coord. Chem. Rev. 2009, 253, 2315-2327;
8. N. Mizuno, M. Misono, Chem. Rev. 1998, 98, 199-218.
9. J. M. Clemente-Juan, E. Coronado, A. Gaita-Ariño, Chem. Soc. Rev. 2012, 41, 7464-7478;
10. N. Casañ-Pastor, L. C. Baker, J. Am. Chem. Soc. 1992, 114, 10384-10401;
11. R. A. Prados, M. T. Pope, Inorg. Chem. 1976, 15, 2547-2553;
12. C. Sanchez, J. Livage, J. P. Launay, M. Fournier, J. Am. Chem. Soc. 1983, 105, 6817-6823.
13. J. Lehmann, A. Gaita-Ariño, E. Coronado, D. Loss, Nat. Nanotechnol. 2007, 2, 312-317.
14. C. Fleming, D.-L. Long, N. McMillan, J. Johnson, N. Bovet, V. Dhanak, N. Gadegaard, P. Kögerler, L. Cronin, M. Kadodwala, Nat. Nanotechnol. 2008, 3, 229-233.
15. D. Velessiotis, N. Glezos, V. Ioannou-Sougleridis, J. Appl. Phys. 2005, 98, 0845031-0845034;
16. A. M. Douvas, E. Makarona, N. Glezos, P. Argitis, J. A. Mielczarski, E. Mielczarski, ACS Nano 2008, 2, 733-742.
17. G. Saito, Y. Yoshida, Bull. Chem. Soc. Jpn. 2007, 80, 1-137;
18. T. Akutagawa, T. Ohta, T. Hasegawa, T. Nakamura, C. A. Christensen, J. Becher, Proc. Natl. Acad. Sci. USA 2002, 99, 5028-5033;
19. R. Tsunashima, Y. Noda, Y. Tatewaki, S.-i. Noro, T. Akutagawa, T. Nakamura, T. Matsumoto, T. Kawai, Appl. Phys. Lett. 2008, 93, 1731021-17310213;
20. E. Coronado, C. J. Gõmez-García, Chem. Rev. 1998, 98, 273-296;
21. L. Ouahab, M. Bencharif, D. Grandjean, C. R. Acad. Sci. Ser. II 1988, 307, 749-755;
22. S. Triki, L. Ouahab, J.-F. Halet, O. Peña, J. Padiou, D. Grandjean, C. Garrigou-Lagrange, P. Delhaes, J. Chem. Soc. Dalton Trans. 1992, 1217-1227;
23. E. Coronado, C. Giménez-Saiz, C. J. Gõmez-García, Coord. Chem. Rev. 2005, 249, 1776-1796;
24. J. R. Galán-Mascarõs, C. Giménez-Saiz, S. Triki, C. J. Gõmez-García, E. Coronado, L. Ouahab, Angew. Chem. Int. Ed. Engl. 1995, 34, 1460-1462;
25. Angew. Chem. 1995, 107, 1601-1603.
26. B. A. Scott, S. J. La Placa, J. B. Torrance, B. D. Silverman, B. Welber, J. Am. Chem. Soc. 1977, 99, 6631-6639;
27. T. Mori, A. Kobayashi, Y. Sasaki, H. Kobayashi, G. Saito, H. Inokuchi, Bull. Chem. Soc. Jpn. 1984, 57, 627-633.
28. S. C. Lee, A. Ueda, H. Kamo, K. Takahashi, M. Uruichi, K. Yamamoto, K. Yakushi, A. Nakao, R. Kumai, K. Kobayashi, H. Nakao, Y. Murakami, H. Mori, Chem. Commun. 2012, 48, 8673-8675.
29. R. Bozio, I. Zanon, A. Girlando, C. Pecile, J. Chem. Phys. 1979, 71, 2282-2293.
30. 3- is observed at 232 or 318 nm. Namely, the orbital energies of the O atoms are 4-5 eV below the HOMO of TTFPy.
31. J. Han, M. Shen, W. Cao, A. M. R. Senos, P. Q. Mantas, Appl. Phys. Lett. 2003, 82, 67-69.
32. D. Yu, C. Wang, B. L. Wehrenberg, P. Guyot-Sionnest, Phys. Rev. Lett. 2004, 92, 2168021-2168024;
33. R. Parthasarathy, X.-M. Lin, H. M. Jaeger, Phys. Rev. Lett. 2001, 87, 1868071-1868074;
34. T. B. Tran, I. S. Beloborodov, X. M. Lin, T. P. Bigioni, V. M. Vinokur, H. M. Jaeger, Phys. Rev. Lett. 2005, 95, 0768061-07680614;
35. Y. Tatewaki, Y. Noda, T. Akutagawa, R. Tsunashima, S.-i. Noro, T. Nakamura, H. Hasegawa, S. Mashiko, J. Becher, J. Phys. Chem. C 2007, 111, 18871-18877;
36. Y. Noda, S.-i. Noro, T. Akutagawa, T. Nakamura, Phys. Rev. Lett. 2010, 82, 2054201-2054206;
37. T. Sugawara, M. Minamoto, M. M. Matsushita, P. Nickels, S. Komiyama, Phys. Rev. B 2008, 77, 2353161-2353167;
38. J. M. Wessels, H.-G. Nothofer, W. E. Ford, F. Wrochem, F. Scholz, T. Vossmeyer, A. Schroedter, H. Weller, A. Yasuda, J. Am. Chem. Soc. 2004, 126, 3349-3356;
39. R. Parthasarathy, X.-M. Lin, H. M. Jaeger, Phys. Rev. Lett. 2001, 87, 1868071-1868074.
40. G. Orsini, V. Tricoli, J. Mater. Chem. 2011, 21, 14530-14542.
41. L. Wang, B. Zhang, J. Zhang, Inorg. Chem. 2006, 45, 6860-6863.
42. 3CN) upon both oxidation and protonation of a similar compound of 2,3-dimethylthio-6-pyridyl-tetrathiafulvalene, see Ref. [15b];
43. Q. Y. Zhu, Y. Liu, W. Lu, Y. Zhang, G. Q. Bian, G. Y. Niu, J. Dai, Inorg. Chem. 2007, 46, 10065-10070.
44. 4- in acetonitrile shows bands at 342 and 750 nm with a shoulder at 1050 nm, see Ref [16b];
45. H.-R. Sun, S.-Y. Zhang, J.-Q. Xu, G.-Y. Yang, T.-S. Shi, J. Electroanal. Chem. 1998, 455, 57-68.
46. int=0.0530), 430 refined parameters, R1=0.0570, wR2=0.1497. Six numbers of crystalline water molecules were crystallographically identified and their six number of O atoms were included to crystallographic composition shown above. CCDC 1008211 (1) contains the supplementary crystallographic data for this paper. These data can be obtained free of charge from The Cambridge Crystallographic Data Centre via www.ccdc.cam.ac.uk/data-request/cif.