-
1
-
-
33744788417
-
-
Akkerman, H. B.; Blom, P. W. M.; de Leeuw, D. M.; de Boer, B. Towards Molecular Electronics with Large-Area Molecular Junctions. Nature 2006, 441, 69-72.
-
Akkerman, H. B.; Blom, P. W. M.; de Leeuw, D. M.; de Boer, B. Towards Molecular Electronics with Large-Area Molecular Junctions. Nature 2006, 441, 69-72.
-
-
-
-
2
-
-
19944433887
-
Molecularly Inherent Voltage-Controlled Conductance Switching
-
Blum, A. S.; Kushmerik, J. G.; Long, D. P.; Patterson, C. H.; Yang, J. C.; Henderson, J. C.; Yao, Y.; Tour, J. M.; Shashidhar, R.; Ratna, B. R. Molecularly Inherent Voltage-Controlled Conductance Switching. Nat. Mater. 2005, 4, 167-172.
-
(2005)
Nat. Mater
, vol.4
, pp. 167-172
-
-
Blum, A.S.1
Kushmerik, J.G.2
Long, D.P.3
Patterson, C.H.4
Yang, J.C.5
Henderson, J.C.6
Yao, Y.7
Tour, J.M.8
Shashidhar, R.9
Ratna, B.R.10
-
3
-
-
30044451315
-
Metal-Free Silicon-Molecule-Nanotube Testbed and Memory Device
-
He, J.; Chen, B.; Flatt, A. K; Stephenson, J. J.; Doyle, C. D.; Tour, J. M. Metal-Free Silicon-Molecule-Nanotube Testbed and Memory Device. Nat. Mater. 2006, 5, 63-68.
-
(2006)
Nat. Mater
, vol.5
, pp. 63-68
-
-
He, J.1
Chen, B.2
Flatt, A.K.3
Stephenson, J.J.4
Doyle, C.D.5
Tour, J.M.6
-
4
-
-
33846164123
-
Monolayer to Multilayer Nanostructural Growth Transition in N-Type Oligothiophenes on Au(111) and Implications for Organic Field-Effect Transistor Performance
-
Dholakia, G. R.; Meyyappan, M.; Facchetti, A.; Marks, T. J. Monolayer to Multilayer Nanostructural Growth Transition in N-Type Oligothiophenes on Au(111) and Implications for Organic Field-Effect Transistor Performance. Nano Lett. 2006, 6, 2447-2455.
-
(2006)
Nano Lett
, vol.6
, pp. 2447-2455
-
-
Dholakia, G.R.1
Meyyappan, M.2
Facchetti, A.3
Marks, T.J.4
-
5
-
-
0035829903
-
Distance Dependence of the Electron-Transfer Rate Across Covalently Bonded Monolayers on Silicon
-
Cheng, J.; Robinson, D. B.; Cicero, R. L.; Eberspacher, T.; Barrelet, C. J.; Chidsey, C. E. D. Distance Dependence of the Electron-Transfer Rate Across Covalently Bonded Monolayers on Silicon. J. Phys. Chem. B 2001, 105, 10900-10904.
-
(2001)
J. Phys. Chem. B
, vol.105
, pp. 10900-10904
-
-
Cheng, J.1
Robinson, D.B.2
Cicero, R.L.3
Eberspacher, T.4
Barrelet, C.J.5
Chidsey, C.E.D.6
-
6
-
-
33845791029
-
Polyoxometalate Clusters, Nanoclusters and Materials: From Self-Assembly to Designer Materials and Devices
-
Long, D.-L.; Burkholder, E.; Cronin, L. Polyoxometalate Clusters, Nanoclusters and Materials: From Self-Assembly to Designer Materials and Devices. Chem. Soc. Rev. 2007, 36, 105-121.
-
(2007)
Chem. Soc. Rev
, vol.36
, pp. 105-121
-
-
Long, D.-L.1
Burkholder, E.2
Cronin, L.3
-
7
-
-
0034816312
-
Electron Delocalization and Magnetic State of Doubly-Reduced Polyoxometalates
-
Duclusaud, H.; Borshch, S. A. Electron Delocalization and Magnetic State of Doubly-Reduced Polyoxometalates. J. Am. Chem. Soc. 2001, 123, 2825-2829.
-
(2001)
J. Am. Chem. Soc
, vol.123
, pp. 2825-2829
-
-
Duclusaud, H.1
Borshch, S.A.2
-
8
-
-
0034822694
-
-
Maestre, J. M, Lopez, X, Bo, C, Poblet, J.-M, Casañ-Pastor, N. Electronic and Magnetic Properties of α-Keggin Anions: A DFT study of [XM12 O40]n, M, W, Mo; X, AlIII, SiIV, PV, FeIII, CoII, CoIII and [SiM11 VO40]m, M, Mo and W, J. Am. Chem. Soc. 2001, 123, 3749-3758
-
m- (M = Mo and W). J. Am. Chem. Soc. 2001, 123, 3749-3758.
-
-
-
-
9
-
-
33749627703
-
3- (M = Mo, W) in the Gas Phase
-
3- (M = Mo, W) in the Gas Phase. J. Phys. Chem. A 2006, 710, 10737-10741.
-
(2006)
J. Phys. Chem. A
, vol.710
, pp. 10737-10741
-
-
Waters, T.1
Huang, X.2
Wang, X.-B.3
Woo, H.-K.4
O'Hair, R.A.J.5
Wedd, A.G.6
Wang, L.-S.7
-
11
-
-
33751153883
-
Polyoxometalate Chemistry: An Old Field with New Dimensions in Several Disciplines
-
Pope, M. T.; Muller, A. Polyoxometalate Chemistry: An Old Field with New Dimensions in Several Disciplines. Angew. Chem., Int Ed. Engl. 1991, 30, 34-48.
-
(1991)
Angew. Chem., Int Ed. Engl
, vol.30
, pp. 34-48
-
-
Pope, M.T.1
Muller, A.2
-
12
-
-
0000523094
-
Structure of the Molecule of 12-Phosphotungstic Acid
-
Keggin, J. F. Structure of the Molecule of 12-Phosphotungstic Acid. Nature 1933, 131, 908-909.
-
(1933)
Nature
, vol.131
, pp. 908-909
-
-
Keggin, J.F.1
-
13
-
-
46849109207
-
-
d bond (type I octahedra according to the Pope classification; see refs 10, 11).
-
d bond (type I octahedra according to the Pope classification; see refs 10, 11).
-
-
-
-
14
-
-
57249097659
-
Comparison of the Photoredox Properties of Polyoxometallates and Semiconducting Particles
-
Hiskia, A.; Mylonas, A.; Papakonstantinou, E. Comparison of the Photoredox Properties of Polyoxometallates and Semiconducting Particles. Chem. Soc. Rev. 2001, 30, 62-69.
-
(2001)
Chem. Soc. Rev
, vol.30
, pp. 62-69
-
-
Hiskia, A.1
Mylonas, A.2
Papakonstantinou, E.3
-
15
-
-
0003611836
-
Photochemistry of Polyoxometallates of Molybdenum and Tungsten and/or Vanadium
-
Papaconstantinou, E. Photochemistry of Polyoxometallates of Molybdenum and Tungsten and/or Vanadium. Chem. Soc. Rev. 1989, 18, 1-31.
-
(1989)
Chem. Soc. Rev
, vol.18
, pp. 1-31
-
-
Papaconstantinou, E.1
-
16
-
-
46849112512
-
-
This electron storage capacity is a general characteristic of POMs with type I octahedra, and it is attributed to the nonbonding character of the lowest unoccupied molecular orbitals (LUMOs) of these octahedra. Since the metal ions in the oxidized type I octahedra have do electronic configuration, the LUMOs are mainly composed of nonbonding, metal dxy orbitals with low contribution of antibonding oxygen orbitals, whereas the highest occupied molecular orbitals (HOMOs) are mainly composed of oxygen 2p orbitals refs 10, 11, 17, 19
-
xy orbitals with low contribution of antibonding oxygen orbitals, whereas the highest occupied molecular orbitals (HOMOs) are mainly composed of oxygen 2p orbitals (refs 10, 11, 17, 19).
-
-
-
-
17
-
-
1542619332
-
Ab Initio and DFT Modelling of Complex Materials: Towards the Understanding of Electronic and Magnetic Properties of Polyoxometalates
-
Poblet, J. M.; López, X.; Bo, C. Ab Initio and DFT Modelling of Complex Materials: Towards the Understanding of Electronic and Magnetic Properties of Polyoxometalates. Chem. Soc. Rev. 2003, 32, 297-308.
-
(2003)
Chem. Soc. Rev
, vol.32
, pp. 297-308
-
-
Poblet, J.M.1
López, X.2
Bo, C.3
-
18
-
-
0037132645
-
-
Suaud, N.; Gaita-Ariño, A.; Clemente-Juan, J. M.; Sánchez-Marin, J.; Coronado, E. Electron Delocalization in Mixed-Valence Keggin Polyoxometalates. Ab Initio Calculation of the Local Effective Transfer Integrals and Its Consequences on the Spin Coupling. J. Am. Chem. Soc. 2002, 724, 15134-15140.
-
Suaud, N.; Gaita-Ariño, A.; Clemente-Juan, J. M.; Sánchez-Marin, J.; Coronado, E. Electron Delocalization in Mixed-Valence Keggin Polyoxometalates. Ab Initio Calculation of the Local Effective Transfer Integrals and Its Consequences on the Spin Coupling. J. Am. Chem. Soc. 2002, 724, 15134-15140.
-
-
-
-
19
-
-
0037164121
-
Electronic Properties of Polyoxometalates: Electron and Proton Affinity of Mixed-Addenda Keggin and Wells-Dawson Anions
-
López, X.; Bo, C.; Poblet, J. M. Electronic Properties of Polyoxometalates: Electron and Proton Affinity of Mixed-Addenda Keggin and Wells-Dawson Anions. J. Am. Chem. Soc. 2002, 124, 12574-12582.
-
(2002)
J. Am. Chem. Soc
, vol.124
, pp. 12574-12582
-
-
López, X.1
Bo, C.2
Poblet, J.M.3
-
20
-
-
20744455681
-
Synthesis and Optical Properties of Conjugated Polymers Containing Polyoxometalate Clusters as Side-Chain Pendants
-
Xu, B.; Lu, M.; Kang, J.; Wang, D.; Brown, J.; Peng, Z. Synthesis and Optical Properties of Conjugated Polymers Containing Polyoxometalate Clusters as Side-Chain Pendants. Chem. Mater. 2005, 17, 2841-2851.
-
(2005)
Chem. Mater
, vol.17
, pp. 2841-2851
-
-
Xu, B.1
Lu, M.2
Kang, J.3
Wang, D.4
Brown, J.5
Peng, Z.6
-
21
-
-
12344283547
-
Synthesis of Main-Chain Polyoxometalate-Containing Hybrid Polymers and Their Applications in Photovoltaic Cells
-
Lu, M.; Xie, B.; Kang, J.; Chen, F-C.; Yang, Y.; Peng, Z. Synthesis of Main-Chain Polyoxometalate-Containing Hybrid Polymers and Their Applications in Photovoltaic Cells. Chem. Mater. 2005, 17, 402-408.
-
(2005)
Chem. Mater
, vol.17
, pp. 402-408
-
-
Lu, M.1
Xie, B.2
Kang, J.3
Chen, F.-C.4
Yang, Y.5
Peng, Z.6
-
22
-
-
17444412721
-
Electrochemistry of ITO Electrode Modified by Multilayer Ultrathin Films Based on Crown-Shaped Polyoxomolybdate
-
Wang, L.; Xiao, D.; Wang, E.; Xu, L. Electrochemistry of ITO Electrode Modified by Multilayer Ultrathin Films Based on Crown-Shaped Polyoxomolybdate. J. Colloid interface Sci. 2005, 285, 435-442.
-
(2005)
J. Colloid interface Sci
, vol.285
, pp. 435-442
-
-
Wang, L.1
Xiao, D.2
Wang, E.3
Xu, L.4
-
23
-
-
23744469722
-
Thermally Enhanced Visible-Light Photochromism of Phosphomolybdic Acid-Polyvinylpyrrolidone Hybrid Films
-
Zhang, G.; Yang, W.; Yao, J. Thermally Enhanced Visible-Light Photochromism of Phosphomolybdic Acid-Polyvinylpyrrolidone Hybrid Films. Adv. Funct. Mater. 2005, 15, 1255-1259.
-
(2005)
Adv. Funct. Mater
, vol.15
, pp. 1255-1259
-
-
Zhang, G.1
Yang, W.2
Yao, J.3
-
24
-
-
36249025198
-
-
Nelson, C. B.; Vyas, R. N.; Mou, Y.; Li, K.; Rabalais, J. W.; Irwin, G. M.; Wang, B. Doping Poly( p-Phenylene Vinylene) with Phosphomolybdate through Layer-by-Layer Fabrication for Optoelectronic Applications. J. Appl. Phys. 2007, 102, 0943091-0943096.
-
Nelson, C. B.; Vyas, R. N.; Mou, Y.; Li, K.; Rabalais, J. W.; Irwin, G. M.; Wang, B. Doping Poly( p-Phenylene Vinylene) with Phosphomolybdate through Layer-by-Layer Fabrication for Optoelectronic Applications. J. Appl. Phys. 2007, 102, 0943091-0943096.
-
-
-
-
25
-
-
10444227451
-
Electrchromic Multilayer Films Based on Trilacunary Dawson-Type Polyoxometalate
-
Gao, G.; Xu, L.; Wang, W.; Wang, Z.; Qiu, Y.; Wang, E. Electrchromic Multilayer Films Based on Trilacunary Dawson-Type Polyoxometalate. Electrochim. Acta 2005, 50, 1101-1106.
-
(2005)
Electrochim. Acta
, vol.50
, pp. 1101-1106
-
-
Gao, G.1
Xu, L.2
Wang, W.3
Wang, Z.4
Qiu, Y.5
Wang, E.6
-
26
-
-
34250010358
-
Spin Qubits with Electrically Gated Polyoxometalate Molecules
-
Lehmann, J.; Gaita-Arino, A.; Coronado, E.; Loss, D. Spin Qubits with Electrically Gated Polyoxometalate Molecules. Nat. Nanotechnol. 2007, 2, 312-317.
-
(2007)
Nat. Nanotechnol
, vol.2
, pp. 312-317
-
-
Lehmann, J.1
Gaita-Arino, A.2
Coronado, E.3
Loss, D.4
-
27
-
-
0031677639
-
Polyoxometalate-Based Molecular Materials
-
Coronado, E.; Gomez-Garcia, C. J. Polyoxometalate-Based Molecular Materials. Chem. Rev. 1998, 98, 273-296.
-
(1998)
Chem. Rev
, vol.98
, pp. 273-296
-
-
Coronado, E.1
Gomez-Garcia, C.J.2
-
28
-
-
0031647244
-
Photo- and Electrochromism of Polyoxometalates and Related Materials
-
Yamase, T. Photo- and Electrochromism of Polyoxometalates and Related Materials. Chem. Rev. 1998, 98, 307-325.
-
(1998)
Chem. Rev
, vol.98
, pp. 307-325
-
-
Yamase, T.1
-
29
-
-
0037384503
-
In Situ Controllable Synthesis of Polyoxometalate Nanoparticles in Polyelectrolyte Muitiiayers
-
Jiang, M.; Wang, E.; Kang, Z.; Lian, S.; Wu, A.; Li, Z. In Situ Controllable Synthesis of Polyoxometalate Nanoparticles in Polyelectrolyte Muitiiayers. J. Mater. Chem. 2003, 13, 647-649.
-
(2003)
J. Mater. Chem
, vol.13
, pp. 647-649
-
-
Jiang, M.1
Wang, E.2
Kang, Z.3
Lian, S.4
Wu, A.5
Li, Z.6
-
30
-
-
0141972588
-
Fabrication of a Metalloporphyrin-Polyoxometalate Hybrid Film by a Layer-by-Layer Method and Its Catalysis for Hydrogen Evolution and Dioxygen Reduction
-
Shen, Y.; Liu, J.; Jiang, J.; Liu, B.; Dong, S. Fabrication of a Metalloporphyrin-Polyoxometalate Hybrid Film by a Layer-by-Layer Method and Its Catalysis for Hydrogen Evolution and Dioxygen Reduction. J. Phys. Chem. B 2003, 107, 9744-9748.
-
(2003)
J. Phys. Chem. B
, vol.107
, pp. 9744-9748
-
-
Shen, Y.1
Liu, J.2
Jiang, J.3
Liu, B.4
Dong, S.5
-
31
-
-
13844319125
-
Layer-by-Layer Self-Assembly of Dye-Polyoxometaiate Multilayer Composite Films and Their Fluorescent Properties
-
Wang, Y.; Hu, C. Layer-by-Layer Self-Assembly of Dye-Polyoxometaiate Multilayer Composite Films and Their Fluorescent Properties. Thin Solid Films 2005, 476, 84-91.
-
(2005)
Thin Solid Films
, vol.476
, pp. 84-91
-
-
Wang, Y.1
Hu, C.2
-
33
-
-
0032668112
-
Formation of a Self-Assembled Monolayer of Diaminododecane and a Heteropolyacid Monolayer on the ITO Surface
-
Oh, S.-Y.; Yun, Y.-J.; Kim, D.-Y.; Han, S.-H. Formation of a Self-Assembled Monolayer of Diaminododecane and a Heteropolyacid Monolayer on the ITO Surface. Langmuir 1999, 15, 4690-4692.
-
(1999)
Langmuir
, vol.15
, pp. 4690-4692
-
-
Oh, S.-Y.1
Yun, Y.-J.2
Kim, D.-Y.3
Han, S.-H.4
-
34
-
-
0030848621
-
Fuzzy Nanoassemblies: Towards Layered Polymeric Multicomposites
-
Decher, G. Fuzzy Nanoassemblies: Towards Layered Polymeric Multicomposites. Science 1997, 277, 1232-1237.
-
(1997)
Science
, vol.277
, pp. 1232-1237
-
-
Decher, G.1
-
35
-
-
0001331987
-
Electrically Conductive Langmuir-Blodgett Films of Charge-Transfer Materials
-
Bryce, M. R.; Petty, M. C. Electrically Conductive Langmuir-Blodgett Films of Charge-Transfer Materials. Nature 1995, 374, 771-776.
-
(1995)
Nature
, vol.374
, pp. 771-776
-
-
Bryce, M.R.1
Petty, M.C.2
-
36
-
-
21344465641
-
Polyoxometalate Monolayers in Langmuir-Blodgett Films
-
Clemente-León, M.; Coronado, E.; Gómez-Garcia, C. J.; Mingotaud, C.; Ravaine, S.; Romualdo-Torres, G.; Delhaès, P. Polyoxometalate Monolayers in Langmuir-Blodgett Films. Chem. Eur. J. 2005, 11, 3979-3987.
-
(2005)
Chem. Eur. J
, vol.11
, pp. 3979-3987
-
-
Clemente-León, M.1
Coronado, E.2
Gómez-Garcia, C.J.3
Mingotaud, C.4
Ravaine, S.5
Romualdo-Torres, G.6
Delhaès, P.7
-
37
-
-
46849088865
-
Polyoxometalates in Memory Devices
-
International Patent Application, PCT, WO 2007/015010 A1, 07/02/2007
-
Bidan, G.; Jalaguier, E. Polyoxometalates in Memory Devices. International Patent Application, (PCT), WO 2007/015010 A1, 07/02/2007.
-
-
-
Bidan, G.1
Jalaguier, E.2
-
38
-
-
0042627818
-
Tunneling Transport in Polyoxometalate Based Composite Materials
-
Glezos, N.; Argitis, P.; Velessiotis, D.; Diakoumakos, C. D. Tunneling Transport in Polyoxometalate Based Composite Materials. Appl. Phys. Lett. 2003, 83, 488-490.
-
(2003)
Appl. Phys. Lett
, vol.83
, pp. 488-490
-
-
Glezos, N.1
Argitis, P.2
Velessiotis, D.3
Diakoumakos, C.D.4
-
39
-
-
27744476269
-
-
Velessiotis, D.; Glezos, N.; loannou-Sougleridis, V. Tungstate Polyoxometalates as Active Components of Molecular Devices. J. Appl. Phys. 2005, 98, 0845031-0845034.
-
Velessiotis, D.; Glezos, N.; loannou-Sougleridis, V. Tungstate Polyoxometalates as Active Components of Molecular Devices. J. Appl. Phys. 2005, 98, 0845031-0845034.
-
-
-
-
40
-
-
0030084093
-
Semiconductor Clusters, Nanocrystals, and Quantum Dots
-
Alivisatos, A. P. Semiconductor Clusters, Nanocrystals, and Quantum Dots. Science 1996, 271, 933-937.
-
(1996)
Science
, vol.271
, pp. 933-937
-
-
Alivisatos, A.P.1
-
41
-
-
34249699048
-
Spectroelectrochemistry of Carbon Nanostructures
-
Kavan, L.; Dunsch, L. Spectroelectrochemistry of Carbon Nanostructures. Chem. Phys. Chem. 2007, 8, 974-998.
-
(2007)
Chem. Phys. Chem
, vol.8
, pp. 974-998
-
-
Kavan, L.1
Dunsch, L.2
-
42
-
-
33750260088
-
Synthesis, Structure and Properties of Metal Nanoclusters
-
Wilcoxon, J. P.; Abrams, B. L. Synthesis, Structure and Properties of Metal Nanoclusters. Chem. Soc. Rev. 2006, 35, 1162-1194.
-
(2006)
Chem. Soc. Rev
, vol.35
, pp. 1162-1194
-
-
Wilcoxon, J.P.1
Abrams, B.L.2
-
43
-
-
33646522949
-
Electrical Characterization of Molecular Monolayers Containing Tungsten Polyoxometalates
-
Glezos, N.; Douvas, A. M.; Argitis, P.; Saurenbach, F.; Chrost, J.; Livitsanos, C. Electrical Characterization of Molecular Monolayers Containing Tungsten Polyoxometalates. Microelectron. Eng. 2006, 83, 1757-1760.
-
(2006)
Microelectron. Eng
, vol.83
, pp. 1757-1760
-
-
Glezos, N.1
Douvas, A.M.2
Argitis, P.3
Saurenbach, F.4
Chrost, J.5
Livitsanos, C.6
-
44
-
-
1442275388
-
A Monolithic Silicon Optoelectronic Transducer as a Real-Time Affinity Biosensor
-
Misiakos, K.; Kakabakos, S. E.; Petrou, P. S.; Ruf, H. H. A Monolithic Silicon Optoelectronic Transducer as a Real-Time Affinity Biosensor. Anal. Chem. 2004, 76, 1366-1373.
-
(2004)
Anal. Chem
, vol.76
, pp. 1366-1373
-
-
Misiakos, K.1
Kakabakos, S.E.2
Petrou, P.S.3
Ruf, H.H.4
-
45
-
-
46849107206
-
-
The OMCT absorption band is due to the promotion of electrons from the high energy electronic states of HOMO to the low energy electronic states of LUMO of POM
-
The OMCT absorption band is due to the promotion of electrons from the high energy electronic states of HOMO to the low energy electronic states of LUMO of POM.
-
-
-
-
46
-
-
33845550546
-
Vibrational Investigations of Polyoxometalates. 2. Evidence for Anion-Anion Interactions in Molybdenum(VI) and Tungsten(VI) Compounds Related to the Keggin Structure
-
Rocchiccioli-Deltcheff, C.; Fournier, M.; Franck R.; Thouvenot, R. Vibrational Investigations of Polyoxometalates. 2. Evidence for Anion-Anion Interactions in Molybdenum(VI) and Tungsten(VI) Compounds Related to the Keggin Structure. Inorg. Chem. 1983, 22, 207-216.
-
(1983)
Inorg. Chem
, vol.22
, pp. 207-216
-
-
Rocchiccioli-Deltcheff, C.1
Fournier, M.2
Franck, R.3
Thouvenot, R.4
-
47
-
-
33845469996
-
Vibrational Investigations of Polyoxometalates. 3. Isomerism in Molybdenum(VI) and Tungsten(VI) Compounds Related to the Keggin Structure
-
Thouvenot, R.; Fournier, M.; Franck R.; Rocchiccioli-Deltcheff, C. Vibrational Investigations of Polyoxometalates. 3. Isomerism in Molybdenum(VI) and Tungsten(VI) Compounds Related to the Keggin Structure. Inorg. Chem. 1984, 23, 598-605.
-
(1984)
Inorg. Chem
, vol.23
, pp. 598-605
-
-
Thouvenot, R.1
Fournier, M.2
Franck, R.3
Rocchiccioli-Deltcheff, C.4
-
48
-
-
0037014688
-
-
Ganapathy, S, Fournier, M, Paul, J. F, Delevoye, L, Guelton, M, Amoureux, J. P. Location of Protons in Anhydrous Keggin Heteropolyacids H3PMO12 O40 and H3PW12 O40 by 1H{31p} /31P{1H} REDOR NMR and DFT Quantum Chemical Calculations. J. Am. Chem. Soc. 2002, 124, 7821-7828
-
1H} REDOR NMR and DFT Quantum Chemical Calculations. J. Am. Chem. Soc. 2002, 124, 7821-7828.
-
-
-
-
49
-
-
0344873632
-
A Study of the Decomposition Behaviour of 12-Tungstophosphate Heteropolyacid in Solution
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Zhu, Z.; Tain, R.; Rhodes, C. A Study of the Decomposition Behaviour of 12-Tungstophosphate Heteropolyacid in Solution. Can. J. Chem. 2003, 81, 1044-1050.
-
(2003)
Can. J. Chem
, vol.81
, pp. 1044-1050
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Zhu, Z.1
Tain, R.2
Rhodes, C.3
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50
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46849114813
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The process conditions in the (a - c) cases of Figure 1 were the optimal conditions found: POM 0.1 M, aq, pH 0.5, rt, 20 min (rinsing: HCI 0.3 M, aq, pH 0.5); DD 0.01 M, aq, HCI 0.3 M, pH 0.5, rt, 20 min (rinsing: HCI 0.3 M, aq, pH 0.5). The POM-based multilayers were fabricated on an APTES adhesion layer.
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The process conditions in the (a - c) cases of Figure 1 were the optimal conditions found: POM 0.1 M, aq, pH 0.5, rt, 20 min (rinsing: HCI 0.3 M, aq, pH 0.5); DD 0.01 M, aq, HCI 0.3 M, pH 0.5, rt, 20 min (rinsing: HCI 0.3 M, aq, pH 0.5). The POM-based multilayers were fabricated on an APTES adhesion layer.
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51
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46849117404
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The distances (in Å) of the bonds in Figure 1b are experimental values obtained from refs 8, 48.
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The distances (in Å) of the bonds in Figure 1b are experimental values obtained from refs 8, 48.
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52
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46849099055
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-3 M, pH 2, rt, 20 min (rinsing: water, pH ≈ 7). The POM-based multilayers were fabricated on an APTES adhesion layer.
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-3 M, pH 2, rt, 20 min (rinsing: water, pH ≈ 7). The POM-based multilayers were fabricated on an APTES adhesion layer.
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53
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0001627102
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External Reflection Infrared Spectroscopy at Metallic, Semiconductor, and Nonmetallic Substrates. 1. Monolayer Films
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Mielczarski, J. A. External Reflection Infrared Spectroscopy at Metallic, Semiconductor, and Nonmetallic Substrates. 1. Monolayer Films. J. Phys. Chem. 1993, 97, 2649-2663.
-
(1993)
J. Phys. Chem
, vol.97
, pp. 2649-2663
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Mielczarski, J.A.1
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54
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0000020004
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Determination of Molecular Orientation and Thickness of Self-Assembled Monolayers of Oleate on Apatite by FTIR Reflection Spectroscopy
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Mielczarski, J. A.; Mielczarski, E. Determination of Molecular Orientation and Thickness of Self-Assembled Monolayers of Oleate on Apatite by FTIR Reflection Spectroscopy. J. Phys. Chem. 1995, 99, 3206-3217.
-
(1995)
J. Phys. Chem
, vol.99
, pp. 3206-3217
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Mielczarski, J.A.1
Mielczarski, E.2
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55
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46849096134
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In the transmission method the electric vectors of incident beam are positioned only parallel to the surface plane of sample. Hence, only the surface molecular groups that have dipole moments parallel to sample interface could produce an absorbance band. When the external reflection method is used there are electric vectors at the interface which are parallel to the interface (as in transmission method) and vertical to the interface depending on the angle of incident beam and polarization
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In the transmission method the electric vectors of incident beam are positioned only parallel to the surface plane of sample. Hence, only the surface molecular groups that have dipole moments parallel to sample interface could produce an absorbance band. When the external reflection method is used there are electric vectors at the interface which are parallel to the interface (as in transmission method) and vertical to the interface depending on the angle of incident beam and polarization.
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56
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33846150054
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A DFT Study on the Effect of Metal, Anion Charge, Heteroatom and Structure upon the Relative Basicities of Polyoxoanions
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Fernández, J. A.; López, X.; Poblet, J. M. A DFT Study on the Effect of Metal, Anion Charge, Heteroatom and Structure upon the Relative Basicities of Polyoxoanions. J. Mol. Cotal, A 2007, 262, 236-242.
-
(2007)
J. Mol. Cotal, A
, vol.262
, pp. 236-242
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Fernández, J.A.1
López, X.2
Poblet, J.M.3
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57
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9144258943
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Generalized Formula for the Electric Tunnel Effect between Similar Electrodes Separated by a Thin Insulating Film
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Simmons, J. G. Generalized Formula for the Electric Tunnel Effect between Similar Electrodes Separated by a Thin Insulating Film. J. Appl. Phys. 1963, 34, 1793-1803.
-
(1963)
J. Appl. Phys
, vol.34
, pp. 1793-1803
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-
Simmons, J.G.1
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58
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0242368154
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Electronic Injection and Conduction Processes for Polymer Devices
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Braun, D. Electronic Injection and Conduction Processes for Polymer Devices. J. Polym. Sci., Part B 2003, 41, 2622-2629.
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(2003)
J. Polym. Sci., Part B
, vol.41
, pp. 2622-2629
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Braun, D.1
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59
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0344110551
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Wang, W.; Lee, T.; Reed, M. A. Mechanism of Electron Conduction in Self-Assembled Alkanethiol Monolayer Devices. Phys. Rev. B 2003, 68, 0354161-0354167.
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Wang, W.; Lee, T.; Reed, M. A. Mechanism of Electron Conduction in Self-Assembled Alkanethiol Monolayer Devices. Phys. Rev. B 2003, 68, 0354161-0354167.
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60
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46849097674
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More details about the XPS spectra obtained are the following: The kinetic energy of the photoelectrons was determined with the hemispheric analyser set to the pass energy of 160 eV for wide scan spectra and 20 eV for high resolution spectra. The electrostatic charge effect of the sample was overcompensated by means of the low-energy electron source working in combination with a magnetic immersion lens. Quantitative elemental compositions were determined from peak areas using experimentally determined sensitivity factors and the spectrometer transmission function. Spectrum background was subtracted according to Shirley. The high resolution spectra were analysed by means of spectra cleconvolution software (Vision 2, Kratos Analytical, U.K.).
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More details about the XPS spectra obtained are the following: The kinetic energy of the photoelectrons was determined with the hemispheric analyser set to the pass energy of 160 eV for wide scan spectra and 20 eV for high resolution spectra. The electrostatic charge effect of the sample was overcompensated by means of the low-energy electron source working in combination with a magnetic immersion lens. Quantitative elemental compositions were determined from peak areas using experimentally determined sensitivity factors and the spectrometer transmission function. Spectrum background was subtracted according to Shirley. The high resolution spectra were analysed by means of spectra cleconvolution software (Vision 2, Kratos Analytical, U.K.).
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61
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46849095217
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The take-off angle is defined as the angle between the normal to the surface of the sample and the electron optical axis of the spectrometer. The effective information depth, varies according to d, do cos θ, where do is the maximum information depth do ≈ 10 nm for the C1s line by employing an Al Kα source
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o ≈ 10 nm for the C1s line by employing an Al Kα source).
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