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Volumn 98, Issue 1, 1998, Pages 273-296

Polyoxometalate-based molecular materials

Author keywords

[No Author keywords available]

Indexed keywords

CHARGE TRANSFER; ELECTRIC PROPERTIES; ELECTRONS; LANGMUIR BLODGETT FILMS; MAGNETIC PROPERTIES; MOLECULES; MULTILAYERS; NONLINEAR OPTICS; ORGANIC COMPOUNDS; ORGANIC POLYMERS; OXIDATION; SALTS;

EID: 0031677639     PISSN: 00092665     EISSN: None     Source Type: Journal    
DOI: 10.1021/cr970471c     Document Type: Article
Times cited : (1055)

References (124)
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    • See for example: (a) Coronado, E.; Galán Mascarós, J. R.; Giménez-Saiz, C.; Gómez-García, C. J. In Magnetism: A Supramolecular Function; NATO ASI Series; Kahn, O., Ed.; Kluwer Academic Publishers: Norwell, MA, 1996; Vol. C484, p 281, and references therein, (b) Ouahab, L. Chem. Mater. 1997, 9, 1909.
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    • See for example: (a) Coronado, E.; Galán Mascarós, J. R.; Giménez-Saiz, C.; Gómez-García, C. J. In Magnetism: A Supramolecular Function; NATO ASI Series; Kahn, O., Ed.; Kluwer Academic Publishers: Norwell, MA, 1996; Vol. C484, p 281, and references therein, (b) Ouahab, L. Chem. Mater. 1997, 9, 1909.
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    • Several short reviews have described the progress made by the combination of magnetic polyoxometalates with organic molecules: (a) Coronado, E.; Gómez-García, C. J. In Polyoxometalates: from Platonic Solids to Anti-retroviral activity; Pope, M. T., Müller, A., Eds.; Kluwer Academic Publishers: Norwell, MA, 1994; p 233. (b) Coronado, E.; Gómez-García, C. J. Comments Inorg. Chem. 1995, 17, 255. (c) Coronado, E.; Delhaes, P.; Galán Mascarós, J. R.; Giménez-Saiz, C.; Gómez-García, C. J. Synth. Met. 1997, 85, 1647.
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    • Several short reviews have described the progress made by the combination of magnetic polyoxometalates with organic molecules: (a) Coronado, E.; Gómez-García, C. J. In Polyoxometalates: from Platonic Solids to Anti-retroviral activity; Pope, M. T., Müller, A., Eds.; Kluwer Academic Publishers: Norwell, MA, 1994; p 233. (b) Coronado, E.; Gómez-García, C. J. Comments Inorg. Chem. 1995, 17, 255. (c) Coronado, E.; Delhaes, P.; Galán Mascarós, J. R.; Giménez-Saiz, C.; Gómez-García, C. J. Synth. Met. 1997, 85, 1647.
    • (1995) Comments Inorg. Chem. , vol.17 , pp. 255
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    • Several short reviews have described the progress made by the combination of magnetic polyoxometalates with organic molecules: (a) Coronado, E.; Gómez-García, C. J. In Polyoxometalates: from Platonic Solids to Anti-retroviral activity; Pope, M. T., Müller, A., Eds.; Kluwer Academic Publishers: Norwell, MA, 1994; p 233. (b) Coronado, E.; Gómez-García, C. J. Comments Inorg. Chem. 1995, 17, 255. (c) Coronado, E.; Delhaes, P.; Galán Mascarós, J. R.; Giménez-Saiz, C.; Gómez-García, C. J. Synth. Met. 1997, 85, 1647.
    • (1997) Synth. Met. , vol.85 , pp. 1647
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    • An authoritative overview presenting the evolution and the recent achievements in the field of the molecular conductors and superconductors can be found in ref 1d.
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    • A general presentation of the chemistry, properties, and applications of polyoxometalates can be found in the following references: (a) Pope, M. T., Heteropoly and Isopoly Oxometalates; Springer-Verlag: Berlin, 1983. (b) Pope, M. T.; Müller, A. Angew. Chem., Int. Ed. Engl. 1991, 30, 34. (c) Polyoxometalates: from Platonic Solids to Anti-retroviral activity; Pope, M. T., Müller, A., Eds.; Kluwer Academic Publishers: Norwell, MA, 1994.
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    • A general presentation of the chemistry, properties, and applications of polyoxometalates can be found in the following references: (a) Pope, M. T., Heteropoly and Isopoly Oxometalates; Springer-Verlag: Berlin, 1983. (b) Pope, M. T.; Müller, A. Angew. Chem., Int. Ed. Engl. 1991, 30, 34. (c) Polyoxometalates: from Platonic Solids to Anti-retroviral activity; Pope, M. T., Müller, A., Eds.; Kluwer Academic Publishers: Norwell, MA, 1994.
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    • A general presentation of the chemistry, properties, and applications of polyoxometalates can be found in the following references: (a) Pope, M. T., Heteropoly and Isopoly Oxometalates; Springer-Verlag: Berlin, 1983. (b) Pope, M. T.; Müller, A. Angew. Chem., Int. Ed. Engl. 1991, 30, 34. (c) Polyoxometalates: from Platonic Solids to Anti-retroviral activity; Pope, M. T., Müller, A., Eds.; Kluwer Academic Publishers: Norwell, MA, 1994.
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    • note
    • 12] series, are still too long to allow for effective d-π interaction since the octahedral sites where the magnetic ions are located are the ones that are most distant from the ET molecules.
  • 84
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    • note
    • + salt the substituted Keggin anions of MnII are present as discrete units, and therefore the Mn octahedral site has a smaller axial elongation than in the ET salt (the differences between the two salts in the metal-oxygen axial distances are around 0.2 Å)
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    • note
    • 4- for instance) there is no cathodic reduction of the anions since the working potential is too small.


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