Rate-enhancing roles of water molecules in methyltrioxorhenium-catalyzed olefin epoxidation by hydrogen peroxide

Journal of the American Chemical Society

Volumn 137, Issue 30, 2015, Pages 9604-9616

  Goldsmith, Bryan R ^a   Hwang, Taeho ^a   Seritan, Stefan ^b   Peters, Baron ^a,b   Scott, Susannah L ^a,b  

^a University of California   (United States)

^b UNIVERSITY OF CALIFORNIA   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

CATALYSIS; COORDINATION REACTIONS; HYDROGEN BONDS; ISOTOPES; LIGANDS; OLEFINS; RHENIUM; RHENIUM COMPOUNDS;

ACTIVATION PARAMETER; AQUEOUS ACETONITRILE; CATALYTIC CYCLES; CO-CATALYTIC EFFECT; KINETIC ISOTOPE EFFECTS; METHYLTRIOXORHENIUM; OLEFIN EPOXIDATION; RELATIVE ABUNDANCE;

MOLECULES;

ACETONITRILE; ALKENE; CYCLOHEXENE DERIVATIVE; EPOXIDE; HYDROGEN PEROXIDE; ISOTOPE; METHYLTRIOXORHENIUM; ORGANOMETALLIC COMPOUND; PROTON; SOLVENT; UNCLASSIFIED DRUG; WATER; METHYLTRIOXORHENIUM VII;

ARTICLE; CATALYSIS; CHEMICAL REACTION; COMPLEX FORMATION; DENSITY FUNCTIONAL THEORY; EPOXIDATION; HYDROGEN BOND; HYDROLYSIS; KINETICS; MATHEMATICAL ANALYSIS; PROTON TRANSPORT; QUANTITATIVE ANALYSIS; SIMULATION; STEADY STATE; CHEMISTRY; CONFORMATION; MOLECULAR DYNAMICS; QUANTUM THEORY; SYNTHESIS;

ALKENES; CATALYSIS; EPOXY COMPOUNDS; HYDROGEN PEROXIDE; MOLECULAR CONFORMATION; MOLECULAR DYNAMICS SIMULATION; ORGANOMETALLIC COMPOUNDS; QUANTUM THEORY; WATER;

EID: 84938854569     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/jacs.5b03750     Document Type: Article

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