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Volumn 120, Issue 44, 1998, Pages 11335-11341

Effects of pyridine and its derivatives on the equilibria and kinetics pertaining to epoxidation reactions catalyzed by methyltrioxorhenium

Author keywords

[No Author keywords available]

Indexed keywords

HYDROGEN PEROXIDE; PYRIDINE DERIVATIVE; RHENIUM;

EID: 0032508935     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja9813414     Document Type: Article
Times cited : (109)

References (30)
  • 4
    • 3643147875 scopus 로고    scopus 로고
    • note
    • The quality of the NMR kinetic data with 1.3 mM α-methylstyrene was not as good as those with 0.32 M α-methylstyrene owing to the error associated with the integration of small signals. As pointed out by one reviewer, the initial rate method using the NMR spectrometer could cause a problem, particularly when the signals of reactants and products are not fully resolved. Reasonable kinetic data could be obtained if one integrates the signals of products rather than those of the reactants and uses an internal standard with an intensity similar to that of the products.
  • 16
    • 3643084356 scopus 로고
    • Klingsberg, E., Ed.; Interscience Publishers: New York
    • Shaw, E. N. In Heterocyclic Compound - Pyridine and Derivatives; Klingsberg, E., Ed.; Interscience Publishers: New York, 1961; Part II, p 117.
    • (1961) Heterocyclic Compound - Pyridine and Derivatives , Issue.2 PART , pp. 117
    • Shaw, E.N.1
  • 21
    • 3643122899 scopus 로고    scopus 로고
    • note
    • -1.
  • 27
    • 0029368868 scopus 로고
    • Al-Ajlouni, A.; Espenson, J. H. J. Am. Chem. Soc. 1995, 117, 9243-9250. The inhibitor present in a-methylstyrene, p-tert-butylcatechol, did not affect the kinetics in the studies reported in this reference. As pointed out by one reviewer, a problem might exist in the present work, but that seems unlikely considering that the data for α-methylstryene were independent of concentration (Table 3).
    • (1995) J. Am. Chem. Soc. , vol.117 , pp. 9243-9250
    • Al-Ajlouni, A.1    Espenson, J.H.2
  • 30
    • 3643118742 scopus 로고    scopus 로고
    • note
    • 2; see ref 3 as well.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.