Proposed Ligand-Centered Electrocatalytic Hydrogen Evolution and Hydrogen Oxidation at a Noninnocent Mononuclear Metal-Thiolate

Journal of the American Chemical Society

Volumn 137, Issue 29, 2015, Pages 9238-9241

  Haddad, Andrew Z ^a   Kumar, Davinder ^a   Ouch Sampson, Kagna ^a   Matzner, Anna M ^a   Mashuta, Mark S ^a   Grapperhaus, Craig A ^a  

^a UNIVERSITY OF LOUISVILLE   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

CATALYTIC OXIDATION; CRYSTAL STRUCTURE; DICHLOROMETHANE; ELECTROCATALYSIS; ELECTROCATALYSTS; ETHYLENE; HYDRIDES; ISOTOPES; LIGANDS; OXIDATION; RATE CONSTANTS; REACTION INTERMEDIATES;

ACID CONCENTRATIONS; CATALYST CONCENTRATION; FIRST-ORDER DEPENDENCE; KINETIC ISOTOPE EFFECTS; METAL HYDRIDE INTERMEDIATES; SECOND-ORDER DEPENDENCE; TURNOVER FREQUENCY; X RAY CRYSTAL STRUCTURES;

HYDROGEN;

DICHLOROMETHANE; ETHYLENE; HYDROGEN; LIGAND; METAL COMPLEX; SULFURIC ACID; THIOL DERIVATIVE;

ARTICLE; CATALYSIS; CATALYST; COMPARATIVE STUDY; CONTROLLED STUDY; CRYSTAL STRUCTURE; CYCLIC POTENTIOMETRY; ELECTROLYSIS; GAS CHROMATOGRAPHY; HYDROGEN EVOLUTION; OBSERVED RATE CONSTANT; OXIDATION; REDUCTION; X RAY ANALYSIS; X RAY CRYSTALLOGRAPHY;

EID: 84938381839     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/jacs.5b05561     Document Type: Article

References (40)

1. Lewis, N. S.; Nocera, D. G. Proc. Natl. Acad. Sci. U. S. A. 2006, 103, 15729-15735 10.1073/pnas.0603395103
2. Barton, B. E.; Olsen, M. T.; Rauchfuss, T. B. Curr. Opin. Biotechnol. 2010, 21, 292-297 10.1016/j.copbio.2010.03.003
3. Darensbourg, M. Y.; Lyon, E. J.; Zhao, X.; Georgakaki, I. P. Proc. Natl. Acad. Sci. U. S. A. 2003, 100, 3683-3688 10.1073/pnas.0536955100
4. Fontecilla-Camps, J. C.; Volbeda, A.; Cavazza, C.; Nicolet, Y. Chem. Rev. 2007, 107, 4273-4303 10.1021/cr050195z
5. Shima, S.; Pilak, O.; Vogt, S.; Schick, M.; Stagni, M. S.; Meyer-Klaucke, W.; Warkentin, E.; Thauer, R. K.; Ermler, U. Science 2008, 321, 572-575 10.1126/science.1158978
6. Jacobsen, G. M.; Yang, J. Y.; Twamley, B.; Wilson, A. D.; Bullock, R. M.; DuBois, M. R.; DuBois, D. L. Energy Environ. Sci. 2008, 1, 167-174 10.1039/b805309j
7. Rakowski Dubois, M.; Dubois, D. L. Acc. Chem. Res. 2009, 42, 1974-1982 10.1021/ar900110c
8. Wiedner, E. S.; Yang, J. Y.; Dougherty, W. G.; Kassel, W. S.; Bullock, R. M.; DuBois, M. R.; DuBois, D. L. Organometallics 2010, 29, 5390-5401 10.1021/om100395r
9. Wiese, S.; Kilgore, U. J.; DuBois, D. L.; Bullock, R. M. ACS Catal. 2012, 2, 720-727 10.1021/cs300019h
10. Gan, L.; Groy, T. L.; Tarakeshwar, P.; Mazinani, S. K. S.; Shearer, J.; Mujica, V.; Jones, A. K. J. Am. Chem. Soc. 2015, 137, 1109-1115 10.1021/ja509779q
11. Karunadasa, H. I.; Chang, C. J.; Long, J. R. Nature 2010, 464, 1329-1333 10.1038/nature08969
12. McNamara, W. R.; Han, Z. J.; Alperin, P. J.; Brennessel, W. W.; Holland, P. L.; Eisenberg, R. J. Am. Chem. Soc. 2011, 133, 15368-15371 10.1021/ja207842r
13. McNamara, W. R.; Han, Z. J.; Yin, C. J.; Brennessel, W. W.; Holland, P. L.; Eisenberg, R. Proc. Natl. Acad. Sci. U. S. A. 2012, 109, 15594-15599 10.1073/pnas.1120757109
14. Singh, W. M.; Baine, T.; Kudo, S.; Tian, S. L.; Ma, X. A. N.; Zhou, H. Y.; DeYonker, N. J.; Pham, T. C.; Bollinger, J. C.; Baker, D. L.; Yan, B.; Webster, C. E.; Zhao, X. Angew. Chem., Int. Ed. 2012, 51, 5941-5944 10.1002/anie.201200082
15. Zarkadoulas, A.; Koutsouri, E.; Mitsopoulou, C. A. Coord. Chem. Rev. 2012, 256, 2424-2434 10.1016/j.ccr.2012.04.016
16. Weber, K.; Krämer, T.; Shafaat, H. S.; Weyhermüller, T.; Bill, E.; van Gastel, M.; Neese, F.; Lubitz, W. J. Am. Chem. Soc. 2012, 134, 20745-20755 10.1021/ja309563p
17. Wilson, A. D.; Newell, R. H.; McNevin, M. J.; Muckerman, J. T.; DuBois, M. R.; DuBois, D. L. J. Am. Chem. Soc. 2006, 128, 358-366 10.1021/ja056442y
18. Grapperhaus, C. A.; Ouch, K.; Mashuta, M. S. J. Am. Chem. Soc. 2009, 131, 64-65 10.1021/ja8086483
19. Ouch, K.; Mashuta, M. S.; Grapperhaus, C. A. Inorg. Chem. 2011, 50, 9904-9914 10.1021/ic200416y
20. Grapperhaus, C. A.; Kozlowski, P. M.; Kumar, D.; Frye, H. N.; Venna, K. B.; Poturovic, S. Angew. Chem., Int. Ed. 2007, 46, 4085-4088 10.1002/anie.200700297
21. Grapperhaus, C. A.; Poturovic, S. Inorg. Chem. 2004, 43, 3292-3298 10.1021/ic035085u
22. Andrieux, C. P.; Blocman, C.; Dumasbouchiat, J. M.; Mhalla, F.; Saveant, J. M. J. Electroanal. Chem. Interfacial Electrochem. 1980, 113, 19-40 10.1016/S0022-0728(80)80508-0
23. Felton, G. A. N.; Vannucci, A. K.; Chen, J. Z.; Lockett, L. T.; Okumura, N.; Petro, B. J.; Zakai, U. I.; Evans, D. H.; Glass, R. S.; Lichtenberger, D. L. J. Am. Chem. Soc. 2007, 129, 12521-12530 10.1021/ja073886g
24. Fourmond, V.; Jacques, P. A.; Fontecave, M.; Artero, V. Inorg. Chem. 2010, 49, 10338-10347 10.1021/ic101187v
25. Saveant, J. M.; Su, K. B. J. Electroanal. Chem. Interfacial Electrochem. 1984, 171, 341-349 10.1016/0022-0728(84)80125-4
26. Darmon, J. M.; Raugei, S.; Liu, T.; Hulley, E. B.; Weiss, C. J.; Bullock, R. M.; Helm, M. L. ACS Catal. 2014, 4, 1246-1260 10.1021/cs500290w
27. Roberts, J. A. S.; Bullock, R. M. Inorg. Chem. 2013, 52, 3823-3835 10.1021/ic302461q
28. Hu, X. L.; Brunschwig, B. S.; Peters, J. C. J. Am. Chem. Soc. 2007, 129, 8988-8998 10.1021/ja067876b
29. Appel, A. M.; DuBois, D. L.; DuBois, M. R. J. Am. Chem. Soc. 2005, 127, 12717-12726 10.1021/ja054034o
30. Marinescu, S. C.; Winkler, J. R.; Gray, H. B. Proc. Natl. Acad. Sci. U. S. A. 2012, 109, 15127-15131 10.1073/pnas.1213442109
31. Kotani, H.; Hanazaki, R.; Ohkubo, K.; Yamada, Y.; Fukuzumi, S. Chem.-Eur. J. 2011, 17, 2777-2785 10.1002/chem.201002399
32. Fukuzumi, S.; Kobayashi, T.; Suenobu, T. J. Am. Chem. Soc. 2010, 132, 1496-1497 10.1021/ja910349w
33. Sellmann, D.; Mahr, G.; Knoch, F.; Moll, M. Inorg. Chim. Acta 1994, 224, 45-59 10.1016/0020-1693(94)04015-X
34. Zhong, F.; Lisi, G. P.; Collins, D. P.; Dawson, J. H.; Pletneva, E. V. Proc. Natl. Acad. Sci. U. S. A. 2014, 111, E306-315 10.1073/pnas.1317173111
35. Dilworth, J. R.; Hutson, A. J.; Morton, S.; Harman, M.; Hursthouse, M. B.; Zubieta, J.; Archer, C. M.; Kelly, J. D. Polyhedron 1992, 11, 2151-2155 10.1016/S0277-5387(00)83689-X
36. Crystal data for [Re(LH)L2]PF6: purple prism, monoclinic, space group P21/c, a = 9.59553(9) Å, b = 33.0018(3) Å, c = 15.41951(15) Å, α = 90°, β = 97.5416(10)°, γ = 90°, V = 4840.66(8) Å3, rcalcd = 1.663 Mg/m3, Z = 4. Data were collected on an Agilent Technologies Gemini CCD diffractometer using Mo Ka radiation. For all 13,986 unique reflections [R(int) = 0.0281], the final anisotropic full-matrix least-squares refinement on F2 for 598 variables converged at R1 = 0.033, wR2 = 0.078 with a GOF of 1.09. CCDC 1403507 and 1410091 contain supplementary crystallographic data.
37. Hoffman, D. M.; Lappas, D.; Putilina, E. Inorg. Chem. 1992, 31, 79-81 10.1021/ic00027a015
38. Gusev, D. G.; Nietlispach, D.; Eremenko, I. L.; Berke, H. Inorg. Chem. 1993, 32, 3628-3636 10.1021/ic00069a015
39. Lu, M.; Campbell, J. L.; Chauhan, R.; Grapperhaus, C. A.; Chen, H. J. Am. Soc. Mass Spectrom. 2013, 24, 502-512 10.1007/s13361-012-0537-1
40. Yan, Y.; Xia, B.; Xu, Z.; Wang, X. ACS Catal. 2014, 4, 1693-1705 10.1021/cs500070x