Influence of support morphology on the bonding of molecules to nanoparticles

Proceedings of the National Academy of Sciences of the United States of America

Volumn 112, Issue 26, 2015, Pages 7903-7908

  Yim, Chi Ming ^a   Pang, Chi L ^a   Hermoso, Diego R ^b   Dover, Coinneach M ^a,f   Muryn, Christopher A ^c   Maccherozzi, Francesco ^d   Dhesi, Sarnjeet S ^d   Pérez, Rubén ^b,e   Thornton, Geoff ^a  

^a UNIVERSITY COLLEGE LONDON   (United Kingdom)

^b UNIVERSIDAD AUTÓNOMA DE MADRID   (Spain)

^c UNIVERSITY OF MANCHESTER   (United Kingdom)

^d DIAMOND LIGHT SOURCE LTD   (United Kingdom)

^e Ciudad Universitaria de Cantoblanco   (Spain)

^f UNIVERSITY OF EDINBURGH   (United Kingdom)

Author keywords

Adsorption; Carpet growth; Nanoparticle; Scanning tunneling microscopy; Surface strain

Indexed keywords

NANOPARTICLE; PALLADIUM; PALLADIUM NANOPARTICLE; UNCLASSIFIED DRUG;

ADSORPTION; ARTICLE; AUGER ELECTRON SPECTROSCOPY; CALORIMETRY; CATALYST; CHEMICAL BINDING; CONTROLLED STUDY; ELECTRON DIFFRACTION; ELECTRON MICROSCOPY; MOLECULE; PARTICLE SIZE; PRIORITY JOURNAL; SCANNING TUNNELING MICROSCOPY; X RAY ABSORPTION SPECTROSCOPY; X RAY PHOTOELECTRON SPECTROSCOPY;

EID: 84937822290     PISSN: 00278424     EISSN: 10916490     Source Type: Journal    
DOI: 10.1073/pnas.1506939112     Document Type: Article

References (45)

1. Zhdanov VP, Kasemo B (2000) Simulations of the reaction kinetics on nanometer supported catalyst particles. Surf Sci Rep 39(2):25-104.
2. Tauster SJ (1987) Strong metal-support interactions. Acc Chem Res 20(11):389-394.
3. Jackson SD, Hargreaves JSJ (2008) Metal Oxide Catalysis (Wiley, Weinheim, Germany).
4. Robel I, Kuno M, Kamat PV (2007) Size-dependent electron injection from excited CdSe quantum dots into TiO2 nanoparticles. J Am Chem Soc 129(14):4136-4137.
5. Haruta M, et al. (1993) Low-temperature oxidation of CO over gold supported on TiO2, α-Fe2O3, and Co3O4. J Catal 144(1):175-192.
6. Tao F, Ma Z (2013) Water-gas shift on gold catalysts: Catalyst systems and fundamental studies. Phys Chem Chem Phys 15(37):15260-15270.
7. Choudhary VR, Dumbre DK (2009) Supported nano-gold catalysts for epoxidation of styrene and oxidation of benzyl alcohol to benzaldehyde. Top Catal 52(12):1677-1687.
8. Kaden WE, Wu T, Kunkel WA, Anderson SL (2009) Electronic structure controls reactivity of size-selected Pd clusters adsorbed on TiO2 surfaces. Science 326(5954):826-829.
9. Herzing AA, Kiely CJ, Carley AF, Landon P, Hutchings GJ (2008) Identification of active gold nanoclusters on iron oxide supports for CO oxidation. Science 321(5894):1331-1335.
10. Ludwig W, Savara A, Schauermann S, Freund H-J (2010) Role of low-coordinated surface sites in olefin hydrogenation: A molecular beam study on Pd nanoparticles and Pd(111). ChemPhysChem 11(11):2319-2322.
11. Green IX, Tang W, Neurock M, Yates JT, Jr (2011) Spectroscopic observation of dual catalytic sites during oxidation of CO on a Au/TiO2 catalyst. Science 333(6043):736-739.
12. Nepijko SA, et al. (1999) Structural investigation of palladium clusters on gamma-Al2O3(111)/NiAl(110) with transmission electron microscopy. Langmuir 15(16):5309-5313.
13. Yudanov IV, Metzner M, Genest A, Rösch N (2008) Size-dependence of adsorption properties of metal nanoparticles: A density functional study on palladium nanoclusters. J Phys Chem C 112(51):20269-20275.
14. Fischer-Wolfarth J-H, et al. (2010) Particle-size dependent heats of adsorption of CO on supported Pd nanoparticles as measured with a single-crystal microcalorimeter. Phys Rev B 81(24):241416.
15. Peter M, Adamovsky S, Flores-Camacho JM, Schauermann S (2013) Energetics of elementary reaction steps relevant for CO oxidation: CO and O2 adsorption on model Pd nanoparticles and Pd(111). Faraday Discuss 162:341-354.
16. Peter M, et al. (2013) Trends in der Bindungsstärke von Oberflächenspezies auf Nanopartikeln: Wie verändert sich die Adsorptionsenergie mit der Partikelgröße? Angew Chem 125(19):5282-5287.
17. Campbell CT, Sellers JRV (2013) Anchored metal nanoparticles: Effects of support and size on their energy, sintering resistance and reactivity. Faraday Discuss 162:9-30.
18. Yoon B, et al. (2005) Charging effects on bonding and catalyzed oxidation of CO on Au8 clusters on MgO. Science 307(5708):403-407.
19. Farmer JA, Campbell CT (2010) Ceria maintains smaller metal catalyst particles by strong metal-support bonding. Science 329(5994):933-936.
20. Bowker M, et al. (2005) Model catalyst studies of the strong metal-support interaction: Surface structure identified by STM on Pd nanoparticles on TiO2 (110). J Catal 234(1):172-181.
21. Humphrey DS, et al. (2009) Self-assembled metallic nanowires on a dielectric support: Pd on rutile TiO2 (110). Nano Lett 9(1):155-159.
22. Pang CL, Lindsay R, Thornton G (2013) Structure of clean and adsorbate-covered single-crystal rutile TiO2 surfaces. Chem Rev 113(6):3887-3948.
23. Sutter PW, Flege JI, Sutter EA (2008) Epitaxial graphene on ruthenium. Nat Mater 7(5):406-411.
24. Matthaei F, et al. (2012) Coulomb attraction during the carpet growth mode of NaCl. J Phys Condens Matter 24(35):354006.
25. Rose MK, et al. (2002) Ordered structures of CO on Pd (111) studied by STM. Surf Sci 512(1):48-60.
26. Yim CM, et al. (2013) CO and O overlayers on Pd nanocrystals supported on TiO2 (110). Faraday Discuss 162:191-200.
27. Yudanov IV, et al. (2003) CO adsorption on Pd nanoparticles: Density functional and vibrational spectroscopy studies. J Phys Chem B 107(1):255-264.
28. Højrup-Hansen K, et al. (1999) Palladium nanocrystals on Al2O3: Structure and adhesion energy. Phys Rev Lett 83(20):4120-4123.
29. Knight MJ, et al. (2008) A structural study of a C3H3 species coadsorbed with CO on Pd (111). Surf Sci 602(16):2743-2751.
30. Dhesi SS, et al. (2010) The Nanoscience Beamline (I06) at Diamond Light Source. AIP Conf Proc 1234:311-314.
31. Stöhr J, Outka DA (1987) Determination of molecular orientations on surfaces from the angular dependence of near-edge x-ray-absorption fine-structure spectra. Phys Rev B Condens Matter 36(15):7891-7905.
32. Sánchez-Sánchez C, et al. (2010) Understanding atomic-resolved STM images on TiO2(110)-(1 x 1) surface by DFT calculations. Nanotechnology 21(40):405702.
33. Rupprechter G (2007) Sum frequency generation and polarization-modulation infrared reflection absorption spectroscopy of functioning model catalysts from ultra-high vacuum to ambient pressure. Adv Catal 51:133-263.
34. Mitsui T, Rose MK, Fomin E, Ogletree DF, Salmeron M (2002) Coadsorption and interactions of O and H on Pd (111). Surf Sci 511(1):259-266.
35. Morkel M, Rupprechter G, Freund H-J (2003) Ultrahigh vacuum and high-pressure coadsorption of CO and H2 on Pd (111): A combined SFG, TDS, and LEED study. J Chem Phys 119(20):10853-10866.
36. Grinberg I, Yourdshahyan Y, Rappe AM (2002) CO on Pt(111) puzzle: A possible solution. J Chem Phys 117(5):2264-2270.
37. Köhler L, Kresse G (2004) Density functional study of CO on Rh(111). Phys Rev B 70(16):165405.
38. Lazić P, et al. (2010) Density functional theory with nonlocal correlation: A key to the solution of the CO adsorption puzzle. Phys Rev B 81(4):045401.
39. Schimka L, et al. (2010) Accurate surface and adsorption energies from many-body perturbation theory. Nat Mater 9(9):741-744.
40. Mavrikakis M, Hammer B, Nørskov JK (1998) Effect of strain on the reactivity of metal surfaces. Phys Rev Lett 81(13):2819-2822.
41. Endo O, et al. (2011) Orientation of n-alkane in thin films on graphite (0001) studied using C K-NEXAFS. J Electron Spectrosc Relat Phenom 184(3):257-260.
42. Kresse G, Furthmüller J (1996) Efficiency of ab-initio total energy calculations for metals and semiconductors using a plane-wave basis set. Comput Mater Sci 6(1):15-50.
43. Kresse G, Furthmüller J (1996) Efficient iterative schemes for ab initio total-energy calculations using a plane-wave basis set. Phys Rev B Condens Matter 54(16):11169-11186.
44. Klimeš J, Bowler DR, Michaelides A (2011) van der Waals density functionals applied to solids. Phys Rev B 83(19):195131.
45. Román-Pérez G, Soler JM (2009) Efficient implementation of a van der Waals density functional: Application to double-wall carbon nanotubes. Phys Rev Lett 103(9):096102.