Role of low-coordinated surface sites in olefin hydrogenation: A molecular beam study on Pd nanoparticles and Pd(111)

ChemPhysChem

Volumn 11, Issue 11, 2010, Pages 2319-2322

  Ludwig, Wiebke ^a   Savara, Aditya ^a   Schauermann, Swetlana ^a   Freund, Hans Joachim ^a  

^a FRITZ HABER INSTITUT DER MAX PLANCK GESELLSCHAFT   (Germany)

Author keywords

Hydrogenation; Nanoparticles; Palladium; Subsurface hydrogen; Surface chemistry

Indexed keywords

HYDROGENATION; NANOPARTICLES; PALLADIUM; SURFACE CHEMISTRY;

OLEFIN HYDROGENATION; PD NANO PARTICLE; PD(111); SUBSURFACE HYDROGENS; SURFACE SITES;

MOLECULAR BEAMS;

EID: 77954982636     PISSN: 14394235     EISSN: 14397641     Source Type: Journal    
DOI: 10.1002/cphc.201000355     Document Type: Article

References (15)

1. G. C. Bond, Metal-Catalysed Reactions of Hydrocarbons, Springer, New York, 2005.
2. M. Wilde, K. Fukutani, W. Ludwig, B. Brandt, J.-H. Fischer, S. Schauermann, H.-J. Freund, Angew. Chem. 2008, 120, 9430.
3. Angew. Chem. Int. Ed. 2008, 47, 9289.
4. A. M. Doyle, Sh. K. Shaikhutdinov, S. D. Jackson, H.-J. Freund, Angew. Chem. 2003, 115, 5398.
5. Angew. Chem. Int. Ed. 2003, 42, 5240.
6. D. Teschner, J. Borsodi, A. Wootsch, Z. Révay, M. Hävecker, A. Knop-Gericke, S. D. Jackson, R. Schlögl, Science 2008, 320, 86.
7. B. Brandt, J.-H. Fischer, W. Ludwig, J. Libuda, F. Zaera, S. Schauermann, H.-J. Freund, J. Phys. Chem. C 2008, 112, 11408.
8. W. Ludwig, B. Brandt, A. Savara, R. J. Madix, S. Schauermann, H.-J. Freund, to be published.
9. K. Christmann, Surf. Sci. Rep. 1988, 9, 1.
10. K. M. Neyman, S. Schauermann, Angew. Chem. 2010, DOI: 10.1002/ange.200904688.
11. Angew. Chem. Int. Ed. 2010, DOI: 10.1002/anie.200904688.
12. J. Horiuti, M. Polanyi, Trans. Faraday. Soc. 1934, 30, 1164.
13. F. Zaera, Chem. Rev. 1995, 95, 2651.
14. T. Schalow, B. Brandt, D. E. Starr, M. Laurin, S. Schauermann, S. K. Shaikhutdinov, J. Libuda, H.-J. Freund, Catal. Lett. 2006, 107, 189.
15. 1 intermediate.