Nitrogen Stereodynamics and Complexation Phenomena as Key Factors in the Deprotonative Dynamic Resolution of Alkylideneaziridines: A Spectroscopic and Computational Study

Journal of Organic Chemistry

Volumn 80, Issue 12, 2015, Pages 6411-6418

  Degennaro, Leonardo ^a   Pisano, Luisa ^b   Parisi, Giovanna ^a   Mansueto, Rosmara ^a,c   Clarkson, Guy J ^c   Shipman, Michael ^c   Luisi, Renzo ^a  

^a UNIVERSITY OF BARI   (Italy)

^b UNIVERSITY OF SASSARI   (Italy)

^c UNIVERSITY OF WARWICK   (United Kingdom)

Author keywords

[No Author keywords available]

Indexed keywords

NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; ORGANIC COMPOUNDS; STEREOCHEMISTRY; STEREOSELECTIVITY;

COMPLEXATION PHENOMENA; COMPUTATIONAL DATA; COMPUTATIONAL STUDIES; DEPROTONATION REACTION; DYNAMIC RESOLUTION; NITROGEN INVERSION; REACTION CONDITIONS; SUBSTITUTION PATTERNS;

NITROGEN;

ALKYL GROUP; AZIRIDINE DERIVATIVE; ELECTROPHILE; NITROGEN; TOLUENE; ALKENE;

ARTICLE; CARBON NUCLEAR MAGNETIC RESONANCE; CHIRALITY; COMPLEX FORMATION; CRYSTAL STRUCTURE; DENSITY FUNCTIONAL THEORY; ELECTROPHILICITY; LITHIATION; NUCLEAR OVERHAUSER EFFECT; PROTON NUCLEAR MAGNETIC RESONANCE; PROTON TRANSPORT; REACTION ANALYSIS; STEREOCHEMISTRY; SUBSTITUTION REACTION; CHEMICAL STRUCTURE; CHEMISTRY; COMPUTER SIMULATION; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; QUANTUM THEORY; STEREOISOMERISM;

ALKENES; AZIRIDINES; COMPUTER SIMULATION; MAGNETIC RESONANCE SPECTROSCOPY; MOLECULAR STRUCTURE; NITROGEN; QUANTUM THEORY; STEREOISOMERISM;

EID: 84934889210     PISSN: 00223263     EISSN: 15206904     Source Type: Journal    
DOI: 10.1021/acs.joc.5b00848     Document Type: Article

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