Tertiary thiols from allylic thiocarbamates by tandem enantioselective [3,3]-sigmatropic rearrangement and stereospecific arylation

Organic Letters

Volumn 16, Issue 4, 2014, Pages 1252-1255

  Mingat, Gaëlle ^a   Maclellan, Paul ^a   Laars, Marju ^a   Clayden, Jonathan ^a  

^a UNIVERSITY OF MANCHESTER   (United Kingdom)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 84894577324     PISSN: 15237060     EISSN: 15237052     Source Type: Journal    
DOI: 10.1021/ol5002522     Document Type: Article

References (31)

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31. p)-COP-Cl, and the R configuration of compounds 7 on the basis that intramolecular arylation of related benzylic thiocarbamates proceeds with retention of configuration (ref 8). Circular dichroism studies of the products arising from further transformations of the products 7 and their analogues (Mingat, G.; McDouall, J. J. W.; Clayden, J. Manuscript in preparation) have since confirmed the assignment of (R)-configuration to 7.