Incorporation of Pendant Bases into Rh(diphosphine)2 Complexes: Synthesis, Thermodynamic Studies, and Catalytic CO2 Hydrogenation Activity of [Rh(P2N2)2]+ Complexes

Journal of the American Chemical Society

Volumn 137, Issue 25, 2015, Pages 8251-8260

  Lilio, Alyssia M ^a   Reineke, Mark H ^a   Moore, Curtis E ^a   Rheingold, Arnold L ^a   Takase, Michael K ^b   Kubiak, Clifford P ^a  

^a UNIVERSITY OF CALIFORNIA   (United States)

^b CALIFORNIA INSTITUTE OF TECHNOLOGY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

CARBON DIOXIDE; CATALYST ACTIVITY; HYDRIDES; HYDROGENATION; SYNTHESIS (CHEMICAL); THERMODYNAMIC PROPERTIES;

CHEMICAL EQUATIONS; CO2 HYDROGENATION; DISTORTED TRIGONAL BIPYRAMIDAL GEOMETRIES; HYDRIDE COMPLEXES; TETRAHEDRAL DISTORTIONS; THERMODYNAMIC CYCLE; THERMODYNAMIC STUDIES; X-RAY DIFFRACTION STUDIES;

RHODIUM COMPOUNDS;

BASE; CARBON DIOXIDE; RHODIUM COMPLEX; RHODIUM(DIPHOSPHINE)2 COMPLEX; UNCLASSIFIED DRUG;

ACIDITY; ARTICLE; CATALYSIS; CATALYST; CHEMICAL STRUCTURE; CONFORMATION; CRYSTAL STRUCTURE; ELECTROCHEMICAL ANALYSIS; ELECTROCHEMISTRY; EQUILIBRIUM CONSTANT; GEOMETRY; HYDROGEN BOND; HYDROGENATION; MASS SPECTROMETRY; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; NUCLEOPHILICITY; OXIDATION; PRECIPITATION; REDUCTION; SOLID STATE; SOLUBILITY; SYNTHESIS; THERMODYNAMICS; TURNOVER NUMBER; X RAY DIFFRACTION;

EID: 84934782858     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/jacs.5b04291     Document Type: Article

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