Synthesis, characterization, and reactivity of cationic hydride [HPd(diphosphine)2]+CF3 SO3-, the missing member of the family [HM(dppe)2]+X- (M = Ni, Pd, Pt). DFT QM/MM structural predictions for the [HPd(dppe)2]+ moiety

Inorganic Chemistry

Volumn 41, Issue 25, 2002, Pages 6550-6552

  Aresta, Michele ^a   Dibenedetto, Angela ^a   Amodio, Eliana ^a   Pápai, Imre ^b   Schubert, Gábor ^b  

^a UNIVERSITY OF BARI   (Italy)

^b CHEMICAL RESEARCH CENTER   (Hungary)

Author keywords

[No Author keywords available]

Indexed keywords

NICKEL; PALLADIUM; PHOSPHINE DERIVATIVE; PLATINUM;

ARTICLE; HYDROGEN BOND; INFRARED SPECTROSCOPY; REACTION ANALYSIS; SYNTHESIS;

EID: 0037121907     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic020631p     Document Type: Article

References (19)

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7. 4SPd•1/8THF, 1: C, 60.49; H, 4.74; P, 11.66; Pd, 10.02; S, 3.02%. Found: C, 60.87; H, 5.07; P, 11.49; Pd, 10.07; S, 2.84%.
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10. See Supporting Information.
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13. 2), 7.24 (m, 32 H, o- and m-dppe), 7.40 (t, 8 H, p-dppe).
14. 2 at 202.48 MHz and 293 K.
15. 2O/EtOH 10%).
16. -) that can be isolated from the reaction mixture.
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