Formation and characterisation of the silver hydride nanocluster cation [Ag3H2((Ph2P)2CH2)]+ and its release of hydrogen

Chemistry - A European Journal

Volumn 20, Issue 50, 2014, Pages 16626-16633

  Girod, Marion ^a,b   Krstić, Marjan ^c   Antoine, Rodolphe ^a,b   MacAleese, Luke ^a,b   Lemoine, JéRome ^a,b   Zavras, Athanasios ^d   Khairallah, George N ^d   Bonacic Koutecky, Vlasta ^c,e   Dugourd, Philippe ^a,b   O'Hair, Richard A J ^d  

^a UNIVERSITÉ DE LYON   (France)

^b UNIVERSITÉ LYON 1   (France)

^c UNIVERSITY OF SPLIT   (Croatia)

^d UNIVERSITY OF MELBOURNE   (Australia)

^e HUMBOLDT UNIVERSITY   (Germany)

Author keywords

fragmentation channels; hydrogen formation; molecular dynamics; multistage mass spectrometry; photochemistry

Indexed keywords

DENSITY FUNCTIONAL THEORY; DISSOCIATION; EXCITED STATES; GASES; GROUND STATE; HYDRIDES; HYDROGEN STORAGE; MASS SPECTROMETRY; MOLECULAR DYNAMICS; NANOCLUSTERS; PHOTOCHEMICAL REACTIONS;

ACTION SPECTROSCOPY; COLLISION INDUCED DISSOCIATION; DEUTERIUM LABELLING; FIRST EXCITED STATE; FRAGMENTATION CHANNELS; HYDROGEN STORAGE MEDIUM; LASER-INDUCED DISSOCIATION; MULTI-STAGE MASS SPECTROMETRY;

SILVER COMPOUNDS;

EID: 84933551959     PISSN: 09476539     EISSN: 15213765     Source Type: Journal    
DOI: 10.1002/chem.201404110     Document Type: Article

References (54)

1. The Hydrogen Economy: Opportunities, Costs, Barriers, and R&D Needs, National Academy, 2004;
2. G. W. Crabtree, M. S. Dresselhaus, M. V. Buchanan, Physics Today 2004, 57, 39-44;
3. P. Jena, J. Phys. Chem. Lett. 2011, 2, 206-211.
4. L. Schlapbach, A. Züttel, Nature 2001, 414, 353-358;
5. F. Schüth, Eur. Phys. J. Special Topics 2009, 176, 155-166;
6. M. T. Kelly, Struct. Bonding (Berlin) 2011, 141, 169-201.
7. For an excellent review on hydrogen storage materials, including a discussion on the "5 commandments" for the ideal hydrogen storage material, see:, W. Grochala, P. P. Edwards, Chem. Rev. 2004, 104, 1283-1315.
8. A. S. Weller, J. S. McIndoe, Eur. J. Inorg. Chem. 2007, 4411-4423.
9. K. Shimizu, R. Sato, A. Satsuma, Angew. Chem. Int. Ed. 2009, 48, 3982-3986;
10. Angew. Chem. 2009, 121, 4042-4046;
11. K. Shimizu, K. Sugino, K. Sawabe, A. Satsuma, Chem. Eur. J. 2009, 15, 2341-2351;
12. K. Shimizu, A. Satsuma, J. Jpn. Pet. Inst. 2011, 54, 347-360.
13. C. W. Liu, H.-W. Chang, C.-S. Fang, B. Sarkar, J.-C. Wang, Chem. Commun. 2010, 46, 4571-4573;
14. C. W. Liu, H.-W. Chang, B. Sarkar, J.-Y. Saillard, S. Kahal, Y.-Y. Wu, Inorg. Chem. 2010, 49, 468-475;
15. C. W. Liu, P.-K. Liao, C.-S. Fang, J.-Y. Saillard, S. Kahal, J.-C. Wang, Chem. Commun. 2011, 47, 5831-5833;
16. A. Zavras, G. N. Khairallah, T. U. Connell, J. M. White, A. J. Edwards, P. S. Donnelly, R. A. J. O'Hair, Angew. Chem. Int. Ed. 2013, 52, 8474-8474;
17. Angew. Chem. 2013, 125, 8632-8632;
18. B. K. Tate, C. M. Wyss, J. Bacsa, K. Kluge, L. Gelbauma, J. P. Sadighi, Chem. Sci. 2013, 4, 3068-3074;
19. A. Zavras, G. N. Khairallah, T. U. Connell, J. M. White, A. J. Edwards, R. J. Mulder, P. S. Donnelly, R. A. J. O'Hair, Inorg. Chem. 2014, 53, 7429-7437.
20. R. Mitrić, J. Petersen, A. Kulesza, M. Röhr, V. Bonačić-Koutecký, C. Brunet, R. Antoine, P. Dugourd, M. Broyer, R. A. J. O'Hair, J. Phys. Chem. Lett. 2011, 2, 548-552.
21. G. N. Khairallah, R. A. J. O'Hair, Angew. Chem. Int. Ed. 2005, 44, 728-731;
22. Angew. Chem. 2005, 117, 738-741;
23. G. N. Khairallah, R. A. J. O'Hair, Dalton Trans. 2005, 2702-2712;
24. G. N. Khairallah, R. A. J. O'Hair, Dalton Trans. 2007, 3149-3157;
25. G. N. Khairallah, R. A. J. O'Hair, Dalton Trans. 2008, 2956-2965;
26. F. Q. Wang, G. N. Khairallah, R. A. J. O'Hair, Int. J. Mass Spectrom. 2009, 283, 17-25;
27. A. J. Clark, A. Zavras, G. N. Khairallah, R. A. J. O'Hair, Int. J. Mass Spectrom. 2014; DOI:.
28. + see:, A. B. Vakhtin, E. M. Markin, K.-I. Sugawara, Chem. Phys. 2000, 262, 93-104.
29. 2 see:
30. A. B. Vakhtin, K.-I. Sugawara, J. Chem. Phys. 2001, 115, 3629-3639;
31. F. Liu, P. B. Armentrout, J. Chem. Phys. 2005, 122, 194320 /- 194320 / 12.
32. + complex has been recently reported:, V. Dryza, E. J. Bieske, J. Phys. Chem. Lett. 2011, 2, 719-724.
33. W. A. Donald, G. N. Khairallah, R. A. J. O'Hair, J. Am. Soc. Mass Spectrom. 2013, 24, 811-815.
34. +:, Y.-M. Chen, J. L. Elkind, P. B. Armentrout, J. Phys. Chem. 1995, 99, 10438-10445.
35. T. Tabarin, A. Kulesza, R. Antoine, R. Mitrić, M. Broyer, P. Dugourd, V. Bonačić-Koutecký, Phys. Rev. Lett. 2008, 101, 213001.
36. R. A. Burrow, F. C. Wouters, L. Borgen de Castro, C. Peppe, Acta Crystallogr. E 2007, 63, o 2559.
37. S. Enthaler, J. Langermann, T. Schmidt, Energy Environ. Sci. 2010, 3, 1207-1217;
38. M. Grasemann, G. Laurenczy, Energy Environ. Sci. 2012, 5, 8171-8181.
39. R. Antoine, P. Dugourd, D. Rayane, E. Benichou, M. Broyer, J. Chem. Phys. 1997, 107, 2664-2672.
40. For a report on the gas-phase decomposition of formic acid catalyzed by magnesium hydrides see:, G. N. Khairallah, R. A. J. O'Hair, Int. J. Mass Spectrom. 2006, 254, 145-151.
41. R. J. Wang, T. Fujimoto, T. Shido, M. Ichikawa, J. Chem. Soc. Chem. Commun. 1992, 962-963;
42. Y. Negishi, Bull. Chem. Soc. Jpn. 2014, 87, 375-389.
43. M. Wuithschick, B. Paul, R. Bienert, A. Sarfraz, U. Vainio, M. Sztucki, R. Kraehnert, P. Strasser, K. Rademann, F. Emmerling, J. Polte Chem. Mater. 2013, 25, 4679-4689, and references cited therein.
44. S. D. Solomon, M. Bahadory, A. V. Jeyarajasingam, S. A. Rutkowsky, C. Boritz, L. Mulfinger, J. Chem. Educ. 2007, 84, 322-325.
45. V. Larraillet, R. Antoine, P. Dugourd, J. Lemoine, Anal. Chem. 2009, 81, 8410-8416;
46. R. Antoine, P. Dugourd, Phys. Chem. Chem. Phys. 2011, 13, 16494-16509.
47. L. Joly, R. Antoine, A. R. Allouche, P. Dugourd, J. Am. Chem. Soc. 2008, 130, 13832-13833.
48. A. D. Becke, J. Chem. Phys. 1988, 38, 3098;
49. A. D. Becke, J. Chem. Phys. 1993, 98, 5648;
50. C. Lee, W. Yang, R. G. Parr, Phys. Rev. B 1988, 37, 785.
51. A. Schäfer, H. Huber, R. Ahlrichs, J. Chem. Phys. 1994, 100, 5829-5835.
52. D. Andrae, U. Haeussermann, M. Dolg, H. Stoll, H. Preuss, Theor. Chim. Acta 1990, 77, 123.
53. J. P. Perdew, K. Burke, M. Ernzerhof, Phys. Rev. Lett. 1996, 77, 3865-3868.
54. K. Eichkorn, O. Treutler, H. Öhm, M. Häser, R. Ahlrichs, Chem. Phys. Lett. 1995, 242, 652-660.