Cobalt-Catalyzed [2π + 2π] Cycloadditions of Alkenes: Scope, Mechanism, and Elucidation of Electronic Structure of Catalytic Intermediates

Journal of the American Chemical Society

Volumn 137, Issue 24, 2015, Pages 7903-7914

  Schmidt, Valerie A ^a   Hoyt, Jordan M ^a   Margulieux, Grant W ^a   Chirik, Paul J ^a  

^a PRINCETON UNIVERSITY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

COBALT; CYCLOADDITION; ELECTRON SPIN RESONANCE SPECTROSCOPY; ELECTRONIC STRUCTURE; FUNCTIONAL GROUPS; HYDROCARBONS; MAGNETIC RESONANCE; MOLECULAR ORBITALS; OLEFINS; PARAMAGNETIC RESONANCE; PYRIDINE; SPECTROSCOPIC ANALYSIS;

CATALYST RESTING STATE; CATALYTIC INTERMEDIATES; ELECTRON PARAMAGNETIC RESONANCES (EPR); METAL COORDINATION SPHERES; PYRIDINE SUBSTITUTIONS; SINGLY OCCUPIED MOLECULAR ORBITALS; SPECTROSCOPIC STUDIES; STRUCTURE ACTIVITY RELATIONSHIPS;

COBALT COMPOUNDS;

ALKADIENE; ALKENE; BICYCLO[3.2.0]HEPTANE DERIVATIVE; CHELATE; COBALT; DEUTERIUM; FUNCTIONAL GROUP; PYRIDINE DERIVATIVE; IMINE; NITROGEN; PYRIDINE;

ARTICLE; CATALYSIS; CATALYST; CHEMICAL STRUCTURE; COVALENT BOND; CYCLIZATION; CYCLOADDITION; DECOMPOSITION; ELECTRON SPIN RESONANCE; ELECTRON TRANSPORT; CHEMISTRY; ELECTRON; QUANTUM THEORY;

ALKENES; CATALYSIS; COBALT; CYCLOADDITION REACTION; ELECTRON SPIN RESONANCE SPECTROSCOPY; ELECTRONS; IMINES; MODELS, MOLECULAR; NITROGEN; PYRIDINES; QUANTUM THEORY;

EID: 84933073703     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/jacs.5b04034     Document Type: Article

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80. Representative procedures are reported here; complete details, including general considerations, are reported in the Supporting Information.