Anion radical [2 + 2] cycloaddition as a mechanistic probe: Stoichiometry- and concentration-dependent partitioning of electron-transfer and alkylation pathways in the reaction of the Gilman reagent Me2CuLi·LiI with bis(enones)

Journal of Organic Chemistry

Volumn 69, Issue 23, 2004, Pages 7979-7984

  Yang, Jingkui ^a   Cauble, David F ^a   Berro, Adam J ^a   Bauld, Nathan L ^a   Krische, Michael J ^a  

^a UNIVERSITY OF TEXAS AT AUSTIN   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

CONCENTRATION (PROCESS); DATA REDUCTION; ELECTROCHEMISTRY; KINETIC THEORY; SOLVENTS;

ANION RADICAL; CYCLOADDITION;

ALKYLATION;

ANION; BIS(ENONE); LITHIUM DERIVATIVE; LITHIUM DIALKYLCUPRATE; POLYCYCLIC AROMATIC HYDROCARBON; RADICAL; REAGENT; SOLVENT; TETRAHYDROFURAN; UNCLASSIFIED DRUG;

ALKYLATION; ARTICLE; CATALYSIS; CONCENTRATION RESPONSE; CONJUGATE; CYCLIZATION; CYCLOADDITION; ELECTROCHEMICAL ANALYSIS; ELECTRON TRANSPORT; KINETICS; MICHAEL ADDITION; STOICHIOMETRY;

ALKYLATION; ANIONS; CATALYSIS; COPPER; CYCLIZATION; CYCLOBUTANES; ELECTROCHEMISTRY; INDICATORS AND REAGENTS; KETONES; KINETICS; LITHIUM; ORGANOMETALLIC COMPOUNDS; OXIDATION-REDUCTION;

EID: 8644235789     PISSN: 00223263     EISSN: None     Source Type: Journal    
DOI: 10.1021/jo048499t     Document Type: Article

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