Stereoselective gold(I) domino catalysis of allylic isomerization and olefin cyclopropanation: Mechanistic studies

Journal of Organic Chemistry

Volumn 80, Issue 11, 2015, Pages 5719-5729

  Klimczyk, Sebastian ^a   Huang, Xueliang ^b   Kählig, Hanspeter ^a   Veiros, Luís F ^c   Maulide, Nuno ^a  

^a UNIVERSITY OF VIENNA   (Austria)

^b FUJIAN INSTITUTE OF RESEARCH ON THE STRUCTURE OF MATTER   (China)

^c INSTITUTO SUPERIOR TÉCNICO   (Portugal)

Author keywords

[No Author keywords available]

Indexed keywords

ACTIVATION ANALYSIS; CATALYSIS; CHEMICAL ACTIVATION; GOLD; ISOMERIZATION; MECHANICS; OLEFINS; STEREOSELECTIVITY;

CATALYTIC TRANSFORMATION; COMPUTATIONAL STUDIES; CYCLOPROPANATION; ISOMERIZATION PATHWAYS; MECHANISTIC STUDIES; OLEFIN CYCLOPROPANATION; OLEFIN ISOMERIZATION; STEREO-SELECTIVE;

ISOMERS;

ALKENE; GOLD; SULFONIUM DERIVATIVE;

ALLYLIC REARRANGEMENT; ARTICLE; CATALYSIS; CONFORMATIONAL TRANSITION; CYCLOPROPANATION; DENSITY FUNCTIONAL THEORY; DIASTEREOISOMER; ELECTRON TRANSPORT; ENANTIOMER; ISOMERIZATION; ISOTOPE LABELING; NUCLEOPHILICITY; PHOSPHORUS NUCLEAR MAGNETIC RESONANCE; PREDICTION; PROTON NUCLEAR MAGNETIC RESONANCE; REACTION ANALYSIS; REACTION TIME; STEREOCHEMISTRY; STEREOISOMERISM;

EID: 84930966104     PISSN: 00223263     EISSN: 15206904     Source Type: Journal    
DOI: 10.1021/acs.joc.5b00666     Document Type: Article

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