Determination of the dominant catalyst derived from the classic [RhCp∗Cl2]2 precatalyst system: Is it single-metal Rh1Cp∗-based, subnanometer Rh4 cluster-based, or Rh(0) n nanoparticle-based cyclohexene hydrogenation catalysis at room temperature and mild pressures?

ACS Catalysis

Volumn 5, Issue 6, 2015, Pages 3876-3886

  Bayram, Ercan ^a   Linehan, John C ^b   Fulton, John L ^b   Szymczak, Nathaniel K ^c   Finke, Richard G ^a  

^a Veterinary Dentistry and Oral Surgery   (United States)

^b PACIFIC NORTHWEST NATIONAL LABORATORY   (United States)

^c UNIVERSITY OF MICHIGAN   (United States)

Author keywords

catalysis; catalyst poisoning studies; determination of the dominant catalyst; in operando spectroscopic studies; nanoparticle catalysis; organometallic complex catalysis; rhodium; subnanometer cluster catalysis; XAFS

Indexed keywords

CATALYSIS; HYDROGENATION; MASS SPECTROMETRY; METAL NANOPARTICLES; OLEFINS; ORGANOMETALLICS; RHODIUM; SPECTROSCOPIC ANALYSIS; X RAY ABSORPTION;

NANOPARTICLE CATALYSIS; OPERANDO; ORGANO-METALLIC COMPLEXES; SUB NANOMETERS; XAFS;

CATALYST POISONING;

EID: 84930654248     PISSN: None     EISSN: 21555435     Source Type: Journal    
DOI: 10.1021/acscatal.5b00315     Document Type: Article

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