Water oxidation catalysis beginning with Co4(H 2O)2(PW9O34)2 10- when driven by the chemical oxidant ruthenium(III)tris(2, 2′-bipyridine): Stoichiometry, kinetic, and mechanistic studies en route to identifying the true catalyst

ACS Catalysis

Volumn 4, Issue 1, 2014, Pages 79-89

  Stracke, Jordan J ^a   Finke, Richard G ^a  

^a Department of Environmental and Radiological Health Sciences   (United States)

Author keywords

homogeneous versus heterogeneous; kinetics and mechanism; ligand oxidation; polyoxometalate catalyst; water oxidation

Indexed keywords

HOMOGENEOUS VERSUS HETEROGENEOUS; KINETICS AND MECHANISM; MECHANISTIC STUDIES; POLYOXOMETALATES; REACTION CONDITIONS; SODIUM PHOSPHATE BUFFER; STANDARD CONDITIONS; WATER OXIDATION;

CATALYSTS; CATALYTIC OXIDATION; COBALT COMPOUNDS; KINETICS; LIGANDS; OXIDANTS; OXIDATION; OXIDES; RATE CONSTANTS; REACTION KINETICS; RUTHENIUM ALLOYS; SODIUM COMPOUNDS; STOICHIOMETRY;

RUTHENIUM;

EID: 84891763447     PISSN: 21555435     EISSN: None     Source Type: Journal    
DOI: 10.1021/cs4006925     Document Type: Article

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