Selective C-C and C-H Bond Activation/Cleavage of Pinene Derivatives: Synthesis of Enantiopure Cyclohexenone Scaffolds and Mechanistic Insights

Journal of the American Chemical Society

Volumn 137, Issue 19, 2015, Pages 6327-6334

  Masarwa, Ahmad ^a   Weber, Manuel ^a   Sarpong, Richmond ^a  

^a UNIVERSITY OF CALIFORNIA   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

CATALYSIS; COVALENT BONDS; KETONES; MONOTERPENES; RHODIUM; SCAFFOLDS; TRANSITION METALS;

C-C BOND ACTIVATION; C-C BOND CLEAVAGES; CH-BOND ACTIVATION; COMPUTATIONAL STUDIES; ELECTROPHILIC REAGENTS; NATURAL PRODUCTS; SYNTHETIC STRATEGIES; TRANSITION-METAL-MEDIATED;

CHEMICAL ACTIVATION;

2 CYCLOHEXENONE; BUTANOL; CARBON; CYCLOBUTANOL DERIVATIVE; HYDROGEN; NATURAL PRODUCT; PHOMACTIN A; PINENE; SPIROINDICUMIDE DERIVATIVE; TRANSITION ELEMENT; UNCLASSIFIED DRUG; CYCLOBUTANE DERIVATIVE; CYCLOBUTANOL; CYCLOHEXANONE DERIVATIVE; FUSED HETEROCYCLIC RINGS; LACTONE; POLYKETIDE; RHODIUM; SPIRO COMPOUND; SPIROINDICUMIDE A; SPIROINDICUMIDE B;

ARTICLE; CATALYSIS; CHEMICAL BOND; ELECTROPHILICITY; HYDROXYLATION; STEREOCHEMISTRY; SYNTHESIS; CHEMICAL STRUCTURE; CHEMISTRY; STEREOISOMERISM;

CATALYSIS; CYCLOBUTANES; CYCLOHEXANONES; HETEROCYCLIC COMPOUNDS WITH 4 OR MORE RINGS; LACTONES; MODELS, MOLECULAR; POLYKETIDES; RHODIUM; SPIRO COMPOUNDS; STEREOISOMERISM;

EID: 84930225615     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/jacs.5b02254     Document Type: Article

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