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Volumn 18, Issue 10-11, 2014, Pages 937-943

Aerobic oxidative N-dealkylation of secondary amines in aqueous solution catalyzed by rhodium porphyrins

Author keywords

iminium ion; oxidative N dealkylation; rhodium porphyrin; secondary amines; water

Indexed keywords


EID: 84929298305     PISSN: 10884246     EISSN: 10991409     Source Type: Journal    
DOI: 10.1142/S108842461450076X     Document Type: Article
Times cited : (11)

References (56)
  • 5
    • 0025307009 scopus 로고
    • For reviews on the mechanistic study of N-dealkylation by P450
    • For reviews on the mechanistic study of N-dealkylation by P450: (a) Guengerich FP and Macdonald TL. FASEB J. 1990; 4: 2453-2459.
    • (1990) FASEB J. , vol.4 , pp. 2453-2459
    • Guengerich, F.P.1    Macdonald, T.L.2
  • 46
    • 85037081138 scopus 로고    scopus 로고
    • Although the TON of diisopropylamine is larger than that of N-tert-butylisopropylamine, we should note that there are two (CH3)2HC-N bonds in the former substrate while there is only one such bond in the latter one. 14 Considering the low TON of some substrates, the reaction time was prolonged from 6 h to 10 h for more accurate results
    • Although the TON of diisopropylamine is larger than that of N-tert-butylisopropylamine, we should note that there are two (CH3)2HC-N bonds in the former substrate while there is only one such bond in the latter one. 14 Considering the low TON of some substrates, the reaction time was prolonged from 6 h to 10 h for more accurate results.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.