The Cobalt Hydride that Never Was: Revisiting Schrauzer's "Hydridocobaloxime"

Journal of the American Chemical Society

Volumn 137, Issue 14, 2015, Pages 4860-4864

  Lacy, David C ^a   Roberts, Gerri M ^a   Peters, Jonas C ^a  

^a California Institute of Technology   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

COBALT; ELECTROCATALYSTS; HYDRIDES; NUCLEAR MAGNETIC RESONANCE; PHOSPHORUS COMPOUNDS; SYNTHESIS (CHEMICAL);

CHEMICAL EQUATIONS; COBALOXIMES; COBALT HYDRIDE; DIMETHYLGLYOXIME; EXPOSED TO; HYDRIDE LIGANDS; HYDROGEN EVOLUTION REACTIONS; MECHANISTIC MODELING;

COBALT COMPOUNDS;

COBALT COMPLEX; DIMER; HYDRIDOCOBALOXIME; LIGAND; MONOMER; OXYGEN; UNCLASSIFIED DRUG;

ARTICLE; CATALYSIS; CHEMICAL BOND; CHEMICAL STRUCTURE; DIMERIZATION; ELECTRON SPIN RESONANCE; FAST ATOM BOMBARDMENT MASS SPECTROMETRY; HYDROGEN EVOLUTION; ISOMERIZATION; MAGNETISM; PHOSPHORUS NUCLEAR MAGNETIC RESONANCE; PROTON NUCLEAR MAGNETIC RESONANCE; PROTON TRANSPORT; REACTION ANALYSIS; SOLID STATE; SYNTHESIS; TAUTOMERIZATION; THERMODYNAMICS;

EID: 84927945526     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/jacs.5b01838     Document Type: Article

References (60)

1. Hu, X.; Cossairt, B. M.; Brunschwig, B. S.; Lewis, N. S.; Peters, J. C. Chem. Commun. 2005, 4723
2. Razavet, M.; Artero, V.; Fontecave, M. Inorg. Chem. 2005, 44, 4786
3. Hu, X.; Brunschwig, B. S.; Peters, J. C. J. Am. Chem. Soc. 2007, 129, 8988
4. Carole, B.; Artero, V.; Fontecave, M. Inorg. Chem. 2007, 46, 1817
5. Du, P.; Schneider, J.; Luo, G.; Brennessel, W. W.; Eisenberg, R. Inorg. Chem. 2009, 48, 4952
6. Bigi, J. P.; Hanna, T. E.; Harman, W. H.; Chang, A.; Chang, C. J. Chem. Commun. 2010, 46, 958
7. Letko, C. S.; Panetier, J. A.; Head-Gordon, M.; Tilley, T. D. J. Am. Chem. Soc. 2014, 136, 9364
8. McNamara, W. R.; Han, Z.; Yin, C.-J.; Brennessel, W. W.; Holland, P. L.; Eisenberg, R. Proc. Natl. Acad. Sci. U. S. A. 2012, 109, 15594
9. McCrory, C. C. L.; Uyeda, C.; Peters, J. C. J. Am. Chem. Soc. 2012, 134, 3164
10. Leung, C.-F.; Chen, Y.-Z.; Yu, H.-Q.; Yiu, S.-M.; Ko, C.-C.; Lau, T.-C. Int. J. Hydrogen Energy 2011, 36, 11640
11. Szajna-Fuller, E.; Bakac, A. Eur. J. Inorg. Chem. 2010, 2488
12. Varma, S.; Castillo, C. E.; Stoll, T.; Fortage, J.; Blackman, A. G.; Molton, F.; Deronzier, A.; Collomb, M.-N. Phys. Chem. Chem. Phys. 2013, 15, 17544
13. Dempsey, J. L.; Brunschwig, B. S.; Winkler, J. R.; Gray, H. B. Acc. Chem. Res. 2009, 42, 1995
14. Thoi, V. S.; Sun, Y.; Long, J. R.; Chang, C. J. Chem. Soc. Rev. 2013, 42, 2388
15. Muckerman, J. T.; Fujita, E. Chem. Commun. 2011, 47, 12456
16. Solis, B. H.; Hammes-Schiffer, S. Inorg. Chem. 2011, 50, 11252
17. Chao, T. H.; Espenson, J. H. J. Am. Chem. Soc. 1978, 100, 129
18. Connolly, P.; Espenson, J. H. Inorg. Chem. 1986, 25, 2684
19. Marinescu, S. C.; Winkler, J. R.; Gray, H. B. Proc. Natl. Acad. Sci. U. S. A. 2012, 109, 15127
20. Wiedner, E. S.; Roberts, J. A. S.; Dougherty, W. G.; Kassel, W. S.; DuBois, D. L.; Bullock, R. M. Inorg. Chem. 2013, 52, 9975
21. Koelle, U.; Ohst, S. Inorg. Chem. 1986, 25, 2689
22. Houlding, V.; Geiger, T.; Kölle, U.; Grätzel, M. J. Chem. Soc., Chem. Commun. 1982, 681
23. Ciancanelli, R.; Noll, B. C.; DuBois, D. L.; Dubois, M. R. J. Am. Chem. Soc. 2002, 124, 2984
24. Rahman, A. F. M. M.; Jackson, W. G.; Willis, A. C.; Rae, A. D. Chem. Commun. 2003, 2748
25. Bhattacharjee, A.; Weiss, A. K. H; Artero, V.; Field, M. J.; Hofer, T. S. J. Phys. Chem. B 2014, 118, 5551
26. Schrauzer, G. N.; Holland, R. J. J. Am. Chem. Soc. 1971, 93, 1505
27. Mckone, J. R.; Marinescu, S. C.; Brunschwig, B. S.; Winkler, J. R.; Gray, H. B. Chem. Sci. 2014, 5, 865
28. Eckenhoff, W. T.; McNamara, W. R.; Du, P.; Eisenburg, R. Biochim. Biophys. Acta 2013, 1827, 958
29. Artero, V.; Chavarot-Kerlidou, M.; Fontecave, M. Angew. Chem., Int. Ed. 2011, 50, 7238
30. Crabtree, R. H. The Organometallic Chemistry of the Transition Metals, 5th ed.; John Wiley & Sons: Hoboken, NJ, 2009.
31. Hartwig, J. F. Organotransition Metal Chemistry, From Bonding to Catalysis; University Science Books: Herndon, VA, 2010.
32. Buckingham, A. D.; Stephens, P. J. J. Chem. Soc. 1964, 2747
33. Buckingham, A. D.; Stephens, P. F. J. Chem. Soc. 1964, 4583
34. Bhattacharjee, A.; Chavarot-Kerlidou, M.; Andreiadis, E. S.; Fontecave, M.; Field, M. J.; Artero, V. Inorg. Chem. 2012, 51, 7087
35. Dahl, L. F.; Rundle, R. E. Acta Crystallogr. 1963, 16, 419
36. Peng, S.-M.; Liaw, D.-S.; Wang, Y.; Simon, A. Angew. Chem., Int. Ed. 1985, 24, 210
37. Simon, G. L.; Adamson, A. W.; Dahl, L. F. J. Am. Chem. Soc. 1972, 94, 7654
38. Brown, L. D.; Raymond, K. N.; Goldberg, S. Z. J. Am. Chem. Soc. 1972, 94, 7664
39. Cotton, F. A.; Duune, T. G.; Wood, J. S. Inorg. Chem. 1964, 3, 1495
40. Handy, L. B.; Ruff, J. K.; Dahl, L. F. J. Am. Chem. Soc. 1970, 92, 7312
41. Caulton, K. G.; Cotton, F. A. J. Am. Chem. Soc. 1971, 93, 1914
42. Schaefer, W. P.; Marsh, R. E. Acta Crystallogr. 1969, B25, 1675
43. Murray, K. S.; Bergen, A. v. d.; Kennedy, B. J.; West, B. O. Aust. J. Chem. 1986, 39, 1479
44. Rosa, A.; Ricciardi, G.; Baerends, E. J.; Stufkens, D. J. Inorg. Chem. 1995, 34, 3425
45. Levenson, R. A.; Gray, H. B. J. Am. Chem. Soc. 1975, 97, 6042
46. Levenson, R. A.; Gray, H. B.; Ceasar, G. P. J. Am. Chem. Soc. 1970, 92, 3653
47. McLain, S. J. J. Am. Chem. Soc. 1988, 110, 643
48. Sun, Y. A. The Anions of C60 and Its Pyrrolidine Derivatives and B. The Search for Hydridocobaloximes. Ph.D. Thesis, University of Southern California, Los Angeles, CA, 1997.
49. Li, G.; Han, A.; Pulling, M. E.; Estes, D. P.; Norton, J. R. J. Am. Chem. Soc. 2012, 134, 14662
50. Halpern, J.; Phelan, P. F. J. Am. Chem. Soc. 1972, 94, 1881
51. The (n Bu)3P-BH3 impurity in [ P-Co II]2 from Schrauzer's prep that we reproducibly observe by IR spectroscopy may have also been present, but not assigned, in a spectrum reported by Artero and Fontecave (ref 8, Figure S4) with a broad feature that they attributed to CO2.
52. Halpern, J.; Pribanic, M. Inorg. Chem. 1970, 9, 2616
53. Wayland, B. B.; Ba, S.; Sherry, A. E. Inorg. Chem. 1992, 31, 148
54. Simándi, L. I.; Budó-Záhonyi, É.; Szeverényi, Z.; Németh, S. J. Chem. Soc., Dalton 1980, 276
55. Simándi, L. I.; Szeverényi, Z.; Budó-Záhonyi, E. Inorg. Nucl. Chem. Lett. 1975, 11, 773
56. Simándi, L. I.; Budó-Záhonyi, E.; Szeverényi, Z. Inorg. Nucl. Chem. Lett. 1976, 12, 237 (e)
57. Cullen, W. R.; Dolphin, D.; Einstein, F. W. B.; Mihichuk, L. M.; Willis, A. C. J. Am. Chem. Soc. 1979, 101, 6898
58. Jacobsen, F. E.; Breece, R. M.; Myers, W. K.; Tierney, D. L.; Cohen, S. M. Inorg. Chem. 2006, 45, 7306
59. Estes, D. P.; Grills, D. G.; Norton, J. R. J. Am. Chem. Soc. 2014, 136, 17362
60. Helm, M. L.; Stewart, M. P.; Bullock, R. M.; Rakowski DuBois, M.; DuBois, D. L. Science 2011, 333, 863