Formal Asymmetric Catalytic Thiolation with a Bifunctional Catalyst at a Water-Oil Interface: Synthesis of Benzyl Thiols

Angewandte Chemie - International Edition

Volumn 54, Issue 15, 2015, Pages 4522-4526

  Guo, Wengang ^a   Wu, Bo ^a   Zhou, Xin ^a   Chen, Ping ^a   Wang, Xu ^a   Zhou, Yong Gui ^a   Liu, Yan ^a   Li, Can ^a  

^a DALIAN INSTITUTE OF CHEMICAL PHYSICS   (China)

Author keywords

asymmetric catalysis; organocatalysis; ortho quinone methides; thiol addition

Indexed keywords

CATALYSIS; OIL SHALE; REACTION KINETICS; STEREOSELECTIVITY;

ASYMMETRIC CATALYSIS; BI-FUNCTIONAL CATALYSTS; CONTROL EXPERIMENTS; ENANTIOSELECTIVE; ORGANOCATALYSIS; QUINONE METHIDES; THIOL ADDITION; WATER OIL INTERFACE;

CATALYSTS;

AMINE; BENZENE DERIVATIVE; INDOLE DERIVATIVE; OIL; QUINONE METHIDE; THIOL DERIVATIVE; WATER;

CATALYSIS; CHEMISTRY; STEREOISOMERISM; SYNTHESIS;

AMINES; BENZENE DERIVATIVES; CATALYSIS; INDOLEQUINONES; OILS; STEREOISOMERISM; SULFHYDRYL COMPOUNDS; WATER;

EID: 84926322836     PISSN: 14337851     EISSN: 15213773     Source Type: Journal    
DOI: 10.1002/anie.201409894     Document Type: Article

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78. We carried out control experiments with different amounts of water to prove the critical role of the inorganic base in the regeneration of catalyst 1h. For details, see the Supporting Information, page S36.