Sources of atmospheric nitrous acid: State of the science, current research needs, and future prospects

Journal of the Air and Waste Management Association

Volumn 64, Issue 11, 2014, Pages 1232-1250

  Spataro, Francesca ^a   Ianniello, Antonietta ^a  

^a CNR Institute of Atmospheric Pollution Research   (Italy)

Author keywords

[No Author keywords available]

Indexed keywords

ATMOSPHERIC CHEMISTRY; BUDGET CONTROL; FREE RADICALS; PHASE INTERFACES; PHOTOLYSIS; PHOTOOXIDATION; POLLUTION CONTROL; SURFACE REACTIONS; TROPOSPHERE; UNCERTAINTY ANALYSIS;

ATMOSPHERIC POLLUTANTS; FIELD AND MODEL STUDIES; HETEROGENEOUS REACTIONS; MEASUREMENT TECHNIQUES; PEROXYACETYL NITRATES; SPECTROSCOPIC TECHNIQUE; TROPOSPHERIC CHEMISTRY; WET CHEMICAL TECHNIQUES;

INORGANIC ACIDS;

HYDROXYL RADICAL; NITROPHENOL; NITROUS ACID; PEROXYACETYLNITRATE; AIR POLLUTANT;

ABSORPTION SPECTROSCOPY; ATMOSPHERIC DEPOSITION; BIOLOGICAL PHENOMENA AND FUNCTIONS CONCERNING THE ENTIRE ORGANISM; BIOMASS; CATALYST; DRY DEPOSITION; EXHAUST GAS; GAS; MINERAL DUST; NITRIFICATION; PHOTOCHEMISTRY; PHOTOLYSIS; PHOTOOXIDATION; POLLUTANT; PRIORITY JOURNAL; REVIEW; TRAFFIC; TROPOSPHERE; URBAN AREA; WATER VAPOR; WIND; AIR POLLUTANT; AIR POLLUTION; ANALYSIS; ATMOSPHERE; CHEMISTRY;

AIR POLLUTANTS; AIR POLLUTION; ATMOSPHERE; NITROUS ACID; PHOTOCHEMICAL PROCESSES;

EID: 84922257740     PISSN: 10962247     EISSN: 21622906     Source Type: Journal    
DOI: 10.1080/10962247.2014.952846     Document Type: Review

References (132)

1. 2 at a rural mountain site. Geophys. Res. Lett. 33: L02809. doi: 10. 1029/2005GL024643.
2. Acker, K., G. Spindler, and E. Brüggemann. 2004. Nitrous and nitric acid measurements during the INTERCOMP2000 campaign in Melpitz. Atmos. Environ. 38: 6497-6505. doi: 10. 1016/j. atmosenv. 2004. 08. 030.
3. Alicke, B., A. Geyer, A. Hofzumahaus, F. Holland, S. Konrad, H. W. Pätz, J. Schäfer, J. Stutz, A. Volz-Thomas, and U. Platt. 2003. OH formation by HONO photolysis during the BERLIOZ experiment. J. Geophys. Res. 108: PHO 3-1-PHO 3-17.
4. Alicke, B., U. Platt, and J. Stutz. 2002. Impact of nitrous acid photolysis on the total hydroxyl radical budget during the Limitation of Oxidant Production/Pianura Padana Produzione di Ozono study in Milan. J. Geophys. Res. Atmos. 107: LOP 9-1-LOP 9-17.
5. Alvarez, E. G., D. Amedro, C. Afif, S. Gligorovski, C. Schoemaecker, C. Fittschen, J.-F. Doussind, and H. Wortham. 2013. Unexpectedly high indoor hydroxyl radical concentrations associated with nitrous acid. Proc. Natl. Acad. Sci. U. S. A. 110: 13294-13299. doi: 10. 1073/pnas. 1308310110.
6. Ammann, M., M. Kalberer, D. T. Jost, L. Tobler, E. Rössler, D. Piguet, H. W. Gäggeler, and U. Baltensperger. 1998. Heterogeneous production of nitrous acid on soot in polluted airmasses. Nature 395: 157-160. doi: 10. 1038/25965.
7. Ammann, M., E. Rössler, R. Strekowskiw, and C. George. 2005. Nitrogen dioxide multiphase chemistry: Uptake kinetics on aqueous solutions containing phenolic compounds. Phys. Chem. Chem. Phys. 7: 2513-2518. doi: 10. 1039/b501808k.
8. 2 loss on simulated urban grime. Chemphyschem 11: 3956-3961. doi: 10. 1002/cphc. 201000540.
9. Andrés-Hernandez, M. D., J. Notholt, J. Hjorth, and O. Schermes. 1996. A DOAS study on the origin of nitrous acid at urban and non-urban site. Atmos. Environ. 30: 175-180.
10. x species. Atmos. Chem. Phys. 4: 1461-1738. doi: 10. 5194/acp-4-1461-2004.
11. 2 with hydrocarbon soot: Focus on HONO yield, surface modification, and mechanism. J. Phys. Chem. A 111: 6263-6273. doi: 10. 1021/jp068884h.
12. Beine, H. J., I. Allegrini, R. Sparapani, A. Ianniello, and F. Valentini. 2001. Three years of springtime trace gas and particle measurements at Ny-Ålesund, Svalbard. Atmos. Environ. 35: 3645-3658. doi: 10. 1016/S1352-2310(00) 00529-X.
13. Beine, H. J., F. Dominè, A. Ianniello, M. Nardino, I. Allegrini, K. Teinilä, and R. Hillamo. 2003. Fluxes of nitrates between snow surfaces and the atmosphere in the European high arctic. Atmos. Chem. Phys. 3: 335-346. doi: 10. 5194/acp-3-335-2003.
14. Bejan, I., Y. Abd El Aal, I. Barnes, T. Benter, B. Bohn, P. Wiesen, and J. Kleffmann. 2006. The photolysis of ortho-nitrophenols: A new gas phase source of HONO. Phys. Chem. Chem. Phys. 8: 2028-2035. doi: 10. 1039/b516590c.
15. 2) concentrations. Atmos. Environ. 39: 2655-2660. doi: 10. 1016/j. atmosenv. 2005. 01. 018.
16. 2 on solid fluoranthene films: A source of gaseous nitrous acid (HONO) in the urban environment. J. Photochem. Photobiol. A Chem. 273: 23-28. doi: 10. 1016/j. jphotochem. 2013. 07. 016.
17. Crowley. J. N., M. Ammann, R. A. Cox, R. G. Hynes, M. E. Jenkin, A. Mellouki, M. J. Rossi, J. Troe, and T. J. Wallington. 2010. Evaluated kinetic and photochemical data for atmospheric chemistry: Volume V-Heterogeneous reactions on solid substrates. Atmos. Chem. Phys. 10: 9059-9223. doi: 10. 5194/acp-10-9059-2010.
18. Cwiertny, D. M., M. A. Young, and V. H. Grassian 2008. Chemistry and photochemistry of mineral dust aerosol. Ann. Rev. Phys. Chem. 59: 27-51. doi: 10. 1146/annurev. physchem. 59. 032607. 093630.
19. Czader, B. H., X. Li, and B. Rappenglück. 2013. CMAQ modeling and analysis of radicals, radical precursors, and chemical transformations. J. Geophys. Res. Atmos. 118: 11, 376-11, 387. doi: 10. 1002/jgrd. 50807.
20. Czader, B. H., B. Rappenglück, P. Percell, D. W. Byun, F. Ngan, and S. Kim. 2012. Modeling nitrous acid and its impact on ozone and hydroxyl radical during the Texas Air Quality Study 2006. Atmos. Chem. Phys. 12: 6939-6951. doi: 10. 5194/acp-12-6939-2012.
21. Dibb, J. E., M. Arsenault, M. C. Peterson, and R. E. Honrath. 2002. Fast nitrogen oxide photochemistry in Summit, Greenland snow. Atmos. Environ. 36: 2501-2511. doi: 10. 1016/S1352-2310(02)00130-9.
22. Dillon, M. B., M. S. Lamanna, G. W. Schade, A. Goldstein, and R. C. Cohen. 2002. Chemical evolution of the Sacramento urban plume: Transport and oxidation. J. Geophys. Res. 107: 40-45. doi: 10. 1029/2001JD000969.
23. Elshorbany, Y. F., J. Kleffmann, R. Kurtenbach, E. Lissi, M. Rubio, G. Villena, E. Gramsch, A. R. Rickard, M. J. Pilling, and P. Wiesen. 2010. Seasonal dependence of the oxidation capacity of the city of Santiago de Chile. Atmos. Environ. 44: 5383-5394. doi: 10. 1016/j. atmosenv. 2009. 08. 036.
24. Elshorbany, Y. F., R. Kurtenbach, P. Wiesen, E. Lissi, M. Rubio, G. Villena, E. Gramsch, A. R. Rickard, M. J. Pilling, and J. Kleffmann. 2009. Oxidation capacity of the city air of Santiago, Chile. Atmos. Chem. Phys. 9: 2257-2273. doi: 10. 5194/acp-9-2257-2009.
25. 2 on air pollution in the South Coast Air Basin of California. Atmos. Chem. Phys. 10: 1171-1181. doi: 10. 5194/acp-10-1171-2010.
26. Febo, A., C. Perrino, and I. Allegrini. 1996. Measurement of nitrous acid in Milan, Italy, by DOAS and diffusion denuders. Atmos. Environ. 30: 3599-609. doi: 10. 1016/1352-2310(96)00069-6.
27. Febo, A., C. Perrino, and M. Cortiello. 1993. A Denuder technique for the measurement of nitrous acid in urban atmospheres. Atmos. Environ. A Gen. Top. 27: 1721-1728. doi: 10. 1016/0960-1686(93)90235-Q.
28. Frenzel, A., S. Kutsuna, K. Takeuchi, and T. Ibusuki. 2000. Solubility and reactivity of peroxyacetyl nitrate (PAN) in dilute aqueous solutions and in sulphuric acid. Atmos. Environ. 34: 3641-3644. doi: 10. 1016/S1352-2310(00) 00132-1.
29. 2 in laboratory systems and in outdoor and indoor atmospheres: An integrated mechanism. Phys. Chem. Chem. Phys. 5: 223-242. doi: 10. 1039/b208564j.
30. 2 on solid organic compounds: A photochemical source of HONO? Faraday Discuss. 130: 195-210. doi: 10. 1039/b417888m.
31. Gonçalves, M., D. Dabdub, W. L. Chang, O. Jorba, and J. M. Baldasano. 2012. Impact of HONO sources on the performance of mesoscale air quality models. Atmos. Environ. 54: 168-176. doi: 10. 1016/j. atmosenv. 2012. 02. 079.
32. Gutzwiller, L., F. Arens, U. Baltensperger, H. W. Gäggeler, and M. Ammann. 2002a. Significance of semivolatile diesel exhaust organics for secondary HONO formation. Environ. Sci. Technol. 36: 677-682. doi: 10. 1021/es015673b.
33. 2 with resorcinol and 2, 7-naphthalenediol in the aqueous phase at different pH. J. Phys. Chem. A 106: 12045-12050. doi: 10. 1021/jp026240d.
34. Gustafsson, R. J., G. Kyriakou, and R. M. Lambert. 2009. The molecular mechanism of tropospheric nitrous acid production on mineral dust surfaces. Chem. Phys. Chem. 9: 1390-1393. doi: 10. 1002/cphc. 200800259.
35. 2 with soot. Environ. Sci. Technol. 47: 3174-3181. doi: 10. 1021/es304468n.
36. 2 under simulated sunlight. Atmos. Environ. 64: 270-276. doi: 10. 1016/j. atmosenv. 2012. 10. 008.
37. Harrison, R. M., and A.-M. Kitto. 1994. Evidence for a surface source of atmospheric nitrous acid. Atmos. Environ. 28: 1089-1094. doi: 10. 1016/1352-2310 (94)90286-0.
38. Harrison, R. M., J. D. Peak, and G. M. Collins. 1996. Tropospheric cycle of nitrous acid, J. Geophys. Res. 101: 14, 429-14, 439. doi: 10. 1029/96JD00341.
39. He, Y., X. Zhou, J. Hou, H. Gao, and S. B. Bertman. 2006. Importance of dew in controlling the air-surface exchange of HONO in rural forested environments. Geophys. Res. Lett. 33: L02813. doi: 10. 1029/2005GL024348.
40. Heland, J., J. Kleffmann, R. Kurtenbach, and P. Wiesen. 2001. A new instrument to measure gaseous nitrous acid (HONO) in the atmosphere. Environ. Sci. Technol. 35: 3207-3212. doi: 10. 1021/es000303t.
41. 3 above the snowpack at Summit, Greenland. Atmos. Environ. 36: 2629-2640. doi: 10. 1016/S1352-2310(02)00132-2.
42. Hofzumahaus, A., F. Rohrer, K. Lu, B. Bohn, T. Brauers, C.-C. Chang, H. Fuchs, F. Holland, K. Kita, Y. Kondo, X. Li, S. Lou, M. Shao, L. Zeng, A. Wahner, and Y. Zhang. 2009. Amplified trace gas removal in the troposphere. Science 324: 1702-1704. doi: 10. 1126/science. 1164566.
43. Ianniello, A., H. J. Beine, M. S. Landis, R. K. Stevens, G. Esposito, A. Amoroso, and I. Allegrini. 2007. Comparing field performances of denuder techniques in the high Arctic. Atmos. Environ. 41: 1604-1615. doi: 10. 1016/j. atmosenv. 2006. 10. 040.
44. Ianniello, A., H. J. Beine, R. Sparapani, F. Di Bari, I. Allegrini, and J. D. Fuentes. 2002. Denuder measurements of gas and aerosol species above Arctic snow surfaces at Alert 2000. Atmos. Environ. 36: 5299-5309. doi: 10. 1016/S1352-2310(02)00646-5.
45. Jenkin, M. E., R. A. Cox, and D. J. Williams. 1988. Laboratory studies of the kinetics of formation of nitrous acid from the thermal reaction of nitrogen dioxide and water vapour. Atmos. Environ. 22: 487-498. doi: 10. 1016/0004-6981(88)90194-1.
46. Kirchstetter, T., and R. Harley, and D. Littlejohn. 1996. Measurement of nitrous acid in motor vehicle exhaust. Environ. Sci. Technol. 30: 2843-2849. doi: 10. 1021/es960135y.
47. Kleffmann, J. 2007. Daytime sources of nitrous acid (HONO) in the atmospheric boundary layer. Chem. Phys. Chem. 8: 1137-1144. doi: 10. 1002/cphc. 200700016.
48. 2 on carbonaceous surfaces. Phys. Chem. Chem. Phys. 1: 5443-5450. doi: 10. 1039/A905545B.
49. 2 conversion processes on acid surfaces possible atmospheric implications. Atmos. Environ. 32: 2721-2729. doi: 10. 1016/S1352-2310(98)00065-X.
50. 2 conversion on perchloric acid surfaces. J. Chem. Soc. Faraday Trans. 94: 3289-3292. doi: 25/02/2014 09: 57: 02.
51. Kleffmann, J., T. Benter, and P. Wiesen. 2004. Heterogeneous reaction of nitric acid with nitric oxide on glass surfaces under simulated atmospheric conditions. J. Phys. Chem. A 108: 5793-5799. doi: 10. 1021/jp040184u.
52. Kleffmann, J., T. Gavriloaiei, A. Hofzumahaus, F. Holland, R. Koppmann, L. Rupp, E. Schlosser, M. Siese, and A. Wahner. 2005. Daytime formation of nitrous acid: A major source of OH radicals in a forest. Geophys. Res. Lett. 32: L05818. doi: 10. 1029/2005GL022524.
53. Kleffmann, J., J. Heland, R. Kurtenbach, J. C. Lörzer, and P. Wiesen. 2002. A new instrument (LOPAP) for the detection of nitrous acid (HONO). Environ. Sci. Pollut. Res. 9: 48-54.
54. Kleffmann, J., R. Kurtenbach, J. Lörzer, P. Wiesen, N. Kalthoff, B. Vogel, and H. Vogel. 2003. Measured and simulated vertical profiles of nitrous acid-Part I: Field measurements. Atmos. Environ. 37: 2949-2955. doi: 10. 1016/S1352-2310(03)00242-5.
55. Kleffmann, J., J. C. Lörzer, P. Wiesen, C. Kern, S. Trick, R. Volkamer, M. Rodenas, and K. Wirtz. 2006. Intercomparison of the DOAS and LOPAP techniques for the detection of nitrous acid (HONO). Atmos. Environ. 40: 3640-3652. doi: 10. 1016/j. atmosenv. 2006. 03. 027.
56. Kleffmann, J., and P. Wiesen. 2008. Technical Note: Quantification of interferences of wet chemical HONO LOPAP measurements under simulated polar conditions. Atmos. Chem. Phys. 8: 6813-6822. doi: 10. 5194/acp-8-6813-2008.
57. Kurtenbach, R., K. H. Becker, J. A. G. Gomes, J. Kleffmann, J. C. Lörzer, M. Spittler, P. Wiesen, R. Ackermann, A. Geyer, and U. Platt. 2001. Investigations of emissions and heterogeneous formation of HONO in a road traffic tunnel. Atmos. Environ. 35: 3385-3394. doi: 10. 1016/S1352-2310(01)00138-8.
58. Lee, B. H., E. C. Wood, S. C. Herndon, B. L. Lefer, W. T. Luke, W. H. Brune, D. D. Nelson, M. S. Zahniser, and J. W. Munger. 2013. Urban measurements of atmospheric nitrous acid: A caveat on the interpretation of the HONO photostationary state. J. Geophys. Res. 118: 12, 274-12, 281. doi: 10. 1012/2013JD020341.
59. 2 via absorption spectroscopy using tunable mid-infrared continuous-wave quantum cascade lasers. Appl. Phys. B 102: 417-423. doi: 10. 1007/s00340-010-4266-5.
60. Lee, K., J. Xue, A. S. Geyh, H. Özkaynak, B. P. Leaderer, C. J. Weschler, and J. D. Spengler. 2002. Nitrous acid, nitrogen dioxide, and ozone concentrations in residential environments. Environ. Health Perspect. 110: 145-150.
61. Li, G., W. Lei, M. Zavala, R. Volkamer, S. Dusanter, P. Stevens, and L. T. Molina. 2010. Impacts of HONO sources on the photochemistry in Mexico City during the MCMA-2006/MILAGO Campaign. Atmos. Chem. Phys. 10: 6551-656. doi: 10. 5194/acp-10-6551-2010.
62. 2O. Science 319: 1657-1660. doi: 10. 1126/science. 1151443.
63. Li, X., T. Brauers, R. Häseler, B. Bohn, H. Fuchs, A. Hofzumahaus, F. Holland, S. Lou, K. D. Lu, F. Rohrer, M. Hu, L. M. Zeng, Y. H. Zhang, R. M. Garland, H. Su, A. Nowak, A. Wiedensohler, N. Takegawa, M. Shao, and A. Wahner. 2012. Exploring the atmospheric chemistry of nitrous acid (HONO) at a rural site in Southern China. Atmos. Chem. Phys. 12: 1497-1513. doi: 10. 5194/acp-12-1497-2012.
64. Li, Y., J. Ana, M. Min, W. Zhang, F. Wang, and P. Xie. 2011. Impacts of HONO sources on the air quality in Beijing, Tianjin and Hebei Province of China. Atmos. Environ. 45: 4735-4744. doi: 10. 1016/j. atmosenv. 2011. 04. 086.
65. Li, Y. Q., J. J. Schwab, and K. L. Demerjian. 2008b. Fast time response measurements of gaseous nitrous acid using a tunable diode laser absorption spectrometer: HONOemission source from vehicle exhausts. Geophys. Res. Lett. 35: L04803. doi: 10. 1029/2007GL031218.
66. Liao, W., A. T. Case, J. Mastromarino, D. Tan, and J. E. Dibb. 2006. Observations of HONO by laser-induced fluorescence at the South Pole during ANTCI 2003. Geophys. Res. Lett. 33: L09810. doi: 10. 1029/2005GL025470.
67. 2. Atmos. Chem. Phys. 13: 1057-1080. doi: 10. 5194/acp-13-1057-2013.
68. 2 concentrations in the Pearl River Delta 2006: A missing OH source in a VOC rich atmosphere. Atmos. Chem. Phys. 12: 1541-1569. doi: 10. 5194/acp-12-1541-2012.
69. Ma, J., Y. Liu, C. Han, Q. Ma, C. Liu, and H. He. 2013. Review of heterogeneous photochemical reactions of NOy on aerosol-A possible daytime source of nitrous acid (HONO) in the atmosphere. J. Environ. Sci. 25: 326-334. doi: 10. 1016/S1001-0742(12)60093-X.
70. x in the atmosphere. J. Phys. Chem. A 104: 9705-9711. doi: 10. 1021/jp001471a.
71. Monge, M. E., B. D'Anna, and C. George. 2010a. Nitrogen dioxide removal and nitrous acid formation on titanium oxide surfaces-An air quality remediation process? Phys. Chem. Chem. Phys. 12: 8991-8998. doi: 10. 1039/b925785c.
72. Monge, M. E., B. D'Anna, L. Mazri, A. Giroir-Fendler, M. Ammann, D. J. Donaldson, and C. George. 2010b. Light changes the atmospheric reactivity of soot. Proc. Natl. Acad. Sci. U. S. A. 107: 6605-6609. doi: 10. 1073/pnas. 0908341107.
73. 2 on mineral dust: Laboratory experiments and model simulations. Geophys. Res. Lett. 35: L05812. doi: 10. 1029/2007GL032006.
74. Oswald, R., T. Behrendt, M. Ermel, D. Wu, H. Su, Y. Cheng, C. Breuninger, A. Moravek, E. Mougin, C. Delon, B. Loubet, A. Pommerening-Röser, M. Sörgel, U. Pöschl, T. Hoffmann, M. O. Andreae, F. X. Meixner, and I. Trebs. 2013. HONO emissions from soil bacteria as a major source of atmospheric reactive nitrogen. Science 341: 1233-1235. doi: 10. 1126/science. 1242266.
75. Pagsberg, P., E. Bjergbakke, E. Ratajczak, and A. Sillesen. 1997. Kinetics of the gas phase reactionOHþNO(þM)!HONO(þM) and the determination of the UVabsorption cross sections of HONO. Chem. Phys. Lett. 272: 383-390. doi: 10. 1016/S0009-2614(97)00576-9.
76. Perner, D., and U. Platt. 1979. Detection of nitrous acid in the atmosphere by differential optical absorption. Geophys. Res. Lett. 6: 917-920. doi: 10. 1029/GL006i012p00917.
77. Pilegaard, K. 2013. Processes regulating nitric oxide emissions from soils. Phil. Trans. R. Soc. B 368: 20130126. doi: 10. 1098/rstb. 2013. 0126.
78. Pinto, J. P., J. Dibb, B. H. Lee, B. Rappenglück, E. C. Wood, M. Levy, R.-Y. Zhang, B. Lefer, X.-R. Ren, J. Stutz, C. Tsai, L. Ackermann, J. Golovko, S. C. Herndon, M. Oakes, Q.-Y. Meng, J. W. Munger, M. Zahniser, and J. Zheng. 2014. Intercomparison of field measurements of nitrous acid (HONO) during the SHARP campaign. J. Geophys. Res. Atmos. 119: 5583-5601. doi: 10. 1002/2013JD020287.
79. Pitts, J. N., Jr., H. W. Biermann, A. M. Winer, and E. C. Tuazon. 1984. Spectroscopic identification and measurement of gaseous nitrous acid in diluite auto exhaust. Atmos. Environ. 18: 847-854. doi: 10. 1016/0004-6981 (84)90270-1.
80. Pitts, J. N., Jr., D. Grosjean, K. van Cauwenberghe, J. P. Schmid, and D. R. Fitz. 1978. Photooxidation of aliphatic amines under simulated atmospheric conditions: Formation of nitrosamines, nitramines, amides, and photochemical oxidant. Environ. Sci. Technol. 12: 946-953. doi: 10. 1021/es60144a009.
81. Platt, U., and J. Stutz. 2008. Differential Optical Absorption Spectroscopy-Principles and Applications. Berlin: Springer Publications.
82. Qin, M., P. H. Xie, W. Q. Liu, A. Li, K. Dou, W. Fang, J.-G. Liu, and W.-J. Zhang. 2006. Observation of atmospheric nitrous acid with DOAS in Beijing, China. J. Environ. Sci. (China) 18: 69-75. doi: 1001-0742(2006)01-0069-07.
83. 2 coupling at an urban site in Guangzhou City, South China. Atmos. Environ. 43: 5731-5742. doi: 10. 1016/j. atmosenv. 2009. 08. 017.
84. 2. Phys. Chem. Chem. Phys. 6: 3836-3843. doi: 10. 1039/b402195a.
85. 2: Key role of molecular nitric acid and its complexes. J. Phys. Chem. A 110: 6886-6897. doi: 10. 1021/jp056426n.
86. Rappenglück, B., L. Ackermann, S. Alvarez, J. Golovko, M. Buhr, R. A. Field, J. Soltis, D. C. Montague, B. Hauze, S. Adamson, D. Risch, G. Wilkerson, D. Bush, T. Stoeckenius, and C. Keslar. 2014. Strong wintertime ozone events in the Upper Green River basin, Wyoming. Atmos. Chem. Phys. 14: 4909-4934. doi: 10. 5194/acp-14-4909-2014.
87. Rappenglück, B., G. Lubertino, S. Alvarez, J. Golovko, B. Czader, and L. Ackermann. 2013. Radical precursors and related species from traffic as observed and modeled at an urban highway junction. J. Air Waste Manage. Assoc. 63: 11: 1270-1286. doi: 10. 1080/10962247. 2013. 822438.
88. Rasmussen, T. R., M. Brauer, and S. Kjaergaard. 1995. Effects of nitrous acid exposure on humanmucous membranes. Am. J. Respir. Crit. Care Med. 151: 1504-1511. doi: 10. 1164/ajrccm. 151. 5. 7735607.
89. 2 in the polluted winter atmosphere: Possible heterogeneous production on aerosols. Atmos. Environ. 34: 3865-3874. doi: 10. 1016/S1352-2310(00)00179-5.
90. Ren, X., J. E. Sanders, A. Rajendran, R. J. Weber, A. H. Goldstein, S. E. Pusede, E. C. Browne, K.-E. Min, and R. C. Cohen. 2011. A relaxed eddy accumulation system for measuring vertical fluxes of nitrous acid. Atmos. Meas. Tech. 4: 2093-2103. doi: 10. 5194/amt-4-2093-2011.
91. Ródenas, M., A. Mulloz, F. Alacreu, T. Brauers, H. P. Dorn, J. Kleffmann, andW. Bloss. 2013. Assessment of HONO measurements: The FIONACampaign at EUPHORE. In Proceedings of the NATO Advanced Research Workshop on Disposal of Dangerous Chemicals in Urban Areas and Mega Cities, Gdansk, October 9-13, ed. I. Barnes and K. J. Rudziński, 45-57, Chapter 4. Poland: Springer. doi: 10. 1007/978-94-007-5034-0.
92. 3 by volatile organic compounds emitted by motor vehicles. Atmos. Environ. 87: 200-206. doi: 10. 1016/j. atmosenv. 2014. 01. 056.
93. Saltzman, B. E. 1954. Colorimetric micro-determination of nitrogen dioxide in the atmosphere. Anal. Chem. 26: 1949-1955. doi: 10. 1021/ac60096a025.
94. Saliba, N. A., and A. Chamseddine. 2012. Uptake of acid pollutants by mineral dust and their effect on aerosol solubility. Atmos. Environ. 46: 256-263. doi: 10. 1016/j. atmosenv. 2011. 09. 074.
95. Saliba, N. A., H. Yang, and B. J. Finlayson-Pitts 2001. Reaction of gaseous nitric oxide with nitric acid on silica surfaces in the presence of water at room temperature. J. Phys. Chem. A 105: 10339-10346. doi: 10. 1021/jp012330r.
96. 2 chemistry on regional air quality. Atmos. Environ. 43: 6383-6387. doi: 10. 1016/j. atmosenv. 2009. 09. 012.
97. Sarwar, G., S. J. Roselle, R. Mathur, W. Appel, R. L. Dennis, and B. Vogel. 2008. A comparison of CMAQ HONO predictions with observations from the Northeast Oxidant and Particle Study. Atmos. Environ. 42: 5760-5770. doi: 10. 1016/j. atmosenv. 2007. 12. 065.
98. Sickles, J. E., II, and L. L. Hodson. 1989. Fate of nitrous acid on selected collection surfaces. Atmos. Environ. 23: 2321-2324. doi: 10. 1016/0004-6981(89) 90193-5.
99. Simon, P. K., and P. K. Dasgupta. 1993. Wet effluent denuder coupled liquid/ion chromatography systems: Annular and parallel plate denuders. Anal. Chem. 65: 1134-1139. doi: 10. 1021/ac00057a006.
100. Sleiman, M., L. A. Gundel, J. F. Pankow, P. Jacob III, B. C. Singer, and H. Destaillats. 2010. Formation of carcinogens indoors by surface-mediated reactions of nicotine with nitrous acid, leading to potential thirdhand smoke hazards. Proc. Natl. Acad. Sci. 107: 6576-6581. doi: 10. 1073/pnas. 0912820107.
101. 2. Atmos. Chem. Phys. 11: 10433-10447. doi: 10. 5194/acp-11-10433-2011.
102. Spataro, F., A. Ianniello, G. Esposito, I. Allegrini, T. Zhu, and M. Hu. 2013. Occurrence of atmospheric nitrous acid in the urban area of Beijing (China). Sci. Total Environ. 447: 210-224. doi: 10. 1016/j. scitotenv. 2012. 12. 065.
103. 2 with S(IV) in aqueous solutions and comparison with field measurements. Atmos. Environ. 37: 2643-2662. doi: 10. 1016/S1352-2310(03)00209-7.
104. Stemmler, K., M. Ammann, C. Donders, J. Kleffmann, and C. George. 2006. Photosensitized reduction of nitrogen dioxide on humic acid as a source of nitrous acid. Nature 440: 195-198. doi: 10. 1038/nature04603.
105. Stemmler, K., M. Ndour, Y. Elshorbany, J. Kleffmann, B. D'Anna, C. George, B. Bohn, and M. Ammann. 2007. Light induced conversion of nitrogen dioxide into nitrous acid on submicron humic acid aerosol. Atmos. Chem. Phys. 7: 4237-4248. doi: 10. 5194/acp-7-4237-2007.
106. 3 and HONO formation in the nighttime chemistry of the urban atmosphere. J. Geophys. Res. 88: 6673-6682. doi: 10. 1029/JC088iC11p06673.
107. Stutz, J., B. Alicke, R. Ackermann, A. Geyer, S. Wang, A. B. White, E. J. Williams, C. W. Spicer, and J. D. Fast. 2004. Relative humidity dependence of HONO chemistry in urban areas. J. Geophys. Res. 109: D03307. doi: 10. 1029/2003JD004135.
108. 2 and HONO over grass in Milan, Italy. J. Geophys. Res. 107: LOP 5-1-LOP 5-15.
109. Stutz, J., H.-J. Oha, S. I. Whitlow, C. Anderson, J. E. Dibb, J. H. Flynn, B. Rappenglück, and B. Lefer. 2010. Simultaneous DOAS and mist-chamber IC measurements of HONO in Houston, TX. Atmos. Environ. 44: 4090-4098. doi: 10. 1016/j. atmosenv. 2009. 02. 003.
110. Su, H., Y. F. Cheng, P. Cheng, Y. H. Zhang, S. Dong, L. M. Zeng, X. Wang, J. Slanina, M. Shao, and A. Wiedensohler. 2008a. Observation of nighttime nitrous acid (HONO) formation at a nonurban site during PRIDE-PRD2004 in China. Atmos. Environ. 42: 6219-6232. doi: 10. 1016/j. atmosenv. 2008. 04. 006.
111. Su, H., Y. Cheng, R. Oswald, T. Behrendt, I. Trebs, F. X. Meixner, O. A. Meinrat, Y. Zhang, and U. Pöschl, 2011. Soil nitrite as a source of atmospheric HONO and OH radicals. Science 333: 1616-1618. doi: 10. 1126/science. 1207687.
112. Su, H., Y. F. Cheng, M. Shao, D. F. Gao, Z. Y. Yu, L. M. Zeng, J. Slanina, Y. H. Zhang, and A. Wiedensohler. 2008b. Nitrous acid (HONO) and its daytime sources at a rural site during the 2004 PRIDE-PRD experiment in China. J. Geophys. Res. 113: D14312. doi: 10. 1029/2007JD009060.
113. Trebs, I., F. X. Meixner, J. Slanina, R. Otjes, P. Jongejan, and M. O. Andreae. 2004. Real-time measurements of ammonia, acidic trace gases and water-soluble inorganic aerosol species at a rural site in the Amazon Basin. Atmos. Chem. Phys. 4: 967-987. doi: 10. 5194/acp-4-967-2004.
114. 2. Environ. Sci. Technol. 29: 202-206. doi: 10. 1021/es00001a026.
115. Usher, C. R., A. E. Michel, and V. H. Grassian. 2003. Reactions on mineral dust. Chem. Rev. 103: 4883-4939. doi: 10. 1021/cr020657y.
116. VandenBoer, T. C., S. S. Brown, J. G. Murphy, W. C. Keene, C. J. Young, A. A. P. Pszenny, S. Kim, C. Warneke, J. A. de Gouw, J. R. Maben, N. L. Wagner, T. P. Riedel, J. A. Thornton, D. E. Wolfe, W. P. Dubé, F. Öztürk, C. A. Brock, N. Grossberg, B. Lefer, B. Lerner, A. M. Middlebrook, and J. M. Roberts. 2013. Understanding the role of the ground surface in HONO vertical structure: High resolution vertical profiles during NACHTT-11. J. Geophys. Res. Atmos. 118: 10, 155-10, 171. doi: 10. 1002/jgrd. 50721, 2013.
117. 3 in Santiago de Chile. Atmos. Environ. 45: 3867-3873. doi: 10. 1016/j. atmosenv. 2011. 01. 073.
118. Villena, G., P. Wiesen, C. A. Cantrell, F. Flocke, A. Fried, S. R. Hall, R. S. Hornbrook, D. Knapp, E. Kosciuch, R. L. Mauldin III, J. A. McGrath, D. Montzka, D. Richter, K. Ullmann, J. Walega, P. Weibring, A. Weinheimer, R. M. Staebler, J. Liao, L. G. Huey, and J. Kleffmann. 2011b. Nitrous acid (HONO) during polar spring in Barrow, Alaska: A net source of OH radicals? J. Geophys. Res. 116: D00R07. doi: 10. 1029/2011JD016643.
119. Vogel, B., H. Vogel, J. Kleffmann, and R. Kurtenbach. 2003. Measured and simulated vertical profiles of nitrous acid-Part II. Model simulations and indications for a photolytic source. Atmos. Environ. 37: 2957-2966. doi: 10. 1016/S1352-2310(03)00243-7.
120. Wang, L., and J. Zhang. 2000. Detection of nitrous acid by cavity ring-down spectroscopy. Environ. Sci. Technol. 34: 4221-4227. doi: 10. 1021/es0011055.
121. 2-HONO conversion on mineral dust particles. Geophys. Res. Lett. 30: 1595. doi: 10. 1029/2003GL017014.
122. Wong, K. W., H.-J. Oh, B. L. Lefer, B. Rappenglück, and J. Stutz. 2011. Vertical profiles of nitrous acid in the nocturnal urban atmosphere of Houston, TX. Atmos. Chem. Phys. 11: 3595-3609. doi: 10. 5194/acp-11-3595-2011.
123. Wong, K. W., C. Tsai, B. Lefer, C. Haman, N. Grossberg, W. H. Brune, X. Ren, W. Luke, and J. Stutz. 2012. Daytime HONO vertical gradients during SHARP 2009 in Houston, TX. Atmos. Chem. Phys. 12: 635-652, 2012. doi: 10. 5194/acp-12-635-2012.
124. y speciation with a combined wet effluent diffusion denuder-aerosol collector coupled to ion chromatography. Atmos. Environ. 33: 1131-1140. doi: 10. 1016/S1352-2310(98)00295-7.
125. Zhang, R., G. Sarwar, J. C. H. Fung, A. K. H. Lau, and Y. Zhang. 2012. Examining the impact of nitrous acid chemistry on ozone and PM over the Pearl River Delta region. Adv. Meteorol. 2012: 140932. doi: 10. 1155/2012/140932.
126. Zhou, X. 2013. An overview of measurement techniques for atmospheric nitrous acid. In Proceedings of the NATOAdvanced Research Workshop on Disposal of Dangerous Chemicals in Urban Areas and Mega Cities, Gdansk, October 9-13, ed. I. Barnes and K. J. Rudziński, 29-44, Chapter 3. Poland: Springer. doi: 10. 1007/978-94-007-5034-0.
127. Zhou, X., H. J. Beine, R. E. Honrath, J. D. Fuentes, W. Simpson, P. B. Shepson, and J. W. Bottenheim. 2001. Snowpack photochemical production of HONO: A major source of OH in the Arctic boundary layer in springtime. Geophys. Res. Lett. 28: 4087-4090. doi: 10. 1029/2001GL013531.
128. Zhou, X., H. Qiao, G. Deng, and K. Civerolo. 1999. A method for the measurement of atmospheric HONO based on DNPH derivatization and HPLC analysis. Environ. Sci. Technol. 33: 3672-3679. doi: 10. 1021/es981304c.
129. Zhou, X., N. Zhang, M. TerAvest, D. Tang, J. Hou, S. Bertman, M. Alaghmand, P. B. Shepson, M. A. Carroll, S. Griffith, S. Dusanter, and P. S. Stevens. 2011. Nitric acid photolysis on forest canopy surface as a source for tropospheric nitrous acid. Nat. GeoSci. 4: 440-443. doi: 10. 1038/NGEO1164.
130. Zhou, X. L., K. Civerolo, H. P. Dai, G. Huang, J. Schwab, and K. Demerjian. 2002. Summertime nitrous acid chemistry in the atmospheric boundary layer at a rural site in New York State. J. Geophys. Res. 107: 4590-4600. doi: 10. 1029/2001JD001539.
131. x environments: Significant atmospheric implications. Geophys. Res. Lett. 30: 2217-2220. doi: 10. 1029/2003GL018620.
132. Ziemba, L. D., J. E. Dibb, R. J. Griffin, C. H. Anderson, S. I. Whitlow, B. L. Lefer, B. Rappenglück, and J. Flynn. 2010. Heterogeneous conversion of nitric acid to nitrous acid on the surface of primary organic aerosol in an urban atmosphere. Atmos. Environ. 44: 4081-4089. doi: 10. 1016/j. atmosenv. 2008. 12. 024.