Wet annular denuder measurements of nitrous acid: Laboratory study of the artefact reaction of NO2 with S(IV) in aqueous solution and comparison with field measurements

Atmospheric Environment

Volumn 37, Issue 19, 2003, Pages 2643-2662

  Spindler, G ^a   Hesper, J ^a   Bruggemann E ^a   Dubois, R ^a   Muller Th ^a   Herrmann, H ^a  

^a LEIBNIZ INSTITUTE FOR TROPOSPHERIC RESEARCH   (Germany)

Author keywords

Artefact correction; Field measurements; Kinetic investigation; Nitrous acid; Wet annular denuder

Indexed keywords

ABSORPTION; INORGANIC ACIDS; NITROGEN OXIDES; PH EFFECTS; RATE CONSTANTS; SULFUR DIOXIDE; TROPOSPHERE;

PHASE FORMATION;

ENVIRONMENTAL ENGINEERING;

NITROUS ACID; SULFUR;

ATMOSPHERIC CHEMISTRY; COMPARATIVE STUDY; FIELD METHOD; LABORATORY METHOD; NITROGEN DIOXIDE; NITROUS ACID; PARTICULATE MATTER; TROPOSPHERE;

ABSORPTION; AQUEOUS SOLUTION; ARTICLE; ARTIFACT; CHEMICAL REACTION; COMPARATIVE STUDY; FIELD EXPERIMENT; ION PAIR CHROMATOGRAPHY; KINETICS; LABORATORY; MEASUREMENT; PARTICULATE MATTER; PHASE TRANSITION; PRIORITY JOURNAL; TEMPERATURE;

EID: 0038289131     PISSN: 13522310     EISSN: None     Source Type: Journal    
DOI: 10.1016/S1352-2310(03)00209-7     Document Type: Article

References (105)

1. Acker K., Möller D., Wieprecht W., Auel R., Kalass D., Tscherwenka W. Nitrous and nitric acid measurements inside and outside of clouds at Mt. Brocken. Journal of Water, Air, and Soil Pollution. 130:2001;331-336.
2. 2O on soot generated in the laboratory. a diffusion tube study at ambient temperature Physical Chemistry Chemical Physics. 2:2000;5584-5593.
3. Ali Z., Thomas C.L.P., Alder J.F. Denuder tubes for sampling of gaseous species. Analyst. 114:1989;759-769.
4. Allegrini I., De Dantis F., di Palo V., Febo A., Perrino C., Possanzini M. Annular denuder method for sampling reactive gases and aerosols in the atmosphere. Science of the Total Environment. 67:1987;1-16.
5. Allegrini I., Febo A., Perrino C., Masia P. Measurements of atmospheric nitric acid in gas phase and nitrate in particulate matter by means of annular denuders. International Journal of Environmental Analytical Chemistry. 54:1994;183-201.
6. Ammann M., Kalberer M., Jost D.T., Tobler L., Rössler E., Piguet D., Gäggeler H.W., Baltensberger U. Heterogeneous production of nitrous acid on soot in polluted air masses. Nature. 395:1998;157-160.
7. Andres-Hernandez M.D., Notholt J., Hjorth J., Schrems O. A DOAS study on the origin of nitrous acid at urban and non-urban sites. Atmospheric Environment. 30:1996;175-180.
8. Appel B.R., Winer A.M., Tokiwa Y., Biermann H.W. Comparison of atmospheric nitrous acid measurements by annular denuder and differential optical absorption systems. Atmospheric Environment. 24A:1990;611-616.
9. 2 on diesel soot particles. Environmental Science and Technology. 35:2001;2191-2199.
10. 2+soot reaction in the atmosphere. Journal of Geophysical Research. 104:1999;1729-1736.
11. 2-oxidation in the droplet phase. Atmospheric Environment. 12:1978;231-239.
12. 2 measurements in Taiwan. Journal of the Air and Waste Management Association. 50:2000;125-130.
13. Becker K.H., Kleffmann J., Kurtenbach R., Wiesen P. Solubility of nitrous acid (HONO) in sulfuric solutions. Journal of Physical Chemistry. 100:1996;14984-14990.
14. Brüggemann E., Spindler G. Wet and dry deposition of sulphur at the site Melpitz in East Germany. Water, Air, and Soil Pollution. 109:1999;81-99.
15. Cape J.N., Hargreaves K.J., Stereton-West R., Fowler D., Colvile R.N., Choularton T.W., Gallagher M.W. Nitrite in orographic clouds as an indicator of nitrous acid in rural air. Atmospheric Environment. 26A:1992;2301-2307.
16. Carslaw N., Carslaw D. The gas-phase chemistry of urban atmospheres. Surveys in Geophysics. 22:2001;31-53.
17. 2 with sulfur (IV) over the pH range 5.3-13. Environmental Science and Technology. 22:1988;586-589.
18. Dasgupta P.K. A diffusion scrubber for the collection of atmospheric gases. Atmospheric Environment. 18:1984;1593-1599.
19. DeMore, W.B., Sander, S.P., Golden, D.M., Hampson, R.F., Kuroly, M.J., Howard, C.J., Ravishankara, A.R., Kolb, C.E., Molina, M.J., 1997. Chemical kinetics and photochemical data for use in stratospheric modeling, Evaluation No. 12. JPL. Publ. No. 97-4.
20. - photolysis in aqueous solution. Berichte der Bunsen-Gesellschaft für Physikalische Chemie. 94:1990;594-599.
21. Febo A., De Santis F., Perrino C., Giustro M. Evaluation of laboratory and field performance of denuder tubes. a theoretical approach Atmospheric Environment. 7:1989;1517-1530.
22. Febo A., Perrino C., Allegrini I. Measurement of nitrous acid in Milan, Italy, by DOAS and diffusion denuders. Atmospheric Environment. 30:1996;3599-3609.
23. Ferm M., Sjödin A. A sodium carbonate coated denuder for determination of nitrous acid in the atmosphere. Atmospheric Environment. 19:1985;979-983.
24. 2(g) on water droplets. Journal of Geophysical Research. 92:1987;10887-10895.
25. Grassian V.H. Chemical reactions of nitrogen oxides on the surface of oxide, carbonate, soot, and mineral dust particles. implication for the chemical balance of the troposphere Journal of Physical Chemistry A. 106:2002;860-877.
26. Grätzel M., Henglein A., Lilie J., Beck G. Pulsradiolytische Untersuchung einiger Elementarprozesse der Oxydation und Reduktion des Nitrit Ions. Berichte der Bunsen-Gesellschaft für Physikalische Chemie. 73:1969;646-653.
27. Gutzwiller L., Arens F., Baltensperger U., Gäggerler H.W., Ammann M. Significance of semivolatile diesel exhaust organics for secondary HONO formation. Environmental Science and Technology. 36:2002;677-682.
28. Harris G.W., Carter W.P.L., Winer A.M., Pitts J.M. Jr., Platt U., Perner D. Observation of nitrous acid in the Los Angeles atmosphere and the implications for the ozone-precurser relationships. Environmental Science and Technology. 16:1982;414-419.
29. Harrison R.M., Kitto A.M.N. Evidence for a surface source of atmospheric nitrous acid. Atmospheric Environment. 28:1994;1089-1094.
30. 3 over a semi-natural ecosystem. discussion Atmospheric Environment. 31:1997;2891-2892.
31. Harrison R.M., Peak J.D., Collins G.M. Tropospheric cycle of nitrous acid. Journal of Geophysical Research. 101:1996;14429-14439.
32. Heland, J., Kleffmann, J., Kurtenbach, R., Lörzer, J., Wiesen, P., 2001a. A new instrument to measure HONO in air: first intercomparison and application. In: Hrsg. Lay, J.P., Becker, K.H., Hauthal, W., Rindone, B., Zetzsch, C. (Eds.), Atmospheric Diagnostics in Urban Regions. Erich Schmidt Verlag, Berlin.
33. Heland J., Kleffmann J., Kurtenbach R., Wiesen P. A new instrument to measure gaseous nitrous acid (HONO) in the atmosphere. Environmental Science and Technology. 35:2001;3207-3212.
34. 4-radicals with aromatic-compounds. Faraday Discussions. 100:1995;129-153.
35. x-(x=3,4,5) radical-anions in aqueous-solution. Journal of Molecular Structure. 348:1995;183-186.
36. Herrmann H., Jacobi H.W., Raabe G., Reese A., Zellner R. Laser-spectroscopic laboratory studies of atmospheric aqueous-phase free-radical chemistry. Fresenius Journal of Analytical Chemistry. 355:1996;343-344.
37. Huang G., Zhou X.L., Deng G.H., Qiao H.C., Civerolo K. Measurements of atmospheric nitrous acid and nitric acid. Atmospheric Environment. 36:2002;2225-2235.
38. 2. Journal of Physical Chemistry. 90:1986;1193-1198.
39. Jacob D.L. Heterogeneous chemistry and tropospheric ozone. Atmospheric Environment. 34:2000;2131-2159.
40. Kalberer M., Ammann M., Arens F., Gäggeler H.W., Baltensberger U. Heterogeneous formation of nitrous acid (HONO) on soot aerosol particles. Journal of Geophysical Research. D104:1999;13825-13832.
41. Kessler C., Platt U. Nitrous acid in polluted air masses. sources and formation pathways Versino B., Angeletti G. Proceedings of the European Symposium on Physico-chemical Behavior of Atmospheric Pollutants. 1984;412-422 Reidel, Dordrecht.
42. 2 in ambient air by a wet annular denuder system. Atmospheric Environment. 22:1988;2541-2548.
43. Khlystov A., Wyers G.P., Slanina J. The steam-jet aerosol collector. Atmospheric Environment. 29:1995;2229-2234.
44. 2 conversion processes on acid surfaces. possible atmospheric implications Atmospheric Environment. 32:1998;2721-2729.
45. 2 on carbonaceous surfaces. Physical Chemistry Chemical Physics. 1:1999;5443-5450.
46. Kurtenbach R., Becker K.H., Gomes J.A.G., Kleffmann J., Lörzer J.C., Splitter M., Wiesen P., Ackermann R., Geyer A., Platt U. Investigations of emissions and heterogeneous formation of HONO in a road traffic tunnel. Atmospheric Environment. 35:2001;3385-3394.
47. Lammel G., Cape J.N. Nitrous acid and nitrite in the atmosphere. Chemical Society Reviews. 25:1996, 361-369.
48. Lammel G., Metzig G. On the occurrence of nitrite in urban fogwater. Chemosphere. 37:1998;1603-1614.
49. Lee Y.N., Schwartz S.E. Evaluation of the rate of uptake of nitrogen-dioxide by atmospheric and surface liquid water. Journal of Geophysical Research. 86:1981;1971-1983.
50. Lee Y.N., Schwartz S.E. Kinetics of oxidation of aqueous sulfur(IV) by nitrogen dioxide. Pruppacher H.R., Semonin R.G., Slinn W.G.N. Precipitation Scavenging Dry Deposition and Resuspension. 1983;453-467 Elsevier, New York.
51. Li S.-M. Equilibrium of particle nitrite with gas phase HONO. tropospheric measurements in the high arctic during polar sunrise Journal of Geophysical Research. 99:1994;25469-25478.
52. Lide, D.R. (Ed.), 1989-1990. Handbook of Chemistry and Physics, 70th Edition. CRC Press, Boca Raton, FL, USA.
53. Littlejohn D., Wang Y., Chang S.-G. Oxidation of aqueous sulfite ion by nitrogen dioxide. Environmental Science and Technology. 27:1993;2162-2167.
54. Løgager T., Sehested K. Formation and decay of peroxynitrous acid. a pulse radiolysis study Journal of Physical Chemistry. 97:1993;6664-6669.
55. 3-Radikal. Dissertation, Universität Leipzig.
56. Matsumoto M., Okita T. Long term measurements of atmospheric gaseous and aerosol species using an annular denuder system in Nara, Japan. Atmospheric Environment. 32:1998;1419-1425.
57. Mark G., Korth H.G., Schuchmann H.P., von Sonntag C. The photochemistry of aqueous nitrate ion revisited. Journal of Photochemistry and Photobiology. A101:1996;89-103.
58. Milani M.R., Dasgupta P.K. Measurement of nitrogen dioxide and nitrous acid using gas-permeable liquid core waveguides. Analytica Chimica Acta. 431:2001;169-180.
59. Monteith J.L., Unsworth M.H. Principles of Environmental Physics. 2nd Edition:1990;Edward Arnold, London, UK.
60. Msibi I.M., Shi J.P., Harrison R.M. Accommodation coefficient for trace gas uptake using deposition profile measurement in a annular reactor. Journal of Atmospheric Chemistry. 17:1993;339-351.
61. Müller Th., Dubois R., Spindler G., Brüggemann E., Ackermann R., Geyer A., Platt U. Measurements of nitrous acid by DOAS and diffusion denuders. Borrell P.M., Borell P. A Comparison. Proceedings of the EUROTRAC Symposium '98. Vol. 1:1999;345-349 WIT press, Southampton.
62. 3 over a semi-natural ecosystem. Atmospheric Environment. 30:1996;3017-3025.
63. 2. Atmospheric Environment. 26A:1992;211-218.
64. 2 by wet-annular denuder air sampling with on-line chromatographic analysis. International Journal of Environmental Analytical Chemistry. 62:1996;207-218.
65. Perner D., Platt U. Detection of nitrous acid in the atmosphere by differential optical absorption. Geophysical Research Letters. 6:1979;917-920.
66. 2 and NO measurements in automobile engine exhaust by optical absorption. Grisar R., Preier H., Schmidke G., Restelli G. Monitoring of Gaseous Pollutants by tuneable diode lasers. 1987;116-119 Reidel, Dordrecht.
67. Pitts J.N. Jr., Biermann H.W., Winer A.M., Tuazon E.C. Spectroscopic identification and measurement of gaseous nitrous acid in dilute auto exhaust. Atmospheric Environment. 18:1984;847-854.
68. Pitts J.N. Jr., Sanhueza, E., Atkinson R., Charter W.P.L., Winer A.M., Harris G.W., Plum C.N. An investigation of the dark formation of nitrous acid in environmental chambers. International Journal of Chemical Kinetics. 16:1984;919-939.
69. 3 radicals and HONO. Geophysical Research Letters. 11:1994;557-560.
70. Platt U. The Origin of nitrous and nitric acid in the atmosphere. Jaeschke W. Chemistry of Multiphase Atmospheric Systems. NATO ASI Series. Vol. G6:1986;299-319 Springer, Berlin, Heidelberg.
71. Platt U. Modern methods of the measurement of atmospheric trace gases. Physical Chemistry Chemical Physics. 1:1999;5409-5415.
72. Platt U., Perner D., Harris G.W., Winer A.M., Pitts J.N. Observation of HONO in an urban atmosphere by differential optical absorption. Nature. 285:1980;312-314.
73. 3 Journal of Atmospheric Chemistry. 16:1993;1-21.
74. 2 in the polluted winter atmosphere. possible heterogeneous production on aerosols Atmospheric Environment. 34:2000;3865-3874.
75. Saliba N.A., Mochida M., Finlayson-Pitts B.J. Laboratory studies of sources of HONO in polluted urban atmospheres. Geophysical Research Letters. 27:2000;3229-3232.
76. Sakamaki F., Hatakeyama S., Akimoto H. Formation of nitrous acid and nitric oxide in the heterogeneous dark reaction of nitrogen dioxide and water vapor in a smog chamber. International Journal of Chemical Kinetics. 15:1983;1013-1029.
77. Schwartz S.E. Mass transport considerations pertinent to aqueous phase reactions of gases in liquid-water clouds. Jaeschke W. Chemistry of Multiphase Atmospheric Systems, NATO ASI Series. Vol. G6:1986;415-471 Springer, Berlin, Heidelberg.
78. Schwartz S.E., White W.H. Kinetics of reactive dissolution of nitrogen oxides into aqueous solution. Advances in Environmental Science and Technology. 12:1983;3-109.
79. Simon P.K., Dasgupta P.K. Wet effluent denuder coupled liquid/ion chromatography system. annular and parallel plate denuders Analytical Chemistry. 65:1993;1134-1139.
80. Sjödin A. Studies of the diurnal variation of nitrous acid in urban air. Atmospheric Environment. 22:1988;1086-1089.
81. Sjödin A., Ferm A. Measurements of nitrous acid in an urban area. Atmospheric Environment. 19:1985;985-992.
82. 2 at the SANA core station Melpitz. Meteorologische Zeitschrift NF. 5:1996;205-220.
83. 2) concentration measurements and estimation of dry deposition over grassland in eastern Germany. Borrell P.M., Borell P. Proceedings of the EUROTRAC Symposium '98. Vol. 2:1999;223-227 WIT press, Southampton.
84. Spindler G., Teichmann U., Sutton M.A. Ammonia dry deposition over grassland - micrometeorological flux-gradient measurements and bidirectional flux calculation using an inferential model. Quarterly Journal of the Royal Meteorological Society. 127:2001;795-814.
85. Stanbury D.M. Reduction potentials involving inorganic free radicals in aqueous solution. Advances in Inorganic Chemistry. 33:1989;69-138.
86. Stockwell W.R., Calvert J.G. The near ultraviolet absorption spectrum of gaseous nitrous acid and nitrogen(III)oxide. Journal of Photochemistry. 8:1978;193-203.
87. Stull B. An Introduction to Boundary Layer Meteorology. 1988;Kluwer Academic Publishers, Dordrecht.
88. Stutz J., Kim E.S., Platt U., Bruno P., Perrino C., Febo A. UV-visible absorption cross sections of nitrous acid. Journal of Geophysical Research. 105D:2000;14585-14592.
89. Tang, I.N., Lee, J.H., 1987. In: Gordon, G.E., Johnson, R.W. (Eds.), The Chemistry of Acid Rain, Sources and Atmospheric Processes. American Chemical Society Symposium Series 349, Washington, DC, pp. 109-117.
90. 4 in aqueous solution. Journal of the American Chemical Society. 92:1970;5821-5828.
91. Večera Z., Dasgupta P.K. Measurement of ambient nitrous-acid and a reliable calibration source for gaseous nitrous-acid. Environmental Science and Technology. 25:1991;255-260.
92. Wagner I., Strehlow H., Busse G. Flash-photolysis of nitrate ions in aqueous solution. Zeitschrift für Physikalische Chemie. 123:1980;1-33.
93. - in aqueous solution. Journal of Physical Chemistry. 92:1988;6278-6283.
94. White J.U. Long optical paths of large apertures. Journal of the Optical Society of America. 32:1942;285-288.
95. Williams E.L., Grosjean D. Removal of atmospheric oxidants with annular denuders. Environmental Science and Technology. 24:1990;811-814.
96. 2O. Journal of Physical Chemistry A. 104:2000;329-335.
97. 2 on aqueous surfaces. Journal of Physical Chemistry. 93:1989;1159-1172.
98. Wyers G.P., Otjes R.P., Slanina J. A continuous-flow denuder for the measurement of ambient concentrations and surface-exchange fluxes of ammonia. Atmospheric Environment. 27a:1993;2085-2090.
99. 2 in an automated denuder. Proceedings of the EUROTRAC Symposium '92. SPB Academic Publishing, The Hague, The Netherlands, pp. 710-712.
100. Yuanqian L., Wenxuan M., Li W. Sampling method for ammonia and ammonium particulates in air with an annular diffusion denuder and a filter pack. Chinese Journal of Analytical Chemistry. 25:1997;238-242.
101. Zhang R., Ming-Taun L., Keyser L.F. Heterogeneous chemistry of HONO on liquid sulfuric acid. a new mechanism of chlorine activation on stratospheric sulfate aerosols Journal of Physical Chemistry. 100:1996;339-345.
102. 2 in the temperature range 278-353. K Journal of Atmospheric Chemistry. 11:1990;411-425.
103. y speciation with a combined wet effluent diffusion denuder-aerosol collector coupled to ion chromatography. Atmospheric Environment. 33:1999;1131-1140.
104. 2. a major source of OH in the arctic boundary layer in springtime Geophysical Research Letters. 28:2001;4087-4090.
105. Zhou X., Qiao H., Deng G., Civerolo K. A method for the measurement of atmospheric HONO based on DNPH derivatization and HPLC analysis. Environmental Science and Technology. 33:1999;3672-3679.