A "naked" FeIII-(O22-)-CuII species allows for structural and spectroscopic tuning of low-spin heme-peroxo-Cu complexes

Journal of the American Chemical Society

Volumn 137, Issue 3, 2015, Pages 1032-1035

  Garcia Bosch, Isaac ^a   Adam, Suzanne M ^a   Schaefer, Andrew W ^b   Sharma, Savita K ^a   Peterson, Ryan L ^a   Solomon, Edward I ^b   Karlin, Kenneth D ^a  

^a JOHNS HOPKINS UNIVERSITY   (United States)

^b STANFORD UNIVERSITY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

IRON COMPOUNDS; PORPHYRINS;

2-METHYLTETRAHYDROFURAN; COORDINATION GEOMETRY; CU COMPOUNDS; DATA CORRELATIONS; DFT CALCULATION; NEW APPROACHES; SPECTROSCOPIC CHARACTERIZATION; STRUCTURAL INSIGHTS;

COPPER COMPOUNDS;

COORDINATION COMPOUND; COPPER DERIVATIVE; IRON DERIVATIVE; PORPHYRIN DERIVATIVE; TETRAHYDROFURAN DERIVATIVE; COPPER; FERROUS ION; HEME; OXYGEN;

ARTICLE; CHEMICAL BOND; CHEMICAL STRUCTURE; COMPLEX FORMATION; DENSITY FUNCTIONAL THEORY; GEOMETRY; SPECTROSCOPY; CHEMISTRY; QUANTUM THEORY;

COORDINATION COMPLEXES; COPPER; FERROUS COMPOUNDS; HEME; MOLECULAR STRUCTURE; OXYGEN; QUANTUM THEORY;

EID: 84921913835     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/ja5115198     Document Type: Article

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