Ferrocene-functionalized graphene oxide nanosheets: Efficient electronic communication between ferrocene centers across graphene nanosheets

Electrochimica Acta

Volumn 156, Issue , 2015, Pages 267-273

  Lu, Yizhong ^a,b   Jiang, Yuanyuan ^a,b   Wu, Haibin ^a   Chen, Wei ^a  

^a CHANGCHUN INSTITUTE OF APPLIED CHEMISTRY   (China)

^b UNIVERSITY OF CHINESE ACADEMY OF SCIENCES   (China)

Author keywords

electronic communication; ferrocene; Graphene; intervalence charge transfer; voltammetry

Indexed keywords

CHARGE TRANSFER; INFRARED DEVICES; NANOSHEETS; ORGANIC POLYMERS; ORGANOMETALLICS; VOLTAMMETRY;

CONJUGATED STRUCTURES; ELECTRON DELOCALIZATION; ELECTRONIC COMMUNICATIONS; FERROCENES; FUNCTIONALIZED GRAPHENE; GRAPHENE OXIDE NANOSHEET; INTERVALENCE CHARGE TRANSFER; SPECTROSCOPIC FEATURES;

GRAPHENE;

EID: 84921491465     PISSN: 00134686     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.electacta.2015.01.049     Document Type: Article

References (48)

1. S. Barlow, and D. OHare Metal-metal interactions in linked metallocenes Chem. Rev. 97 1997 637 669
2. B. Bechlars, D.M. D'Alessandro, D.M. Jenkins, A.T. Iavarone, S.D. Glover, C.P. Kubiak, and J.R. Long High-spin ground states via electron delocalization in mixed-valence imidazolate-bridged divanadium complexes Nat. Chem. 2 2010 362 368
3. J.R. Winkler, and H.B. Gray Electron-Transfer in Ruthenium-Modified Proteins Chem. Rev. 92 1992 369 379
4. G. Mclendon, and R. Hake Interprotein Electron-Transfer Chem. Rev. 92 1992 481 490
5. B.S. Brunschwig, C. Creutz, and N. Sutin Optical transitions of symmetrical mixed-valence systems in the Class II-III transition regime Chem. Soc. Rev. 31 2002 168 184
6. A. Heckmann, and C. Lambert Organic Mixed-Valence Compounds: A Playground for Electrons and Holes Angew. Chem. Int. Edit. 51 2012 326 392
7. C. Lambert, and G. Noll The class II/III transition in triarylamine redox systems J. Am. Chem. Soc. 121 1999 8434 8442
8. D.R. Gamelin, E.L. Bominaar, M.L. Kirk, K. Wieghardt, and E.I. Solomon Excited-state contributions to ground-state properties of mixed-valence dimers: Spectral and electronic-structural studies of [Fe-2(OH)(3)(tmtacn)(2)](2+) related to the [Fe2S2](+) active sites of plant-type ferredoxins J. Am. Chem. Soc. 118 1996 8085 8097
9. D.R. Gamelin, E.L. Bominaar, C. Mathoniere, M.L. Kirk, K. Wieghardt, J.J. Girerd, and E.I. Solomon Excited-state distortions and electron delocalization in mixed-valence dimers: Vibronic analysis of the near-IR absorption and resonance Raman profiles of [Fe-2(OH)(3)(tmtacn)(2)](2+) Inorg. Chem. 35 1996 4323 4335
10. A.C. Ribou, J.P. Launay, M.L. Sachtleben, H. Li, and C.W. Spangler Intervalence electron transfer in mixed valence diferrocenylpolyenes. Decay law of the metal-metal coupling with distance Inorg. Chem. 35 1996 3735 3740
11. T.Y. Dong, T.J. Ke, S.M. Peng, and S.K. Yeh Electron-Transfer in the Mixed-Valence Complexes (E)-1,2-Bis(1'-Ethyl-1-Ferrocenyl)-1,2-Dimethylethylene and (Z)-1,2-Bis(1'-Ethyl-1-Ferrocenyl)-1,2-Dimethylethylene Inorg. Chem. 28 1989 2103 2106
12. V.V. Dementev, F. Cervanteslee, L. Parkanyi, H. Sharma, K.H. Pannell, M.T. Nguyen, and A. Diaz Structure and Electrochemistry of Ferrocenyloligosilanes - Alpha Omega-Bis(Ferrocenyl) Oligosilanes and Alpha,Omega-(1,1'-Ferrocenediyl) Oligosilanes Organometallics 12 1993 1983 1987
13. H. Sun, J. Steeb, and A.E. Kaifer Efficient electronic communication between two identical ferrocene centers in a hydrogen-bonded dimer J. Am. Chem. Soc. 128 2006 2820 2821
14. D.O. Cowan, C. Levanda, J. Park, and F. Kaufman Organic Solid-State.8. Mixed-Valence Ferrocene Chemistry Acc. Chem. Res. 6 1973 1 7
15. R.D. Williams, V.I. Petrov, H.P. Lu, and J.T. Hupp Intramolecular electron transfer in biferrocene monocation: Evaluation of Franck-Condon effects via a time-dependent analysis of resonance Raman scattering in the extended near-infrared J. Phys. Chem. A 101 1997 8070 8076
16. G.M. Brown, T.J. Meyer, D.O. Cowan, C. Levanda, F. Kaufman, P.V. Roling, and M.D. Rausch Oxidation-State and Electron-Transfer Properties of Mixed-Valence 1,1'-Polyferrocene Ions Inorg. Chem. 14 1975 506 511
17. R. Rulkens, A.J. Lough, I. Manners, S.R. Lovelace, C. Grant, and W.E. Geiger Linear oligo(ferrocenyldimethylsilanes) with between two and nine ferrocene units: Electrochemical and structural models for poly(ferrocenylsilane) high polymers J. Am. Chem. Soc. 118 1996 12683 12695
18. W.H. Morrison, S. Krogsrud, and D.N. Hendrick Polarographic and Magnetic Susceptibility Study of Various Biferrocene Compounds Inorg. Chem. 12 1973 1998 2004
19. D. Astruc From organotransition-metal chemistry toward molecular electronics: Electronic communication between ligand-bridged metals Acc. Chem. Res. 30 1997 383 391
20. D. Astruc, M. Lacoste, and L. Toupet How to Design a Fast 2-Electron Transfer - Structural Rearrangement in the 2nd Electron-Transfer Provides Stabilization J. Chem. Soc. Chem. Comm. 1990 558 561
21. J. Alvarez, and A.E. Kaifer Structural and pH control on the electronic communication between two identical ferrocene sites Organometallics 18 1999 5733 5734
22. M.B. Robin, and P. Day Mixed Valence Compounds -A Survey and Classification Adv. Inorg. Chem. Radiochem. 10 1967 247 422
23. W. Chen, S.W. Chen, F.Z. Ding, H.B. Wang, L.E. Brown, and J.P. Konopelski Nanoparticle-mediated intervalence transfer J. Am. Chem. Soc. 130 2008 12156 12162
24. W. Chen, N.B. Zuckerman, X.W. Kang, D. Ghosh, J.P. Konopelski, and S.W. Chen Alkyne-Protected Ruthenium Nanoparticles J. Phys. Chem. C 114 2010 18146 18152
25. X.W. Kang, N.B. Zuckerman, J.P. Konopelski, and S.W. Chen Alkyne-Stabilized Ruthenium Nanoparticles: Manipulation of Intraparticle Charge Delocalization by Nanoparticle Charge States Angew. Chem. Int Edit. 49 2010 9496 9499
26. Y. Song, X.W. Kang, N.B. Zuckerman, B. Phebus, J.P. Konopelski, and S.W. Chen Ferrocene-functionalized carbon nanoparticles Nanoscale 3 2011 1984 1989
27. M. Yamada, I. Quiros, J. Mizutani, K. Kubo, and H. Nishihara Preparation of palladium nanoparticles functionalized with biferrocene thiol derivatives and their electro-oxidative deposition Phys. Chem. Chem. Phys. 3 2001 3377 3381
28. W. Chen, L.E. Brown, J.P. Konopelski, and S.W. Chen Intervalence transfer of ferrocene moieties adsorbed on electrode surfaces by a conjugated linkage Chem. Phys. Lett. 471 2009 283 285
29. N.S. Hush Intervalence-transfer absorption. Part 2. Theoretical considerations and spectroscopic data Prog. Inorg. Chem 8 1967 391 444
30. Y.W. Zhu, S. Murali, W.W. Cai, X.S. Li, J.W. Suk, J.R. Potts, and R.S. Ruoff Graphene and Graphene Oxide: Synthesis, Properties, and Applications Adv. Mater. 22 2010 3906 3924
31. C.C. Huang, C. Li, and G.Q. Shi Graphene based catalysts Energ. Environ. Sci. 5 2012 8848 8868
32. Y.Y. Shao, J. Wang, H. Wu, J. Liu, I.A. Aksay, and Y.H. Lin Graphene Based Electrochemical Sensors and Biosensors: A Review Electroanalysis 22 2010 1027 1036
33. W.S. Hummers, and R.E. Offeman Preparation of Graphitic Oxide J. Am. Chem. Soc. 80 1958 1339
34. D. Li, M.B. Muller, S. Gilje, R.B. Kaner, and G.G. Wallace Processable aqueous dispersions of graphene nanosheets Nat. Nanotechnol. 3 2008 101 105
35. L.S. Fan, Q.X. Zhang, K.K. Wang, F.H. Li, and L. Niu Ferrocene functionalized graphene: preparation, characterization and efficient electron transfer toward sensors of H2O2 J. Mater. Chem. 22 2012 6165 6170
36. C. Jin, J. Lee, E. Lee, E. Hwang, and H. Lee Nonvolatile resistive memory of ferrocene covalently bonded to reduced graphene oxide Chem. Commun. 48 2012 4235 4237
37. Y.Z. Lu, Y.Y. Jiang, W.T. Wei, H.B. Wu, M.M. Liu, L. Niu, and W. Chen Novel blue light emitting graphene oxide nanosheets fabricated by surface functionalization J. Mater. Chem. 22 2012 2929 2934
38. M.M. Liu, Y.Z. Lu, and W. Chen PdAg Nanorings Supported on Graphene Nanosheets: Highly Methanol-Tolerant Cathode Electrocatalyst for Alkaline Fuel Cells Adv. Funct. Mater. 23 2013 1289 1296
39. Y.S. Sohn, D.N. Hendrickson, J.H. Smith, and H.B. Gray Single-crystal electronic spectrum of ferrocene at 4.2 degrees K Chem. Phys. Lett. 6 1970 499 501
40. T.Y. Dong, K.L. Chen, M.C. Lin, and L.S. Lee Toward the development of molecular wires: Ruthenium(II) terpyridine complexes containing polyferrocenyl as a spacer Organometallics 24 2005 4198 4206
41. T. Mochida, H. Shimizu, S. Suzuki, and T. Akasaka Synthesis and properties of azole-substituted ferrocenes J. Organomet. Chem. 691 2006 4882 4889
42. L.H. Guan, Z.J. Shi, M.X. Li, and Z.N. Gu Ferrocene-filled single-walled carbon nanotubes Carbon 43 2005 2780 2785
43. D. Yang, A. Velamakanni, G. Bozoklu, S. Park, M. Stoller, R.D. Piner, S. Stankovich, I. Jung, D.A. Field, C.A. Ventrice, and R.S. Ruoff Chemical analysis of graphene oxide films after heat and chemical treatments by X-ray photoelectron and Micro-Raman spectroscopy Carbon 47 2009 145 152
44. M.J. Powers, and T.J. Meyer Intervalence Transfer in Mixed-Valence Biferrocene Ions J. Am. Chem. Soc. 100 1978 4393 4398
45. C.M. Woodbridge, D.L. Pugmire, R.C. Johnson, N.M. Boag, and M.A. Langell HREELS and XPS studies of ferrocene on Ag(100) J Phys Chem B 104 2000 3085 3093
46. B. Fabre, and F. Hauquier Single-component and mixed ferrocene-terminated alkyl monolayers covalently bound to Si(111) surfaces J Phys Chem B 110 2006 6848 6855
47. M.R. Guascito, E. Mesto, C. Malitesta, R.A. Picca, and F. Scordari The effect of XPS background removing method on the appraisal of Ti and Fe: The case of phlogopites and brookite Am Mineral 99 2014 139 148
48. T. Yamashita, and P. Hayes Analysis of XPS spectra of Fe2+ and Fe3+ ions in oxide materials Appl Surf Sci 254 2008 2441 2449