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Volumn 2, Issue 5, 2010, Pages 362-368

High-spin ground states via electron delocalization in mixed-valence imidazolate-bridged divanadium complexes

Author keywords

[No Author keywords available]

Indexed keywords

COORDINATION COMPOUND; IMIDAZOLE DERIVATIVE; LIGAND; MAGNESIUM; VANADIUM;

EID: 77951674366     PISSN: 17554330     EISSN: 17554349     Source Type: Journal    
DOI: 10.1038/nchem.585     Document Type: Article
Times cited : (157)

References (50)
  • 1
    • 0027912953 scopus 로고
    • Magnetic bistability in a metal-ion cluster
    • Sessoli, R., Gatteschi, D., Caneschi, A. & Novak, M. A. Magnetic bistability in a metal-ion cluster. Nature 365, 141-143 (1993).
    • (1993) Nature , vol.365 , pp. 141-143
    • Sessoli, R.1    Gatteschi, D.2    Caneschi, A.3    Novak, M.A.4
  • 4
    • 33947264083 scopus 로고    scopus 로고
    • A record anisotropy barrier for a single-molecule magnet
    • Milios, C. J. et al. A record anisotropy barrier for a single-molecule magnet. J. Am. Chem. Soc. 129, 2754-2755 (2007).
    • (2007) J. Am. Chem. Soc. , vol.129 , pp. 2754-2755
    • Milios, C.J.1
  • 6
    • 0035848831 scopus 로고    scopus 로고
    • Quantum computing in molecular systems
    • Leuenberger, M. N. & Loss, D. Quantum computing in molecular systems. Nature 410, 789-793 (2001).
    • (2001) Nature , vol.410 , pp. 789-793
    • Leuenberger, M.N.1    Loss, D.2
  • 10
    • 33748835384 scopus 로고    scopus 로고
    • The rational design of high symmetry coordination clusters
    • Caulder, D. L. & Raymond, K. N. The rational design of high symmetry coordination clusters. J. Chem. Soc. Dalton Trans. 1185-1200 (1999).
    • (1999) J. Chem. Soc. Dalton Trans. , pp. 1185-1200
    • Caulder, D.L.1    Raymond, K.N.2
  • 12
    • 19744365669 scopus 로고    scopus 로고
    • Coordination assemblies from a Pd (II)-cornered square complex
    • Fujita, M., Tominaga, M., Hori, A. & Therrien, B. Coordination assemblies from a Pd (II)-cornered square complex. Acc. Chem. Res. 38, 371-380 (2005).
    • (2005) Acc. Chem. Res. , vol.38 , pp. 371-380
    • Fujita, M.1    Tominaga, M.2    Hori, A.3    Therrien, B.4
  • 13
    • 20344392400 scopus 로고    scopus 로고
    • Directed assembly of metal-cyanide cluster magnets
    • Beltran, L. M. C. & Long, J. R. Directed assembly of metal-cyanide cluster magnets. Acc. Chem. Res. 38, 325-334 (2005).
    • (2005) Acc. Chem. Res. , vol.38 , pp. 325-334
    • Beltran, L.M.C.1    Long, J.R.2
  • 14
    • 33746681317 scopus 로고    scopus 로고
    • A ferromagnetically coupled Mn19 aggregate with a record S = 83/2 ground spin state
    • Ako, A. M. et al. A ferromagnetically coupled Mn19 aggregate with a record S = 83/2 ground spin state. Angew. Chem. Int. Ed. 45, 4926-4929 (2006).
    • (2006) Angew. Chem. Int. Ed. , vol.45 , pp. 4926-4929
    • Ako, A.M.1
  • 15
    • 33845228938 scopus 로고
    • Binuclear complexes of ruthenium ammines
    • Creutz, C. & Taube, H. Binuclear complexes of ruthenium ammines. J. Am. Chem. Soc. 95, 1086-1094 (1973).
    • (1973) J. Am. Chem. Soc. , vol.95 , pp. 1086-1094
    • Creutz, C.1    Taube, H.2
  • 16
    • 0000776899 scopus 로고
    • Intervalence-transfer absorption. Part 2. Theoretical considerations and spectroscopic data
    • Hush, N. S. Intervalence-transfer absorption. Part 2. Theoretical considerations and spectroscopic data. Prog. Inorg. Chem. 8, 391-444 (1967).
    • (1967) Prog. Inorg. Chem. , vol.8 , pp. 391-444
    • Hush, N.S.1
  • 17
    • 37049092191 scopus 로고
    • Charge transfer in mixed-valence solids. Part VIII. Contribution of valence delocalization to the ferromagnetism of Prussian blue
    • Mayoh, B. & Day, P. Charge transfer in mixed-valence solids. Part VIII. Contribution of valence delocalization to the ferromagnetism of Prussian blue. J. Chem. Soc. Dalton Trans. 1483-1486 (1976).
    • (1976) J. Chem. Soc. Dalton Trans. , pp. 1483-1486
    • Mayoh, B.1    Day, P.2
  • 19
    • 0035470233 scopus 로고    scopus 로고
    • The localised-to-delocalised transition in mixed-valence chemistry
    • Demadis, K. D., Hartshorn, C. M. & Meyer, T. J. The localised-to-delocalised transition in mixed-valence chemistry. Chem. Rev. 101, 2655-2685 (2001).
    • (2001) Chem. Rev. , vol.101 , pp. 2655-2685
    • Demadis, K.D.1    Hartshorn, C.M.2    Meyer, T.J.3
  • 20
    • 0036256298 scopus 로고    scopus 로고
    • Optical transitions of symmetrical mixed-valence systems in the class II-III transition regime
    • Brunschwig, B. S., Creutz, C. & Sutin, N. Optical transitions of symmetrical mixed-valence systems in the class II-III transition regime. Chem. Soc. Rev. 31, 168-184 (2002).
    • (2002) Chem. Soc. Rev. , vol.31 , pp. 168-184
    • Brunschwig, B.S.1    Creutz, C.2    Sutin, N.3
  • 21
    • 33745713801 scopus 로고    scopus 로고
    • Current trends and future challenges in the experimental, theoretical and computational analysis of intervalence charge transfer (IVCT) transitions
    • D'Alessandro, D. M. & Keene. F. R. Current trends and future challenges in the experimental, theoretical and computational analysis of intervalence charge transfer (IVCT) transitions. Chem. Soc. Rev. 35, 424-440 (2006).
    • (2006) Chem. Soc. Rev. , vol.35 , pp. 424-440
    • D'Alessandro, D.M.1    Keene, F.R.2
  • 22
    • 77957027443 scopus 로고
    • Mixed-valence chemistry-a survey and classification
    • Robin, M. B. & Day. P. Mixed-valence chemistry-a survey and classification. Adv. Inorg. Chem. Radiochem. 10, 247-403 (1967).
    • (1967) Adv. Inorg. Chem. Radiochem. , vol.10 , pp. 247-403
    • Robin, M.B.1    Day, P.2
  • 23
    • 36149016363 scopus 로고
    • Interaction between the d-shells in the transition metals. II
    • Ferromagnetic compounds of manganese with perovskite structure
    • Zener, C. Interaction between the d-shells in the transition metals. II. Ferromagnetic compounds of manganese with perovskite structure. Phys. Rev. 82, 403-405 (1951).
    • (1951) Phys. Rev. , vol.82 , pp. 403-405
    • Zener, C.1
  • 25
    • 36749113960 scopus 로고
    • Electron transfer between magnetic ions in mixed valence binuclear systems
    • Girerd, J.-J. Electron transfer between magnetic ions in mixed valence binuclear systems. J. Chem. Phys. 79, 1766-1775 (1983).
    • (1983) J. Chem. Phys. , vol.79 , pp. 1766-1775
    • Girerd, J.-J.1
  • 27
    • 0021408283 scopus 로고
    • Electronic structure, magnetic properties, ESR and optical spectra for 2-iron ferredoxin models by LCAO-Xα valence bond theory
    • Noodleman, L. & Baerends, E. J. Electronic structure, magnetic properties, ESR and optical spectra for 2-iron ferredoxin models by LCAO-Xα valence bond theory. J. Am. Chem. Soc. 106, 2316-2327 (1984).
    • (1984) J. Am. Chem. Soc. , vol.106 , pp. 2316-2327
    • Noodleman, L.1    Baerends, E.J.2
  • 28
    • 11944257212 scopus 로고
    • Interplay of electron exchange and electron transfer in metal polynuclear complexes in proteins or chemical models
    • Blondin, G. & Girerd, J.-J. Interplay of electron exchange and electron transfer in metal polynuclear complexes in proteins or chemical models. Chem. Rev. 90, 1359-1376 (1990).
    • (1990) Chem. Rev. , vol.90 , pp. 1359-1376
    • Blondin, G.1    Girerd, J.-J.2
  • 29
    • 0040626535 scopus 로고    scopus 로고
    • Localization vs. delocalization in the dimeric mixed-valence clusters in the generalized vibronic model. Magnetic manifestations
    • Borras-Almenar, J. J., Coronado, E., Ostrovsky, S. M., Palii, A. V. & Tsukerblat, B. S. Localization vs. delocalization in the dimeric mixed-valence clusters in the generalized vibronic model. Magnetic manifestations. Chem. Phys. 240, 149-161 (1999).
    • (1999) Chem. Phys. , vol.240 , pp. 149-161
    • Borras-Almenar, J.J.1    Coronado, E.2    Ostrovsky, S.M.3    Palii, A.V.4    Tsukerblat, B.S.5
  • 31
    • 16944361970 scopus 로고    scopus 로고
    • 2thiophenolato bridging ligands
    • 2thiophenolato bridging ligands. J. Am. Chem. Soc. 118, 12376-12390 (1996).
    • (1996) J. Am. Chem. Soc. , vol.118 , pp. 12376-12390
    • Beissel, T.1
  • 32
    • 0342357728 scopus 로고    scopus 로고
    • Magnetic investigations on a valence-delocalized Fe (II)-Fe (III) complex
    • Saal, C. et al. Magnetic investigations on a valence-delocalized Fe (II)-Fe (III) complex. Ber. Bunsenges. Phys. Chem. 100, 2086-2090 (1996).
    • (1996) Ber. Bunsenges. Phys. Chem. , vol.100 , pp. 2086-2090
    • Saal, C.1
  • 33
    • 0037051637 scopus 로고    scopus 로고
    • Tetracyanide-bridged divanadium complexes: Redox switching between strong antiferromagnetic and strong ferromagnetic coupling
    • Shores, M. P. & Long, J. R. Tetracyanide-bridged divanadium complexes: redox switching between strong antiferromagnetic and strong ferromagnetic coupling. J. Am. Chem. Soc. 124, 3512-3513 (2002).
    • (2002) J. Am. Chem. Soc. , vol.124 , pp. 3512-3513
    • Shores, M.P.1    Long, J.R.2
  • 34
    • 37049067820 scopus 로고
    • 2+ (L=N, N', N"-trimethyl-1, 4, 7-triazacyclononane)
    • 2+ (L=N, N', N"-trimethyl-1, 4, 7-triazacyclononane). Chem. Commun. 1, 59-62 (1989).
    • (1989) Chem. Commun. , vol.1 , pp. 59-62
    • Drůeke, S.1
  • 35
    • 36549104985 scopus 로고
    • Mo̊ssbauer and electron paramagnetic resonance study of the double-exchange and Heisenberg-exchange interactions in a novel binuclear iron (II/III) delocalized-valence compound
    • Ding, X.-Q. et al. Mo̊ssbauer and electron paramagnetic resonance study of the double-exchange and Heisenberg-exchange interactions in a novel binuclear iron (II/III) delocalized-valence compound. J. Chem. Phys. 92, 178-186 (1990).
    • (1990) J. Chem. Phys. , vol.92 , pp. 178-186
    • Ding, X.-Q.1
  • 38
    • 8144227197 scopus 로고    scopus 로고
    • Synthesis of methylene-and methine-bridged oligopyridines
    • Dyker, G. & Muth, O. Synthesis of methylene-and methine-bridged oligopyridines. Eur. J. Org. Chem. 21, 4319-4322 (2004).
    • (2004) Eur. J. Org. Chem. , vol.21 , pp. 4319-4322
    • Dyker, G.1    Muth, O.2
  • 39
    • 0037047838 scopus 로고    scopus 로고
    • A spectrochemical walk: Single-site perturbation within a series of six-coordinate ferrous complexes
    • Goldsmith, C. R., Jonas, R. T., Cole, A. P. & Stack, T. D. P. A spectrochemical walk: single-site perturbation within a series of six-coordinate ferrous complexes. Inorg. Chem. 41, 4642-4652 (2002).
    • (2002) Inorg. Chem. , vol.41 , pp. 4642-4652
    • Goldsmith, C.R.1    Jonas, R.T.2    Cole, A.P.3    Stack, T.D.P.4
  • 40
    • 0037047837 scopus 로고    scopus 로고
    • A periodic walk: A series of first-row transition metal complexes with the Pentadentate Ligand PY5
    • Gebbink, R. J. M. K., Jonas, R. T., Goldsmith, C. R. & Stack, T. D. P. A periodic walk: a series of first-row transition metal complexes with the pentadentate ligand PY5. Inorg. Chem. 41, 4633-4641 (2002).
    • (2002) Inorg. Chem. , vol.41 , pp. 4633-4641
    • Gebbink, R.J.M.K.1    Jonas, R.T.2    Goldsmith, C.R.3    Stack, T.D.P.4
  • 41
    • 37049086110 scopus 로고
    • Interaction of palladium (II) acetate with substituted pyridines, including a cyclometallation reaction and the structure of (acetato-O) {meso-2, 6-bis[1-phenyl-1-(pyridin-2-yl) ethyl]pyridine-N, N', N"}palladium (II) acetate trihydrate
    • Canty, A. J., Minchin, N. J., Skelton, B. W. & White, A. H. Interaction of palladium (II) acetate with substituted pyridines, including a cyclometallation reaction and the structure of (acetato-O) {meso-2, 6-bis[1-phenyl-1-(pyridin-2-yl) ethyl]pyridine-N, N', N"}palladium (II) acetate trihydrate. J. Chem. Soc. Dalton Trans. 2205-2210 (1986).
    • (1986) J. Chem. Soc. Dalton Trans. , pp. 2205-2210
    • Canty, A.J.1    Minchin, N.J.2    Skelton, B.W.3    White, A.H.4
  • 42
    • 0034598481 scopus 로고    scopus 로고
    • Improved electrochemistry in low-polarity media using tetrakis (pentafluorophenyl) borate salts as supporting electrolytes
    • LeSuer, R. & Geiger, W. E. Improved electrochemistry in low-polarity media using tetrakis (pentafluorophenyl) borate salts as supporting electrolytes. Angew. Chem. Int. Ed. 39, 248-250 (2000).
    • (2000) Angew. Chem. Int. Ed. , vol.39 , pp. 248-250
    • LeSuer, R.1    Geiger, W.E.2
  • 43
    • 0035808148 scopus 로고    scopus 로고
    • A versatile variable temperature thin layer reflectance spectroelectrochemical cell
    • Zavarine, I. S. & Kubiak, C. P. A versatile variable temperature thin layer reflectance spectroelectrochemical cell. J. Electroanal. Chem. 495, 106-109 (2001).
    • (2001) J. Electroanal. Chem. , vol.495 , pp. 106-109
    • Zavarine, I.S.1    Kubiak, C.P.2
  • 44
    • 24544439587 scopus 로고
    • Vanadium (II) complexes of substituted imidazoles
    • Ciampolini, M. & Mani, F. Vanadium (II) complexes of substituted imidazoles. Inorg. Chim. Acta 24, 91-95 (1977).
    • (1977) Inorg. Chim. Acta , vol.24 , pp. 91-95
    • Ciampolini, M.1    Mani, F.2
  • 47
    • 11244324760 scopus 로고    scopus 로고
    • Directed assembly of metal-organic cubes from deliberately predesigned molecular building blocks
    • Liu, Y., Kravtsov, V., Walsh, R. D., Poddar, P., Srikanth, H. & Eddaoudi, M. Directed assembly of metal-organic cubes from deliberately predesigned molecular building blocks. Chem. Commun. 2806-2807 (2004).
    • (2004) Chem. Commun. , pp. 2806-2807
    • Liu, Y.1    Kravtsov, V.2    Walsh, R.D.3    Poddar, P.4    Srikanth, H.5    Eddaoudi, M.6
  • 49
    • 33645459483 scopus 로고    scopus 로고
    • Molecular building blocks approach to the assembly of zeolite-like metal-organic frameworks (ZMOFs) with extra-large cavities
    • Liu, Y., Kravtsov, V. C., Larsen, R. & Eddaoudi, M. Molecular building blocks approach to the assembly of zeolite-like metal-organic frameworks (ZMOFs) with extra-large cavities. Chem. Commun. 1488-1490 (2006).
    • (2006) Chem. Commun. , pp. 1488-1490
    • Liu, Y.1    Kravtsov, V.C.2    Larsen, R.3    Eddaoudi, M.4
  • 50
    • 33745900775 scopus 로고    scopus 로고
    • Exceptional chemical and thermal stability of zeolitic imidazolate frameworks
    • Park, K. S. et al. Exceptional chemical and thermal stability of zeolitic imidazolate frameworks. Proc. Natl Acad. Sci. USA 103, 10186-10191 (2006).
    • (2006) Proc. Natl. Acad. Sci. USA , vol.103 , pp. 10186-10191
    • Park, K.S.1


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