Carbene-dichlorosilylene stabilized phosphinidenes exhibiting strong intramolecular charge transfer transition

Journal of the American Chemical Society

Volumn 137, Issue 1, 2015, Pages 150-153

  Roy, Sudipta ^a   Stollberg, Peter ^a   Herbst Irmer, Regine ^a   Stalke, Dietmar ^a   Andrada, Diego M ^b   Frenking, Gernot ^b   Roesky, Herbert W ^a  

^a UNIVERSITY OF GÖTTINGEN   (Germany)

^b PHILIPPS UNIVERSITY MARBURG   (Germany)

Author keywords

[No Author keywords available]

Indexed keywords

CARBONYLATION; CHARGE TRANSFER; ELECTRONIC STRUCTURE; SILICON;

COORDINATE BONDS; GENERAL FORMULAS; INERT ATMOSPHERES; INTRAMOLECULAR CHARGE TRANSFER TRANSITION; INTRAMOLECULAR CHARGE TRANSFERS; N-HETEROCYCLIC CARBENES; ROOM TEMPERATURE; THEORETICAL CALCULATIONS;

ORGANIC COMPOUNDS;

ALKYL GROUP; CARBENE; CARBENOID; DICHLOROSILYLENE; PHOSPHINE DERIVATIVE; UNCLASSIFIED DRUG;

ARTICLE; ATMOSPHERE; CALCULATION; COLOR; CRYSTAL; DENSITY FUNCTIONAL THEORY; ENERGY; INTRAMOLECULAR CHARGE TRANSFER TRANSITION; MOLECULAR BIOLOGY; ROOM TEMPERATURE;

EID: 84921059039     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/ja512089e     Document Type: Article

References (62)

1. Schmeisser, M.; Voss, P. Z. Anorg. Allg. Chem. 1964, 334, 50
2. Schenk, P. W.; Bloching, H. Z. Anorg. Allg. Chem. 1964, 334, 57
3. See SI for more refs.
4. Koe, J. R.; Powell, D. R.; Buffy, J. J.; Hayase, S.; West, R. Angew. Chem., Int. Ed. 1998, 37, 1441
5. Angew. Chem. 1998, 110, 1514.
6. Ghadwal, R. S.; Azhakar, R.; Roesky, H. W. Acc. Chem. Res. 2013, 46, 444
7. Ghadwal, R. S.; Roesky, H. W.; Merkel, S.; Henn, J.; Stalke, D. Angew. Chem., Int. Ed. 2009, 48, 5683
8. Angew. Chem. 2009, 121, 5793. and references herein
9. Mondal, K. C.; Dittrich, B.; Maity, B.; Koley, D.; Roesky, H. W. J. Am. Chem. Soc. 2014, 136, 9568
10. Martin, D.; Soleilhavoup, M.; Bertrand, G. Chem. Sci. 2011, 2, 389
11. Back, M.; Henry-Ellinger, M.; Martin, C. D.; Martin, D.; Bertrand, G. Angew. Chem., Int. Ed. 2013, 52, 2939
12. Angew. Chem. 2013, 125, 3011.
13. Martin, D.; Canac, Y.; Lavallo, V.; Bertrand, G. J. Am. Chem. Soc. 2014, 136, 5023
14. Martin, C. D.; Soleilhavoup, M.; Bertrand, G. Chem. Sci. 2013, 4, 3020
15. Lavallo, V.; Canac, Y.; Donnadieu, B.; Schoeller, W. W.; Bertrand, G. Angew. Chem., Int. Ed. 2006, 45, 3488
16. Angew. Chem. 2006, 118, 3568.
17. Mondal, K. C.; Roesky, H. W.; Schwarzer, M. C.; Frenking, G.; Niepötter, B.; Wolf, H.; Herbst-Irmer, R.; Stalke, D. Angew. Chem., Int. Ed. 2013, 52, 2963
18. Angew. Chem. 2013, 125, 3036.
19. Tonner, R.; Öxler, F.; Neumüller, B.; Petz, W.; Frenking, G. Angew. Chem., Int. Ed. 2006, 45, 8038
20. Angew. Chem. 2006, 118, 8206.
21. Dyker, C. A.; Lavallo, V.; Donnadieu, B.; Bertrand, G. Angew. Chem. 2008, 120, 3250
22. Angew. Chem., Int. Ed. 2008, 47, 3206.
23. Fürstner, A.; Alcarazo, M.; Goddard, R.; Lehmann, C. W. Angew. Chem., Int. Ed. 2008, 47, 3210
24. Angew. Chem. 2008, 120, 3254.
25. Schmidbaur, H. Angew. Chem., Int. Ed. Engl. 1983, 22, 907
26. Angew. Chem. 1983, 95, 980.
27. Morosaki, T.; Suzuki, T.; Wang, W.-W.; Nagase, S.; Fujii, T. Angew. Chem., Int. Ed. 2014, 53, 9569
28. Angew. Chem. 2014, 126, 9723.
29. Xiong, Y.; Yao, S.; Inoue, S.; Epping, J. D.; Driess, M. Angew. Chem. 2013, 125, 7287
30. Angew. Chem., Int. Ed. 2013, 52, 7147.
31. Xiong, Y.; Yao, S.; Tan, G.; Inoue, S.; Driess, M. J. Am. Chem. Soc. 2013, 135, 5004
32. See SI.
33. Driess, M.; Block, S.; Brym, M.; Gamer, M. T. Angew. Chem., Int. Ed. 2006, 45, 2293
34. Angew. Chem. 2006, 118, 2351.
35. Hansen, K.; Szilvasi, T.; Blom, B.; Inoue, S.; Epping, J.; Driess, M. J. Am. Chem. Soc. 2013, 135, 11795
36. Hansen, K.; Szilvasi, T.; Blom, B.; Irran, E.; Driess, M. Chem.-Eur. J. 2014, 20, 1947
37. Smit, C. N.; Lock, F. M.; Bickelhaupt, F. Tetrahedron Lett. 1984, 25, 3011
38. Niecke, E.; Klein, E.; Nieger, M. Angew. Chem., Int. Ed. 1989, 28, 751
39. Angew. Chem. 1989, 101, 792.
40. Bender, H. R. G.; Niecke, E.; Nieger, M. J. Am. Chem. Soc. 1993, 115, 3314
41. Lange, D.; Klein, E.; Bender, H.; Niecke, E.; Nieger, M.; Pietschnig, R.; Schoeller, W. W.; Ranaivonjatovo, H. Organometallics 1998, 17, 2425
42. Driess, M. Angew. Chem., Int. Ed. 1991, 30, 1022
43. Angew. Chem. 1991, 103, 979.
44. Driess, M.; Rell, S.; Pritzkow, H. J. Chem. Soc., Chem. Commun. 1995, 253
45. Driess, M.; Pritzkow, H.; Rell, S.; Winkler, U. Organometallics 1996, 15, 1845
46. Driess, M.; Block, S.; Brym, M.; Gamer, M. T. Angew. Chem. 2006, 118, 2351
47. Angew. Chem., Int. Ed. 2006, 45, 2293.
48. Hansen, K.; Szilvasi, T.; Blom, B.; Inoue, S.; Epping, J.; Driess, M. J. Am. Chem. Soc. 2013, 135, 11795
49. Hansen, K.; Szilvasi, T.; Blom, B.; Irran, E.; Driess, M. Chem.-Eur. J. 2014, 20, 1947
50. Corriu, R.; Lanneau, G.; Priou, C. Angew. Chem., Int. Ed. 1991, 30, 1130
51. Angew. Chem. 1991, 103, 1153.
52. Lee, V. Y.; Kawei, M.; Sekiguchi, A.; Ranaivonjatovo, H.; Escudie, J. Organometallics 2009, 28, 4262
53. Gau, D.; Kato, T.; Saffon-Merceron, N.; Cossio, F. P.; Baceiredo, A. J. Am. Chem. Soc. 2009, 131, 8762
54. Cui, H.; Zhang, J.; Cui, C. Organometallics 2013, 32, 1
55. Willmes, P.; Cowley, M. J.; Hartmann, M.; Zimmer, M.; Huch, V.; Scheschkewitz, D. Angew. Chem., Int. Ed. 2014, 53, 2216
56. Angew. Chem. 2014, 126, 2248.
57. Breit, N. C.; Szilvasi, T.; Inoue, S. Chem.-Eur. J. 2014, 20, 9312
58. Khan, S.; Michel, R.; Sen, S. S.; Roesky, H. W.; Stalke, D. Angew. Chem. 2011, 123, 11990
59. Angew. Chem., Int. Ed. 2011, 50, 11786.
60. Pietschnig, R.; Orthaber, A. Eur. J. Inorg. Chem. 2006, 4570
61. Iwamoto, T.; Kobayashi, M.; Uchiyama, K.; Sasaki, S.; Nagendran, S.; Isobe, H.; Kira, M. J. Am. Chem. Soc. 2009, 131, 3156
62. Iwamoto, T.; Ohnishi, N.; Akasaka, N.; Ohno, K.; Ishida, S. J. Am. Chem. Soc. 2013, 135, 10606