Synthesis and unusual reactivity of compounds containing silicon-phosphorus and silicon-arsenic double bonds: New silylidenephosphanes and -arsanes of the type R2Si=E(SiR3) (E = P, As)

Organometallics

Volumn 15, Issue 7, 1996, Pages 1845-1855

  Driess, Matthias ^a   Pritzkow, Hans ^a   Rell, Stefan ^a   Winkler, Uwe ^a  

^a UNIVERSITY OF HEIDELBERG   (Germany)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0001143607     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om9508851     Document Type: Article

References (49)

1. (a) West, R. Angew. Chem. Int. Ed. Engl. 1987, 26, 1201.
2. (b) West, R. Pure Appl. Chem. 1984, 56, 163.
3. (c) Masamune, S.; Batcheller, S. A.; Tsumuraya T. Angew. Chem., Int. Ed. Engl. 1991, 30, 902.
4. (a) Brook, A. G.; Baines, K. M. Adv. Organomet. Chem. 1986, 25, 1.
5. (b) Raabe, G.; Michl, J. Multiple Bonds to Silicon. In The Chemistry of Organic Silicon Compounds; Patai, S., Rappoport, Z., Eds.; Wiley: New York, 1989; Part 2, p 1044.
6. (a) Wiberg, N.; Schurz, K.; Fischer, G. Angew. Chem., Int. Ed. Engl. 1985, 24, 1053.
7. (b) Hesse, M.; Klingebiel, U. Angew. Chem., Int. Ed. Engl. 1986, 25, 649.
8. (c) Wiberg, N.; Schurz, K.; Müller, G.; Riede, J. Angew. Chem., Int. Ed. Engl. 1988, 27, 935.
9. (a) Smit, C. N.; Lock, F. M.; Bickelhaupt, F. Tetrahedron Lett. 1984, 25, 3011.
10. (b) Smit, C. N.; Bickelhaupt, F. Organometallics 1987, 6, 1156.
11. (c) van den Winkel, Y.; Bastiaans, H. M. M.; Bickelhaupt, F. J. Organomet. Chem. 1991, 405, 183.
12. Driess, M. Angew. Chem., Int. Ed. Engl. 1991, 30, 1022.
13. Driess, M.; Winkler, U.; Imhof, W.; Zsolnai, L.; Huttner, G. Chem. Ber. 1994, 127, 1031.
14. Niecke, E.; Klein, E.; Nieger, M. Angew. Chem., Int. Ed. Engl. 1989, 28, 751.
15. Niecke, E.; Bender, H. R. G.; Nieger, M. J. Am. Chem. Soc. 1993, 115, 3314.
16. Bender, H. R. G. Dissertation, University of Bonn, 1993.
17. (a) Dykema, J. K.; Troung, P. N.; Gordon, M. S. J. Am. Chem. Soc. 1985, 107, 4535.
18. (b) Schleyer, P. v. R.; Kost, D. J. Am. Chem. Soc. 1988, 110, 2105.
19. Albright, T. A.; Burdett, J.; Whangbo, M.-H. in Orbital Interactions in Chemistry; Wiley: New York, 1985; p 95.
20. Driess, M.; Rell, S.; Pritzkow, H. J. Chem. Soc., Chem. Commun. 1995, 253.
21. Driess, M.; Janoschek, R. J. Mol. Struct. (Theochem.) 1994, 313, 129
22. Driess, M.; Pritzkow, H. Angew. Chem., Int. Ed. Engl. 1992, 31, 316.
23. Wiberg, N.; Schuster, H. Chem. Ber. 1991, 124, 93.
24. (a) Driess, M.; Pritzkow, H. Angew. Chem., Int. Ed. Engl. 1992, 31, 751.
25. (b) Driess, M.; Pritzkow, H. Phosphorus, Sulfur, Silicon Rel. Elem. 1993, 76, 57.
26. Driess, M.; Pritzkow, H. J. Chem. Soc., Chem. Commun. 1993, 1585.
27. 31P-NMR Data in Multiple Bonds and Low Coordination in Phosphorus Chemistry; Regitz, M., Scherer, O. J., Eds.; Thieme: Stuttgart, Germany, 1990; p 463.
28. Gudat, D.; Niecke, E.; Sachs, W.; Rademacher, P. Z. Anorg. Allg. Chem. 1987, 545, 7.
29. (a) Driess, M.; Fanta, A. D.; Powell, D. R.; West, R. Angew. Chem., Int. Ed. Engl. 1989, 28, 1038.
30. (b) Driess, M.; Pritzkow, H.; Reisgys, M. Chem. Ber. 1991, 124, 1923.
31. (c) Fanta, A. D.; Tan, R. P.; Comerlato, N. M.; Driess, M.; Powell, D. R.; West, R. Inorg. Chim. Acta 1992, 198-200, 733.
32. Tan, R. P.; Comerlato, N. M.; Powell, D. R.; West, R. Angew. Chem., Int. Ed. Engl. 1992, 31, 1217.
33. Driess, M.; Janoschek, R.; Pritzkow, H. Angew. Chem., Int. Ed. Engl. 1992, 31, 460.
34. Young, D. J. D.; West, R. Chem. Lett. 1986, 6, 883.
35. (a) Weidenbruch, M.; Hamann, J.; Diel, H.; Lentz, D.; von Schnering, H. G.; Peters, K. J. Organomet. Chem. 1992, 426, 35.
36. (b) Weidenbruch, M. Novel Ring Systems from Cyclotrisilanes and Cyclotristannanes. In The Chemistry of Inorganic Ring Systems; Steudel, R., Ed.; Studies in Inorganic Chemistry, Vol. 14; Elsevier: Amsterdam, 1992; p 51.
37. Becker, G.; Massa, W.; Schmidt, R. E.; Uhl, G. Z. Anorg. Allg. Chem. 1984, 517, 75.
38. McKillop, K. L.; Gillette, G. R.; Powell, D. R.; West, R. J. Am. Chem. Soc. 1992, 114, 5203. See also ref 1.
39. Gillette, G. R.; West, R. J. Organomet. Chem. 1990, 394, 45.
40. Driess, M.; Pritzkow, H.; Sander, M. Angew. Chem., Int. Ed. Engl. 1992, 32, 283.
41. (a) Brook, A. D.; Kun Kong, Y.; Saxena, A. K.; Sawyer, J. F. Organometallics 1988, 7, 2245.
42. (b) Brook, A. G.; Saxena, A. K.; Sawyer, J. F. Organometallics 1989, 8, 850.
43. Yokelson, H. B.; Millevolte, A. J.; Haller, K. J.; West, R. J. Chem. Soc., Chem. Commun. 1987, 1605.
44. Fluck, E.; Heckmann, G. Chemical Shift Interpretations in Phosphorus-31P NMR Spectroscopy. In Stereochemical Analysis; Verkade, J. G., Quin, L. D., Eds.; Verlag Chemie: Weinheim, Germany, 1987; p 76.
45. Nakadaira, Y.; Oharu, K.; Sakurai, H. J. Organomet. Chem. 1986, 309, 247.
46. (a) Schäfer, H.; Fritz, G.; Hölderich, W. Z. Anorg. Allg. Chem. 1977, 428, 222.
47. (b) Becker, G.; Becker, W.; Schmidt, M.; Schwarz, W.; Westerhausen, M. Z. Anorg. Allg. Chem. 1991, 605, 7.
48. Watanabe, H.; Takeuchi, K.; Nakajima, K.; Nagai, Y.; Goto, M. Chem. Lett. 1988, 1343.
49. Sheldrick, G. M. SHELXS 86, SHELXL-93, Universität Göttingen.