Perchloropolysilane: X-ray structure, solid-state 29Si NMR spectroscopy, and reactions of [SiCl2](n)

Angewandte Chemie - International Edition

Volumn 37, Issue 10, 1998, Pages 1441-1442

  Koe, Julian R ^a   Powell, Douglas R ^a   Buffy, Jarrod J ^a   Hayase, Shuzi ^b   West, Robert ^a  

^a UNIVERSITY OF WISCONSIN MADISON   (United States)

^b NONE

Author keywords

Chlorine; Perchloropolysilane; Polymers; Polysilane; Silicon

Indexed keywords

EID: 0032486442     PISSN: 14337851     EISSN: None     Source Type: Journal    
DOI: 10.1002/(SICI)1521-3773(19980605)37:10<1441::AID-ANIE1441>3.0.CO;2-4     Document Type: Article

References (13)

1. 29Si NMR (59.591 MHz): δ = -3.9; peak width at half height = 350 Hz.
2. a) R. Schwarz, H. Meckbach, Z. Anorg. Allg. Chem. 1937,232,241;
3. b) R. Schwarz, A. Koster, ibid. 1952, 270, 2;
4. c) E. Hengge, D. Kovar, ibid. 1979, 458, 163.
5. K. Hassler, E. Hengge, D. Kovar, J. Mol. Struct. 1980, 66, 25; E. Hengge, H. G. Schuster, W. Peter, J. Organomet. Chem. 1980, 186, C45; H. Stuger, E. Hengge, Monatsh. Chem. 1988, 119, 873; H. Stuger, R. Janoschek, Phosphorus Sulfur Silicon 1992, 68, 129.
6. K. Hassler, E. Hengge, D. Kovar, J. Mol. Struct. 1980, 66, 25; E. Hengge, H. G. Schuster, W. Peter, J. Organomet. Chem. 1980, 186, C45; H. Stuger, E. Hengge, Monatsh. Chem. 1988, 119, 873; H. Stuger, R. Janoschek, Phosphorus Sulfur Silicon 1992, 68, 129.
7. K. Hassler, E. Hengge, D. Kovar, J. Mol. Struct. 1980, 66, 25; E. Hengge, H. G. Schuster, W. Peter, J. Organomet. Chem. 1980, 186, C45; H. Stuger, E. Hengge, Monatsh. Chem. 1988, 119, 873; H. Stuger, R. Janoschek, Phosphorus Sulfur Silicon 1992, 68, 129.
8. K. Hassler, E. Hengge, D. Kovar, J. Mol. Struct. 1980, 66, 25; E. Hengge, H. G. Schuster, W. Peter, J. Organomet. Chem. 1980, 186, C45; H. Stuger, E. Hengge, Monatsh. Chem. 1988, 119, 873; H. Stuger, R. Janoschek, Phosphorus Sulfur Silicon 1992, 68, 129.
9. K. Utvary, E. Hengge, Monatsh. Chem. 1979, 110, 1295.
10. J. R. Koe, D. R. Powell, J. J. Buffy, R. West, Polyhedron 1998, in press.
11. 2) = 1.303, Flack = 0 (2). Further details on the crystal structure investigation may be obtained from the Fachinformationszentrum Karlsruhe. D-76344 Eggenstein-Leopoldshafen, Germany (fax: (+49) 7247-808-666 (Frau S. Höhler-Schlimm); e-mail: crysdata@fiz-karlsruhe.de), on quoting the depository number CSD-59 448.
12. 29Si NMR (99.36 MHz): δ = -11.2. All the peaks in the NMR spectra were broad.
13. International Tables for Crystallography, Vol. C, Kluwer, Boston, 1995, Tables 6.1.1.4, 4.2.6.8, and 4.2.4.2.