The gelation of oil using ethyl cellulose

Carbohydrate Polymers

Volumn 117, Issue , 2015, Pages 869-878

  Davidovich Pinhas, M ^a   Barbut, S ^a   Marangoni, A G ^a  

^a UNIVERSITY OF GUELPH   (Canada)

Author keywords

Ethyl cellulose; Gel point; Oleogel; Rheology; Thermo reversible gelation

Indexed keywords

CELLULOSE; ELASTICITY; GELATION; MOLECULAR WEIGHT; OIL SHALE; RHEOLOGY; THERMOANALYSIS;

CONFORMATIONAL CHANGE; ETHYL CELLULOSE; GEL POINT; LOW MOLECULAR WEIGHT; OLEOGEL; POLYMER MOLECULAR WEIGHT; RHEOLOGICAL ANALYSIS; THERMAL TRANSITIONS;

COOLING;

CANOLA OIL; CELLULOSE; ETHYL CELLULOSE; GEL; MONOUNSATURATED FATTY ACID; OLEOGELS; ORGANIC COMPOUND;

ANALOGS AND DERIVATIVES; CHEMISTRY; FLOW KINETICS; GEL; KINETICS; MECHANICS; MOLECULAR WEIGHT; TRANSITION TEMPERATURE;

CELLULOSE; FATTY ACIDS, MONOUNSATURATED; GELS; KINETICS; MECHANICAL PROCESSES; MOLECULAR WEIGHT; ORGANIC CHEMICALS; RHEOLOGY; TRANSITION TEMPERATURE;

EID: 84916613656     PISSN: 01448617     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.carbpol.2014.10.035     Document Type: Article

References (46)

1. Aiache, J. M., Gauthier, P., & Aiache, S. (1992). New gelification method for vegetable oils I: Cosmetic application. International Journal of Cosmetic Science, 14, 228-234.
2. Aymard, P., Martin, D. R., Plucknett, K., Foster, T. J., Clark, A. H., & Norton, I. T. (2001). Influence of thermal history on the structural and mechanical properties of agarose gels. Biopolymers, 59, 131-144.
3. Braudo, E. E., Muratalieva, I. R., Piashchina, I. G., & Tolstoguzov, V. B. (1991). Correlation between the temperatures of formation/breakdown of the gel network and conformational transitions of agarose macromolecules. Carbohydrate Polymers, 15, 317-321.
4. Cattaruzza, A., Radford, S., & Marangoni, A. G. (2012). Dough products comprising ethylcellulose and exhibiting reduced oil migration. WO/2012/066277.
5. Davidovich-Pinhas, M., Co, E., Barbut, S., & Marangoni, A. G. (2014). Physical structure and thermal behavior of ethylcellulose. Cellulose, 21, 3243-3255.
6. Doesburg, J. J., & Grevers, G. (1959). Setting time and setting temperature of pectin jellies. Journal of Food Science, 25, 634-645.
7. Eleya, M. M. O., & Turgeon, S. L. (2000). Rheology of k-carrageenan and blactoglobulin mixed gels. Food Hydrocolloids, 14, 29-40.
8. Funami, T., Funami, M., Yada, H., & Nakao, Y. (2000). A rheological study on the effects of heating rate and dispersing method on the gelling characteristics of curdlan aqueous dispersions. Food Hydrocolloids, 14, 509-518.
9. Funamia, T., Funamib, M., Yadab, H., & Nakaob, Y. (1999). Rheological and thermal studies on gelling characteristics of curdlan. Food Hydrocolloids, 13, 317-324.
10. Gravelle, A. J., Barbut, S., & Marangoni, A. G. (2012). Ethylcellulose oleogels: Manufacturing considerations and effects of oil oxidation. Food Research International, 48, 578-583.
11. Gravelle, A. J., Barbut, S., & Marangoni, A. G. (2013). Fractionation of ethylcellulose oleogels during setting. Food Function, 4, 153-161.
12. Gravelle, A. J., Barbut, S., Quinton, M., & Marangoni, A. G. (2014). Towards the development of a predictive model of the formulation-dependent mechanical behaviour of ethylcellulose oleogels. Journal of Food Engineering, 143, 114-122.
13. Harris, P. (1990). Food gels. Essex: Elsevier Applied Science.
14. Hinton, C. L. (1950). The setting temperature of pectin jellies. Journal of the Science of Food and Agriculture, 1, 300-307.
15. Kasapis, S., Al-Marhoobi, I. M., & Mitchell, J. R. (2003). Molecular weight effects on the glass transition of gelatin/cosolute mixtures. Biopolym, 70, 169-185.
16. Kavanagh, G. M., & Ross-Murphy, S. B. (1998). Rheological characterization of polymer gels. Progress in Polymer Science, 23(3), 533-562.
17. Kjøniksen, A.-L., Nystrom, B., & Lindman, B. (1998). Dynamic viscoelasticity of gelling and nongelling aqueous mixtures of ethyl(hydroxyethyl)cellulose and an ionic surfactant. Macromolecules, 31, 1852-1858.
18. Koch, W. (1937). Properties and uses of ethylcellulose. Industrial & Engineering Chemistry, 29, 687-690.
19. Laredo, T., Barbut, S., & Marangoni, A. G. (2011). Molecular interactions of polymer oleogelation. Soft Matter, 7, 2734-2743.
20. Lefebvre, J., & Doublier, J.-L. (1998). Rheological behavior of polysaccharides aqueous systems. In S. Dumitriu (Ed.), Polysaccharides: Structural diversity and functional versatility (pp. 357-409). New York, NY: Marcel Dekker.
21. Li, L. (2002). Thermal gelation of methylcellulose in water: Scaling and thermoreversibility. Macromolecules, 35, 5990-5998.
22. Li, L., Thangamathesvaran, P. M., Yue, C. Y., Tam, K. C., Hu, X., & Lam, Y. C. (2001). Gel network structure of methylcellulose in water. Langmuir, 17, 8062-8068.
23. Mangionea, M. R., Giacomazza, D., Bulone, D., Martorana, V., & Biagio, P. L. S. (2003). Thermoreversible gelation of k-carrageenan: Relation between conformational transition and aggregation. Biophysical Chemistry, 104, 95-105.
24. Marangoni, A. G. (2010a). Chocolate compositions containing ethylcellulose. WO/2012/066277.
25. Marangoni, A. G. (2010b). Polymer gelation of oils. WO/2010/143066.
26. Marangoni, A. G. (2012). Thixotropic compositions. WO/2012/071651.
27. Marangoni, A. G., & Garti, N. (2011). An overview of the past, present, and future of organogels. In A. G. Marangoni, & N. Garti (Eds.), Edible oleogels: Structure and health implications (pp. 1-18). Urbana, IL: AOCS Press.
28. Michon, C., Cuvelier, G., & Launay, B. (1993). Concentration dependence of the critical viscoelastic properties of gelatin at the gel point. Rheologica Acta, 32, 94-103.
29. Miyazaki, S., Suisha, F., Kawasaki, N., Shirakawa, M., Yamatoya, K., & Attwood, D. (1998). Thermally reversible xyloglucan gels as vehicles for rectal drug delivery. Journal of Controlled Release, 56, 75-83.
30. Miyoshi, E., Takaya, T., & Nishinari, K. (1996). Rheological and thermal studies of gelsol transition in gellan gum aqueous solutions. Carbohydrate Polymers, 30, 109-119.
31. Nishinari, K. (1997). Rheological and DSC study of sol-gel transition in aqueous dispersions of industrially important polymers and colloids. Colloid and Polymer Science, 275, 1093-1107.
32. Nordby, M. H., Kjøniksen, A.-L., Nystrom, B., & Roots, J. (2003). Thermoreversible gelation of aqueous mixtures of pectin and chitosan. Rheology. Biomacromolecules, 4, 337-343.
33. Normand, V. R., Lootens, D. L., Amici, E., Plucknett, K. P., & Aymard, P. (2000). New insight into agarose gel mechanical properties. Biomacromolecules, 1, 730-738.
34. Nystrom, B., Walderhaug, H., Hansen, F. K., & Lindman, B. (1995). Rheological behavior during thermoreversible gelation of aqueous mixtures of ethyl(hydroxyethy1)cellulose and surfactants. Langmuir, 11, 750-757.
35. Payró, E. R., & Llacuna, J. L. (2006). Rheological characterization of the gel point in sol-gel transition. Journal of Non-Crystalline Solids, 352, 2220-2225.
36. Pernetti, M., Malssen, K. F. V., Flöter, E., & Bot, A. (2007). Structuring of edible oils by alternatives to crystalline fat. Current Opinion in Colloid & Interface Science, 12, 221-231.
37. Rocha, J. C. B., Lopes, J. D., Mascarenhas, M. C. N., Arellano, D. B., Guerreiro, L. M. R., & Cunha, R. L. D. (2013). Thermal and rheological properties of organogels formed by sugarcane or candelilla wax in soybean oil. Food Research International, 50, 318-323.
38. Rochas, C., Rmaudo, M., & Landry, S. (1990). Role of the molecular weight on the mechanical properties of kappa carrageenan gels. Carbohydrate Polymers, 12, 255-266.
39. Rubinstein, M., & Colby, R. H. (2003). Polymer physics. New York: Oxford University Press Inc.
40. Sarkar, N. (1979). Thermal gelation properties of methyl and hydroxypropyl methylcellulose. Journal of Applied Polymer Science, 24, 1073-1087.
41. Sekiguchi, Y., Sawatari, C., & Kondo, T. (2003). A gelation mechanism depending on hydrogen bond formation in regioselectively substituted O-methylcelluloses. Carbohydrate Polymers, 53, 145-153.
42. Tung, C.-Y. M., & Dynes, P. J. (1982). Relationship between viscoelastic properties and gelation in thermosetting systems. Journal of Applied Polymer Science, 27, 569-574.
43. Visintin, R. F. G., Lapasin, R., Vignati, E., D'Antona, P., & Lockhart, T. P. (2005). Rheological behavior and structural interpretation of waxy crude oil gels. Langmuir, 21, 6240-6249.
44. Winter, H. H., & Chambon, F. (1986). Analysis of linear viscoelasticity of a crosslinking polymer at the gel point. Journal of Rheology, 30, 367-382.
45. Zetzl, A. K., Marangoni, A. G., & Barbut, S. (2012). Mechanical properties of ethylcellulose oleogels and their potential for saturated fat reduction in frankfurters. Food Function, 3, 327-337.
46. Zhang, H., Nishinari, K., Williams, M. A. K., Foster, T. J., & Norton, I. T. (2002). A molecular description of the gelation mechanism of curdlan. International Journal of Biological Macromolecules, 30, 7-16.