-
1
-
-
33845279754
-
-
a) A. Igau, H. Grutzmacher, A. Baceiredo, G. Bertrand, J. Am. Chem. Soc. 1988, 110, 6463 - 6466;
-
(1988)
J. Am. Chem. Soc.
, vol.110
, pp. 6463-6466
-
-
Igau, A.1
Grutzmacher, H.2
Baceiredo, A.3
Bertrand, G.4
-
2
-
-
0001286592
-
-
b) A. J. Arduengo III, R. L. Harlow, M. Kline, J. Am. Chem. Soc. 1991, 113, 361-363.
-
(1991)
J. Am. Chem. Soc.
, vol.113
, pp. 361-363
-
-
Arduengo, A.J.1
Harlow, R.L.2
Kline, M.3
-
3
-
-
84903539227
-
-
For recent reviews, see: a) M. N. Hopkinson, C. Richter, M. Schedler, F. Glorius, Nature 2014, 510, 485 - 496;
-
(2014)
Nature
, vol.510
, pp. 485-496
-
-
Hopkinson, M.N.1
Richter, C.2
Schedler, M.3
Glorius, F.4
-
6
-
-
78249280908
-
-
Angew. Chem. 2010, 122, 7094 - 7107;
-
(2010)
Angew. Chem.
, vol.122
, pp. 7094-7107
-
-
-
9
-
-
49649084986
-
-
Angew. Chem. 2008, 120, 3166-3216.
-
(2008)
Angew. Chem.
, vol.120
, pp. 3166-3216
-
-
-
10
-
-
80054746218
-
-
a) D. Martin, M. Melaimi, M. Soleilhavoup, G. Bertrand, Organometallics 2011, 30, 5304 - 5313;
-
(2011)
Organometallics
, vol.30
, pp. 5304-5313
-
-
Martin, D.1
Melaimi, M.2
Soleilhavoup, M.3
Bertrand, G.4
-
11
-
-
78449247161
-
-
b) M. Melaimi, M. Soleihavoup, G. Bertrand, Angew. Chem. Int. Ed. 2010, 49, 8810 - 8849;
-
(2010)
Angew. Chem. Int. Ed.
, vol.49
, pp. 8810-8849
-
-
Melaimi, M.1
Soleihavoup, M.2
Bertrand, G.3
-
12
-
-
79952439487
-
-
Angew. Chem. 2010, 122, 8992-9032.
-
(2010)
Angew. Chem.
, vol.122
, pp. 8992-9032
-
-
-
13
-
-
70350496543
-
-
E. Aldeco-Perez, A. J. Rosenthal, B. Donnadieu, P. Parameswaran, G. Frenking, G. Bertrand, Science 2009, 326, 556-559.
-
(2009)
Science
, vol.326
, pp. 556-559
-
-
Aldeco-Perez, E.1
Rosenthal, A.J.2
Donnadieu, B.3
Parameswaran, P.4
Frenking, G.5
Bertrand, G.6
-
15
-
-
79951643203
-
-
For recent reviews, see: a) M. Asay, C. Jones, M. Driess, Chem. Rev. 2011, 111, 354 - 396;
-
(2011)
Chem. Rev.
, vol.111
, pp. 354-396
-
-
Asay, M.1
Jones, C.2
Driess, M.3
-
16
-
-
84908704339
-
-
b) Y. Mizuhata, T. Sasamori, N. Tokitoh, Chem. Rev. 2009, 109, 3479 - 3511;
-
(2009)
Chem. Rev.
, vol.109
, pp. 3479-3511
-
-
Mizuhata, Y.1
Sasamori, T.2
Tokitoh, N.3
-
17
-
-
84889765211
-
-
Wiley, Chichester
-
c) M. F. Lappert, P. P. Power, A. Protchenko, A. Seeber, Metal Amide Chemistry, Wiley, Chichester, 2009;
-
(2009)
Metal Amide Chemistry
-
-
Lappert, M.F.1
Power, P.P.2
Protchenko, A.3
Seeber, A.4
-
19
-
-
84989870693
-
-
For NHC-stabilized diatomic group 14 element allotropes, see: a) C. Jones, A. Sidiropoulos, N. Holzmann, G. Frenking, A. Stasch, Chem. Commun. 2012, 48, 9855 - 9857;
-
(2012)
Chem. Commun.
, vol.48
, pp. 9855-9857
-
-
Jones, C.1
Sidiropoulos, A.2
Holzmann, N.3
Frenking, G.4
Stasch, A.5
-
20
-
-
71949091870
-
-
b) A. Sidiropoulos, C. Jones, A. Stasch, S. Klein, G. Frenking, Angew. Chem. Int. Ed. 2009, 48, 9701 - 9704;
-
(2009)
Angew. Chem. Int. Ed.
, vol.48
, pp. 9701-9704
-
-
Sidiropoulos, A.1
Jones, C.2
Stasch, A.3
Klein, S.4
Frenking, G.5
-
21
-
-
77952376873
-
-
Angew. Chem. 2009, 121, 9881 - 9884;
-
(2009)
Angew. Chem.
, vol.121
, pp. 9881-9884
-
-
-
22
-
-
50149085174
-
-
c) Y. Wang, Y. Xie, P. Wei, R. B. King, H. F. Schufer III, P. V. R. Schleyer, G. H. Robinson, Science 2008, 321, 1069 - 1071;
-
(2008)
Science
, vol.321
, pp. 1069-1071
-
-
Wang, Y.1
Xie, Y.2
Wei, P.3
King, R.B.4
Schufer, H.F.5
Schleyer, P.V.R.6
Robinson, G.H.7
-
24
-
-
0032837811
-
-
N.Wiberg, H.-W. Lerner, S.-K. Vasisht, S.Wagner, K. Karaghiosoff, H. Nöth, W. Ponikwar, Eur. J. Inorg. Chem. 1999, 1211-1218.
-
(1999)
Eur. J. Inorg. Chem.
, pp. 1211-1218
-
-
Wiberg, N.1
Lerner, H.-W.2
Vasisht, S.-K.3
Wagner, S.4
Karaghiosoff, K.5
Nöth, H.6
Ponikwar, W.7
-
25
-
-
77950962167
-
-
a) M. Kira, Chem. Commun. 2010, 46, 2893 - 2903;
-
(2010)
Chem. Commun.
, vol.46
, pp. 2893-2903
-
-
Kira, M.1
-
26
-
-
72249103225
-
-
b) M. Kira, T. Iwamoto, S. Ishida, H. Masuda, T. Abe, C. Kabuto, J. Am. Chem. Soc. 2009, 131, 17135 - 17144;
-
(2009)
J. Am. Chem. Soc.
, vol.131
, pp. 17135-17144
-
-
Kira, M.1
Iwamoto, T.2
Ishida, S.3
Masuda, H.4
Abe, T.5
Kabuto, C.6
-
27
-
-
12844275931
-
-
c) T. Iwamoto, H. Masuda, C. Kabuto, M. Kira, Organometallics 2005, 24, 197 - 199;
-
(2005)
Organometallics
, vol.24
, pp. 197-199
-
-
Iwamoto, T.1
Masuda, H.2
Kabuto, C.3
Kira, M.4
-
28
-
-
0037434767
-
-
d) S. Ishida, T. Iwamoto, C. Kabuto, M. Kira, Nature 2003, 421, 725 - 727;
-
(2003)
Nature
, vol.421
, pp. 725-727
-
-
Ishida, S.1
Iwamoto, T.2
Kabuto, C.3
Kira, M.4
-
29
-
-
79959966033
-
-
For another example of trisilaallene without structural characterization, see: e) H. Tanaka, S. Inoue, M. Ichinohe, M. Driess, A. Sekiguchi, Organometallics 2011, 30, 3475-3478.
-
(2011)
Organometallics
, vol.30
, pp. 3475-3478
-
-
Tanaka, H.1
Inoue, S.2
Ichinohe, M.3
Driess, M.4
Sekiguchi, A.5
-
30
-
-
84874610017
-
-
a) K. C. Mondal, H.W. Roesky, M. C. Schwarzer, G. Frenking, B. Niepotter, H.Wolf, R. Herbst-Irmer,D. Stalke, Angew. Chem. Int. Ed. 2013, 52, 2963 - 2967;
-
(2013)
Angew. Chem. Int. Ed.
, vol.52
, pp. 2963-2967
-
-
Mondal, K.C.1
Roesky, H.W.2
Schwarzer, M.C.3
Frenking, G.4
Niepotter, B.5
Wolf, H.6
Herbst-Irmer, R.7
Stalke, D.8
-
31
-
-
84879394447
-
-
Angew. Chem. 2013, 125, 3036 - 3040;
-
(2013)
Angew. Chem.
, vol.125
, pp. 3036-3040
-
-
-
32
-
-
84883120963
-
-
b) Y. Li, K. C. Mondal, H.W. Roesky, H. Zhu, P. Stollberg, R. Herbst-Irmer, D. Stalke, D. M. Andrada, J. Am. Chem. Soc. 2013, 135, 12422-12428.
-
(2013)
J. Am. Chem. Soc.
, vol.135
, pp. 12422-12428
-
-
Li, Y.1
Mondal, K.C.2
Roesky, H.W.3
Zhu, H.4
Stollberg, P.5
Herbst-Irmer, R.6
Stalke, D.7
Andrada, D.M.8
-
33
-
-
84875779913
-
-
a) Y. Xiong, S. Yao, G. Tan, S. Inoue, M. Driess, J. Am. Chem. Soc. 2013, 135, 5004 - 5007;
-
(2013)
J. Am. Chem. Soc.
, vol.135
, pp. 5004-5007
-
-
Xiong, Y.1
Yao, S.2
Tan, G.3
Inoue, S.4
Driess, M.5
-
34
-
-
84880140182
-
-
b) Y. Xiong, S. Yao, S. Inoue, J. D. Epping, M. Driess, Angew. Chem. Int. Ed. 2013, 52, 7147 - 7150;
-
(2013)
Angew. Chem. Int. Ed.
, vol.52
, pp. 7147-7150
-
-
Xiong, Y.1
Yao, S.2
Inoue, S.3
Epping, J.D.4
Driess, M.5
-
35
-
-
84915797141
-
-
Angew. Chem. 2013, 125, 7287-7290.
-
(2013)
Angew. Chem.
, vol.125
, pp. 7287-7290
-
-
-
36
-
-
84897655779
-
-
a) T. Chu, L. Belding, A. van der Est, T. Dudding, I. Korobkov, G. I. Nikonov, Angew. Chem. Int. Ed. 2014, 53, 2711 - 2715;
-
(2014)
Angew. Chem. Int. Ed.
, vol.53
, pp. 2711-2715
-
-
Chu, T.1
Belding, L.2
Van Der Est, A.3
Dudding, T.4
Korobkov, I.5
Nikonov, G.I.6
-
37
-
-
84904606609
-
-
Angew. Chem. 2014, 126, 2749 - 2753;
-
(2014)
Angew. Chem.
, vol.126
, pp. 2749-2753
-
-
-
38
-
-
84886995129
-
-
For a Sn analogue, see: b) J. Flock, A. Suljanovic, A. Torvisco, W. Schoefberger, B. Gerke, R. Pöttgen, R. C. Fischer, M. Flock, Chem. Eur. J. 2013, 19, 15504-15517.
-
(2013)
Chem. Eur. J.
, vol.19
, pp. 15504-15517
-
-
Flock, J.1
Suljanovic, A.2
Torvisco, A.3
Schoefberger, W.4
Gerke, B.5
Pöttgen, R.6
Fischer, R.C.7
Flock, M.8
-
39
-
-
84887729556
-
-
a) P. Liu, M. Wesolek, A. A. Danopoulos, P. Braunstein, Organometallics 2013, 32, 6286 - 6297;
-
(2013)
Organometallics
, vol.32
, pp. 6286-6297
-
-
Liu, P.1
Wesolek, M.2
Danopoulos, A.A.3
Braunstein, P.4
-
41
-
-
82355172803
-
-
c) T. G. Larocque, A. C. Badaj, S. Dastgir, G. G. Lavoie, Dalton Trans. 2011, 40, 12705 - 12712;
-
(2011)
Dalton Trans.
, vol.40
, pp. 12705-12712
-
-
Larocque, T.G.1
Badaj, A.C.2
Dastgir, S.3
Lavoie, G.G.4
-
42
-
-
77955856019
-
-
d) J. A. Thagfi, S. Dastgir, A. J. Lough, G. G. Lavoie, Organometallics 2010, 29, 3133-3138.
-
(2010)
Organometallics
, vol.29
, pp. 3133-3138
-
-
Thagfi, J.A.1
Dastgir, S.2
Lough, A.J.3
Lavoie, G.G.4
-
43
-
-
84901065479
-
-
CCDC 1012364 (2), 1012365 (3), 1012366 (4), and 1018493 (5) contain the supplementary crystallographic data for this paper. These data can be obtained free of charge from The Cambridge Crystallographic Data Centre via www.ccdc.cam.ac.uk/data-request/cif.
-
The Cambridge Crystallographic Data Centre Via
-
-
-
44
-
-
84863421505
-
-
A. P. Singh, H.W. Roesky, E. Carl, D. Stalke, J.-P. Demers, A. Lange, J. Am. Chem. Soc. 2012, 134, 4998-5003.
-
(2012)
J. Am. Chem. Soc.
, vol.134
, pp. 4998-5003
-
-
Singh, A.P.1
Roesky, H.W.2
Carl, E.3
Stalke, D.4
Demers, J.-P.5
Lange, A.6
-
45
-
-
84877687221
-
-
a) S. Khan, G. Gopakumar, W. Thiel, M. Alcarazo, Angew. Chem. Int. Ed. 2013, 52, 5644 - 5647;
-
(2013)
Angew. Chem. Int. Ed.
, vol.52
, pp. 5644-5647
-
-
Khan, S.1
Gopakumar, G.2
Thiel, W.3
Alcarazo, M.4
-
46
-
-
84879918934
-
-
Angew. Chem. 2013, 125, 5755 - 5758;
-
(2013)
Angew. Chem.
, vol.125
, pp. 5755-5758
-
-
-
47
-
-
84870044765
-
-
b) Y. Xiong, S. Yao, S. Inoue, A. Berkefeld, M. Driess, Chem. Commun. 2012, 48, 12198 - 12200;
-
(2012)
Chem. Commun.
, vol.48
, pp. 12198-12200
-
-
Xiong, Y.1
Yao, S.2
Inoue, S.3
Berkefeld, A.4
Driess, M.5
-
48
-
-
77149178389
-
-
c) F. Cheng, J. D. Dyke, F. Ferrante, A. L. Hector, W. Levason, G. Reid, M. Webster, W. Zhang, Dalton Trans. 2010, 39, 847 - 856;
-
(2010)
Dalton Trans.
, vol.39
, pp. 847-856
-
-
Cheng, F.1
Dyke, J.D.2
Ferrante, F.3
Hector, A.L.4
Levason, W.5
Reid, G.6
Webster, M.7
Zhang, W.8
-
49
-
-
33748232771
-
-
d) T. Probst, O. Steigelmann, J. Riede, H. Schmidbaur, Angew. Chem. Int. Ed. Engl. 1990, 29, 1397 - 1398;
-
(1990)
Angew. Chem. Int. Ed. Engl.
, vol.29
, pp. 1397-1398
-
-
Probst, T.1
Steigelmann, O.2
Riede, J.3
Schmidbaur, H.4
-
50
-
-
0007913952
-
-
Angew. Chem. 1990, 102, 1471-1473.
-
(1990)
Angew. Chem.
, vol.102
, pp. 1471-1473
-
-
-
51
-
-
33646400689
-
-
(for full reference, see the Supporting Information)
-
M. J. Frisch et al., Gaussian, Inc., Wallingford, CT, 2010 (for full reference, see the Supporting Information).
-
(2010)
Gaussian, Inc., Wallingford, CT
-
-
Frisch, M.J.1
-
52
-
-
84891775244
-
-
For different viewpoints on the use of dative arrows, see: a) D. Himmel, I. Krossing, A. Schnepf, Angew. Chem. Int. Ed. 2014, 53, 370 - 374;
-
(2014)
Angew. Chem. Int. Ed.
, vol.53
, pp. 370-374
-
-
Himmel, D.1
Krossing, I.2
Schnepf, A.3
-
53
-
-
84899971571
-
-
Angew. Chem. 2014, 126, 378 - 382;
-
(2014)
Angew. Chem.
, vol.126
, pp. 378-382
-
-
-
55
-
-
84905229306
-
-
Angew. Chem. 2014, 126, 6152 - 6158;
-
(2014)
Angew. Chem.
, vol.126
, pp. 6152-6158
-
-
-
56
-
-
84902135452
-
-
c) D. Himmel, I. Krossing, A. Schnepf, Angew. Chem. Int. Ed. 2014, 53, 6047 - 6049;
-
(2014)
Angew. Chem. Int. Ed.
, vol.53
, pp. 6047-6049
-
-
Himmel, D.1
Krossing, I.2
Schnepf, A.3
-
57
-
-
84915806613
-
-
Angew. Chem. 2014, 126, 6159-6160.
-
(2014)
Angew. Chem.
, vol.126
, pp. 6159-6160
-
-
-
58
-
-
0029835104
-
-
a) R.West, H. Sohn, D. R. Powell, T. Müller, Y. Apeloig, Angew. Chem. Int. Ed. 1996, 35, 1002 - 1004;
-
(1996)
Angew. Chem. Int. Ed.
, vol.35
, pp. 1002-1004
-
-
West, R.1
Sohn, H.2
Powell, D.R.3
Müller, T.4
Apeloig, Y.5
-
59
-
-
0006050582
-
-
Angew. Chem. 1996, 108, 1095 - 1097;
-
(1996)
Angew. Chem.
, vol.108
, pp. 1095-1097
-
-
-
60
-
-
0029799814
-
-
b)W. P. Freeman, T. D. Tilley, L. M. Liable-Sand, A. L. Rheingold, J. Am. Chem. Soc. 1996, 118, 10457 - 10468;
-
(1996)
J. Am. Chem. Soc.
, vol.118
, pp. 10457-10468
-
-
Freeman, W.P.1
Tilley, T.D.2
Liable-Sand, L.M.3
Rheingold, A.L.4
-
62
-
-
53349114266
-
-
Angew. Chem. 2007, 119, 6716-6740.
-
(2007)
Angew. Chem.
, vol.119
, pp. 6716-6740
-
-
-
63
-
-
84902572246
-
-
Elsevier, Amsterdam
-
a) V. Ya. Lee, A. Sekiguchi, Comprehensive Inorganic Chemistry II, Vol.1, Elsevier, Amsterdam, 2013, pp. 289 - 324;
-
(2013)
Comprehensive Inorganic Chemistry II
, vol.1
, pp. 289-324
-
-
Ya. Lee, V.1
Sekiguchi, A.2
-
65
-
-
84891585394
-
-
Wiley, Chichester, Chapter 5
-
c) V. Ya. Lee, A. Sekiguchi, Organometallic Compounds of Low-Coordinate Si, Ge, Sn and Pb: From Phantom Species to Stable Compounds, Wiley, Chichester, 2010, Chapter 5.
-
(2010)
Organometallic Compounds of Low-Coordinate Si Ge Sn and Pb: From Phantom Species to Stable Compounds
-
-
Ya. Lee, V.1
Sekiguchi, A.2
-
66
-
-
33745344889
-
-
a)W. A. Herrmann, M. Denk, J. Behm, W. Scherer, F.-R. Klingan, H. Bock, B. Solouki, M. Wagner, Angew. Chem. Int. Ed. Engl. 1992, 31, 1485 - 1488;
-
(1992)
Angew. Chem. Int. Ed. Engl.
, vol.31
, pp. 1485-1488
-
-
Herrmann, W.A.1
Denk, M.2
Behm, J.3
Scherer, W.4
Klingan, F.-R.5
Bock, H.6
Solouki, B.7
Wagner, M.8
-
67
-
-
0001634009
-
-
Angew. Chem. 1992, 104, 1489 - 1492;
-
(1992)
Angew. Chem.
, vol.104
, pp. 1489-1492
-
-
|